2-[10-(Dicyanomethylidene)-6-dodecoxy-2-(5-thiophen-3-ylpentoxy)anthracen-9-ylidene]propanedinitrile | 540475-28-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-[10-(Dicyanomethylidene)-6-dodecoxy-2-(5-thiophen-3-ylpentoxy)anthracen-9-ylidene]propanedinitrile
• 英文别名: 2-[10-(dicyanomethylidene)-6-dodecoxy-2-(5-thiophen-3-ylpentoxy)anthracen-9-ylidene]propanedinitrile
• CAS: 540475-28-3
• 化学式: C₄₁H₄₄N₄O₂S
• 分子量: 656.892
• InChiKey: RTLHRRORDPNNRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  48
• 可旋转键数：
  19
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  142
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  2,6-二羟基蒽醌 在 吡啶 、 四氯化钛 、 potassium carbonate 、 sodium iodide 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 反应 120.0h， 生成 2-[10-(Dicyanomethylidene)-6-dodecoxy-2-(5-thiophen-3-ylpentoxy)anthracen-9-ylidene]propanedinitrile
  参考文献：
  名称：

  Synthesis of Soluble Donor−Acceptor Double-Cable Polymers Based on Polythiophene and Tetracyanoanthraquinodimethane (TCAQ)

  摘要：

  [GRAPHICS]Novel suitably functionalized tetracyanoanthraquinodimethane (TCAQ) derivatives covalently linked to thiophene moieties have been synthesized. The thiophene-based monomers have been chemically polymerized and copolymerized to yield new and soluble donor-acceptor double-cable polymers. The absorption and emission data reveal that the optical properties can be finely tuned by modifying the ratio of monomers in the copolymerization process.

  DOI：

  10.1021/ol034324e

文献信息

• Synthesis of Soluble Donor−Acceptor Double-Cable Polymers Based on Polythiophene and Tetracyanoanthraquinodimethane (TCAQ)
  作者：Francesco Giacalone、José L. Segura、Nazario Martín、Marinella Catellani、Silvia Luzzati、Natalia Lupsac

  DOI：10.1021/ol034324e

  日期：2003.5.1

  [GRAPHICS]Novel suitably functionalized tetracyanoanthraquinodimethane (TCAQ) derivatives covalently linked to thiophene moieties have been synthesized. The thiophene-based monomers have been chemically polymerized and copolymerized to yield new and soluble donor-acceptor double-cable polymers. The absorption and emission data reveal that the optical properties can be finely tuned by modifying the ratio of monomers in the copolymerization process.