1,4,7,10,13,16,19-heptaoxacyclodocosane-20,22-dione | 76561-94-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 大环内酯类和类似物
• 英文名称: 1,4,7,10,13,16,19-heptaoxacyclodocosane-20,22-dione
• CAS: 76561-94-9
• 化学式: C₁₅H₂₆O₉
• 分子量: 350.366
• InChiKey: YKIUOTNEDBTZJP-UHFFFAOYSA-N

物化性质

• 沸点：
  196-198 °C(Press: 0.8 Torr)
• 密度：
  1.092±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  98.8
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  1,4,7,10,13,16,19-heptaoxacyclodocosane-20,22-dione 在 4-乙酰氨基苯磺酰叠氮 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 二氯甲烷 为溶剂， 以88%的产率得到21-diazo-1,4,7,10,13,16,19-heptaoxacyclodocosane-20,22-dione
  参考文献：
  名称：

  Reactions of macrocyclic rhodium carbenoids: regioselective synthesis of indol-3-yl macrocyclic lactones and cryptands

  摘要：

  A wide variety of new macrocyclic diazocarbonyl compounds with various spacers was synthesized. Macrocyclic rhodium(H) carberioid insertion with various substituted indoles was performed to afford regioselectively, indol-3-yl macrocyclic di- or tetralactones (C3-alkylation). Double carberioid insertion was also performed to afford indolyl cryptand molecules. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.11.102
• 作为产物：
  描述：

  六甘醇 、 丙二酰氯 以 苯 为溶剂， 反应 48.0h， 以57%的产率得到1,4,7,10,13,16,19-heptaoxacyclodocosane-20,22-dione
  参考文献：
  名称：

  Bradshaw, Jerald S.; Jolley, Scott T.; Jones, Brian A., Journal of Heterocyclic Chemistry, 1980, vol. 17, # 9, p. 1317 - 1318

  摘要：

  DOI：

文献信息

• Solar cells based on poly(3-alkyl)thiophenes and [60]fullerene: a comparative study
  作者：Nadia Camaioni、Luigi Garlaschelli、Alessandro Geri、Michele Maggini、Giorgia Possamai、Giovanni Ridolfi

  DOI：10.1039/b201338j

  日期：2002.6.21

  Photovoltaic cells made, at ambient conditions, from blends of regioregular poly(3-alkylthiophenes) and soluble fullerene derivatives are compared. It is shown that the cell performance is affected by the length of the donor side-chain, as it occurs in devices based on pure polythiophenes. The highest value of power conversion efficiency (0.84%) were obtained by using poly(3-hexylthiophene) and a fullerene concentration of 33-40% by weight. We anticipate a significant further improvement in power conversion efficiency upon a mild thermal treatment of the cells.

  在环境条件下，由规整聚（3-烷基噻吩）和可溶富勒烯衍生物混合制成的光伏电池进行了比较。研究表明，电池性能受到供体侧链长度的影响，这与基于纯聚噻吩的器件表现一致。使用聚（3-己基噻吩）和33-40%重量比的富勒烯浓度时，获得了最高的功率转换效率（0.84%）。我们预期经过温和的热处理后，功率转换效率将有显著进一步提高。
• Cyclopolymers as Liquid Membrane Carriers
  作者：Emanuela Cagnoni、Dario Pasini、Alessandro Galbiati、Marina Ricci、Righetti

  DOI：10.1021/ma034901e

  日期：2003.11.1
• Malonate Crown Ethers as Building Blocks for Novel D-π-A Chromophores
  作者：Dario Pasini、Pier Paolo Righetti、Valerio Rossi

  DOI：10.1021/ol016798o

  日期：2002.1.1

  [GRAPHICS]A series of new crown ethers, Incorporating a malonate ester functionality, have been synthesized and derivatized with pi-electron rich aldehydes; to give, conjugated, extended "push-pull" compounds. Their ability to bind Lewis acid-like metal cations, such as Mg2+ and Eu3+, has been characterized, and the relative stability constants are presented. When the metal cation is bound to the malonate moiety within the crown ether cavity, the D-pi-A character of the molecular structure is greatly enhanced.
• BRADSHAW J. S.; JOLLEY S. T.; JONES B. A., J. HETEROCYCL. CHEM., 1980, 17, NO 6, 1317-1318
  作者：BRADSHAW J. S.、 JOLLEY S. T.、 JONES B. A.

  DOI：——

  日期：——
• Bradshaw, Jerald S.; Jolley, Scott T.; Jones, Brian A., Journal of Heterocyclic Chemistry, 1980, vol. 17, # 9, p. 1317 - 1318
  作者：Bradshaw, Jerald S.、Jolley, Scott T.、Jones, Brian A.

  DOI：——

  日期：——