1,2-bis(4-pyridylthio)ethane | 100517-56-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1,2-bis(4-pyridylthio)ethane
• 英文别名: 4-(2-pyridin-4-ylsulfanylethylsulfanyl)pyridine
• CAS: 100517-56-4
• 化学式: C₁₂H₁₂N₂S₂
• 分子量: 248.373
• InChiKey: HVUUVUMACNYXNA-UHFFFAOYSA-N

物化性质

• 沸点：
  422.1±30.0 °C(Predicted)
• 密度：
  1.25±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  76.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 1,2-bis(4-pyridylthio)ethane 、 potassium iodide 以 水 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 0.17h， 以45%的产率得到{[1,2-bis(4-pyridylthio)ethane](CuI₂)₂}
  参考文献：
  名称：

  由 4-吡啶基二硫醚配体引导的五种新型卤化铜/硫氰酸盐配位化合物：合成、结构和光催化性能

  摘要：

  摘要 三种结构相关的柔性 4-吡啶基二硫醚配体 1,2-双(4-吡啶硫基)乙烷 (Bpyte)、1,3-双(4-吡啶硫基)丙烷 (Bpytp) 和 1, 4-双( 4-吡啶硫基）丁烷 (Bpytb) 与 CuI（CuBr 和 CuSCN）形成五种新的配合物：{[Bpyte](CuI2)2} (1), {[Bpytp]CuI2} (2), {[Bpytp]3 (CuBr2)3} (3), {[Bpytp]Cu(SCN)2(CH3CN)} (4) 和 {[Bpytb]Cu(SCN)2(DMF)} (5)，已通过 IR 表征， SEM-EDS（能量色散光谱仪）、紫外-可见吸收光谱和热重分析。单晶 X 射线分析表明化合物 1-5 具有一维链。此外，化合物2-5对可见光照射下的甲基橙（MO）表现出良好的光催化降解。

  DOI：

  10.1016/j.molstruc.2018.07.047
• 作为产物：
  描述：

  4-溴吡啶盐酸盐 、 1,2-乙二硫醇 在 sodium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 1,2-bis(4-pyridylthio)ethane
  参考文献：
  名称：

  聚苯乙烯负载的离子液体铜络合物：一种可重复使用的催化剂，用于一锅三组分点击反应

  摘要：

  固定在聚苯乙烯上的1,2-双（4-吡啶硫基）乙烷的铜（II）络合物用作高稳定，活性，可重复使用的绿色催化剂，可通过一锅三点击合成1,2,3-三唑卤化物，叠氮化钠和炔烃的-组分反应。通过FT-IR光谱，热重分析，元素分析，场发射扫描电子显微镜，能量色散X射线，透射电子显微镜和元素分析对催化剂进行了表征。使用0.2摩尔％的催化剂，有机金属卤化物或α-溴代酮和烷基/芳基末端炔烃的高选择性，广泛的多样性以及优异的产物收率。该催化体系在合成双-1,4-二取代的1,2,3-三唑。此外，该催化剂可以循环使用七次而不会降低其催化活性。

  DOI：

  10.1016/j.apcata.2015.07.015

文献信息

• The toxicity of organic sulphides to the eggs and larvae of the glasshouse red spider mite. I.—SS′-disubstituted alkane-αω-dithiols
  作者：R. F. Brookes、J. E. Cranham、W. A. W. Cummings、D. Greenwood、B. S. Jackson、H. A. Stevenson

  DOI：10.1002/jsfa.2740080106

  日期：1957.1

  A laboratory test method for assessing the activity of chemicals against the eggs and young mites of the glasshouse red spider (Tetranychus telarius L.) is described. The results given by a series of SS′-disubstituted alkane-αω-dithiols using this test method are tabulated and discussed.

  描述了一种实验室测试方法，用于评估化学品对温室红蜘蛛（Tetranychus telarius L.）的卵和幼螨的活性。使用该测试方法由一系列 SS'-二取代烷烃-αω-二硫醇给出的结果列表和讨论。
• Molecular tectonics: tubular crystals with controllable channel size and orientation
  作者：Mei-Jin Lin、Abdelaziz Jouaiti、David Pocic、Nathalie Kyritsakas、Jean-Marc Planeix、Mir Wais Hosseini

  DOI：10.1039/b915665h

  日期：——

  The combination of flexible neutral organic tectons based on two pyridines interconnected by a thioether or thioester type spacer with an inorganic ZnSiF6 pillar leads to the formation of 2-D coordination networks and the packing of the latter generates crystals offering controllable tubular channels with imposed orientation along the pillar axis.

  基于两个吡啶通过硫醚或硫酯类间隔物相互连接的柔性中性有机构件与无机ZnSiF6支柱的结合，形成了二维配位网络，后者的堆积生成了提供可控的管状通道，并沿支柱轴线具有固定方向的晶体。
• Self-Assembly of Palladium-Based Macrocycles with N-Heterocyclic Carbene as the “Corner” Ligand
  作者：Xu-Qiong Xiao、Ai-Quan Jia、Yue-Jian Lin、Guo-Xin Jin

  DOI：10.1021/om100040g

  日期：2010.11.8

  Metallacyclic complexes [(C-Mes-C-meth)Pd(L)](2)(OTf)(4) (C-Mes-C-meth = 1,1'-dimesityl-3,3'-methylenediimidazolin-2,2'-diylidene; L = 4,4'-dithiodipyridine (L-1) (5), 1,2-bis(4-pyridylthio)ethane (L-2) (6), 1,3-bis(4-pyridylthio)propane (L-3) (7)) were obtained by the self-assembly of [(C-Mes-C-meth)-Pd(CH3CN)(2)](OTf)(2) with flexible pyridine-based ligands L-1-L-3 in high yields. The reaction of [(C-Mes-C-meth)Pd(CH3CN)(2)](OTf)(2) with a rigid pyrazine ligand led to the formation of mononuclear [(C-Mes-C-meth)Pd(pyrazine)(2)](OTf)(2) (4), which can be ascribed to the effect of the steric bulk of the substituent. Complexes 4-6 have been well characterized by elemental analyses, H-1 NMR and IR spectra, and single-crystal molecular structure analysis.
• Syntheses and Reactions of Half-Sandwich Iridium, Rhodium, and Ruthenium Metallacycles Containing 4-Pyridyl Dithioether Ligands†Dedicated to Professor Kazuyuki Tatsumi on the occasion of his 60th birthday.
  作者：Ai-Quan Jia、Ying-Feng Han、Yue-Jian Lin、Guo-Xin Jin

  DOI：10.1021/om900921g

  日期：2010.1.11

  Metallacyclic complexes [CP4*Ir-4(mu-L')(2)(mu-L)(2)](OTf)(4) (2a, L' = 6,11-dioxy-5,12-naphthacencdione (dhnq(2-)); L = 4-pyridyl dithioether), [CP2*Rh-2(mu-L')(mu-L)](OTf)(2) (3b), and [(p-cymene)(2)Ru-2-(mu-L')(mu-L)](OTf)(2) (3c) were obtained by the reactions of CP2*M-2(mu-L')Cl-2 (M = Ir (1a), Rh (1b)) or (p-cymene)(2)Ru-2(mu-L')Cl-2 (1c) with a flexible bipyridine-based ligand (L) in the presence of AgOTf (OTf = CF3SO3). Treatments of tetranuclear complex 2a and binuclear complexes 3b and 3c with [Cp*IrCl](2)(OTf)(2) or [Cp*RhCl](2)(OTf)(2) gave the homotrinuclear complexes [Cp-3*Ir-3(mu-L')(mu-L)Cl]-(OTf)(3) (4a) and [CP3*Rh-3(mu-L')(mu-L)Cl](OTf)(3) (4b) and heterotrinuclear complexes [CP3*Ir2Rh-(mu-L')(mu-L)Cl](OTf)(3) (4c), [CP3*Rh2Ir(mu-L')(mu-L)Cl](OTf)(3) (4d), [Cp*)-p-cymene)(2)Ru2Ir(mu.-L')-(mu-L)Cl](OTf)(3) (4e), and [Cp*)-p-cymene)(2)Ru2Rh(mu-L')(mu-L)Cl](OTf)(3) (4f), respectively. The flexible tetranuclear complex 2a exhibited different conformations with different guest solvents. The complexes were characterized by IR, H-1 NMR spectroscopy, and elemental analysis. In addition, X-ray Structure analyses Were Performed oil ligand L and complexes 2a, 3c, 4a, and 4e.