1,4-phenylene bis-phenylcarbamate | 22824-04-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-phenylene bis-phenylcarbamate
• 英文别名: N,N'-p-phenylene-bis-carbamic acid diphenyl ester；N.N'-p-Phenylen-dicarbamidsaeure-diphenylester；N.N'-Bis-phenoxycarbonyl-p-phenylendiamin；N,N'-p-Phenylen-bis-carbamidsaeure-diphenylester；diphenyl 1,4-phenylenebiscarbamate；phenyl N-[4-(phenoxycarbonylamino)phenyl]carbamate
• CAS: 22824-04-0
• 化学式: C₂₀H₁₆N₂O₄
• 分子量: 348.358
• InChiKey: WZSRGXUAELHAOV-UHFFFAOYSA-N

物化性质

• 熔点：
  238.5 °C
• 沸点：
  473.6±41.0 °C(Predicted)
• 密度：
  1.343±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.7
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  phenyl (4-nitrophenyl)carbamate 在 盐酸 、 乙醚 、 乙醇 、 N,N-二甲基苯胺 、 tin(ll) chloride 作用下， 生成 1,4-phenylene bis-phenylcarbamate
  参考文献：
  名称：

  FORMATION AND BEHAVIOR OF SOME CARBOARYLOXYAMINOANILINES

  摘要：

  DOI：

  10.1021/jo01198a008

文献信息

• METHOD FOR PRODUCING AMIDES OR POLYAMIDES BY USING AROMATIC CARBAMATES BY WAY OF ISOCYANATES AS PRECURSORS THROUGH CATALYZED THERMAL PROCESSES AND METHOD FOR PRODUCING AROMATIC CARBAMATE PRECURSORS FROM AROMATIC AMINES
  申请人：Great Eastern Resins Industrial Co., Ltd.

  公开号：US20180186731A1

  公开（公告）日：2018-07-05

  The present invention is directed to a process for preparing amides or polyamides by replacing isocyanate starting materials of a catalyzed thermal reaction with aromatic carbamates. Through the catalyzed thermal process involving a non-isocyanate precursor of the present invention, efficiency for producing amides or polyamides can be significantly improved, and the impure side products produced from a side reaction of isocyanate can be greatly curtailed. Hence, amides or polyamides of high purity and yield can be achieved. The invention also relates to a process for preparing aromatic carbamates, the new non-isocyanate precursors for amides or polyamides.

  本发明涉及一种通过用芳香族氨基甲酸酯替换催化热反应的异氰酸酯起始材料来制备酰胺或聚酰胺的方法。通过本发明的非异氰酸酯前体参与的催化热过程，可以显着提高生产酰胺或聚酰胺的效率，并且可以大大减少异氰酸酯的副反应产生的不纯副产物。因此，可以实现高纯度和高产率的酰胺或聚酰胺。本发明还涉及一种制备芳香族氨基甲酸酯的方法，这是用于制备酰胺或聚酰胺的新的非异氰酸酯前体。
• PROCESS FOR PRODUCING ARYL CARBAMATES
  申请人：UBE INDUSTRIES LIMITED

  公开号：EP0902014A1

  公开（公告）日：1999-03-17

  A process for producing an aryl carbamate of a high purity at a high yield by reacting a diaryl carbonate with an amine compound having one or more hydrogen atoms bonded to the N position in the presence of carboxylic acid(s) of the following general formulae (I): R1-COOH and/or (II): R2-COOH (wherein R1 represents an alkyl or cycloalkyl group having a carbon atom at the α-position, which is bonded to only one hydrogen atom, and R2 represents an alkyl group having a carbon atom at the α-position, which is not bonded to a hydrogen atom).

  一种高纯度、高收率的氨基甲酸芳基酯的生产工艺，该工艺是在下列通式(I)的羧酸存在下，使碳酸二芳基酯与一个或多个氢原子键合在 N 位上的胺化合物反应：R1-COOH 和/或 (II)：R2-COOH（其中 R1 代表烷基或环烷基，在 α 位有一个碳原子，只与一个氢原子键合；R2 代表烷基，在 α 位有一个碳原子，不与氢原子键合）。
• Method for producing amides or polyamides by using aromatic carbamates by way of isocyanates as precursors through catalyzed thermal processes and method for producing aromatic carbamate precursors from aromatic amines
  申请人：Great Eastern Resins Industrial Co., Ltd.

  公开号：US10450265B2

  公开（公告）日：2019-10-22

  The present invention is directed to a process for preparing amides or polyamides by replacing isocyanate starting materials of a catalyzed thermal reaction with aromatic carbamates. Through the catalyzed thermal process involving a non-isocyanate precursor of the present invention, efficiency for producing amides or polyamides can be significantly improved, and the impure side products produced from a side reaction of isocyanate can be greatly curtailed. Hence, amides or polyamides of high purity and yield can be achieved. The invention also relates to a process for preparing aromatic carbamates, the new non-isocyanate precursors for amides or polyamides.

  本发明涉及一种用芳香族氨基甲酸酯取代催化热反应中的异氰酸酯起始原料来制备酰胺或聚酰胺的工艺。通过本发明中涉及非异氰酸酯前体的催化热工艺，可以显著提高生产酰胺或聚酰胺的效率，并大大减少异氰酸酯副反应产生的不纯副产品。因此，可以获得高纯度和高产率的酰胺或聚酰胺。本发明还涉及一种制备芳香族氨基甲酸酯（酰胺或聚酰胺的新型非异氰酸酯前体）的工艺。
• Raiford; Dudley, Proceedings of the Iowa Academy of Science, 1944, vol. 51, p. 313,315,316
  作者：Raiford、Dudley

  DOI：——

  日期：——
• US6143917A
  申请人：——

  公开号：US6143917A

  公开（公告）日：2000-11-07