Bis[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl] benzene-1,4-dicarboxylate | 903597-50-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl] benzene-1,4-dicarboxylate
• 英文别名: bis[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl] benzene-1,4-dicarboxylate
• CAS: 903597-50-2
• 化学式: C₃₆H₂₈O₈P₂
• 分子量: 650.561
• InChiKey: GTNOPODBFKKPAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  46
• 可旋转键数：
  10
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  Bis[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl] benzene-1,4-dicarboxylate 在 硝酸 、 乙酸酐 作用下， 反应 4.5h， 以55%的产率得到Bis[2-(2-nitro-6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl] benzene-1,4-dicarboxylate
  参考文献：
  名称：

  WO2006/84489

  摘要：

  公开号：
• 作为产物：
  描述：

  双(2-羟基乙基)对苯二甲酸酯 在 对甲苯磺酸甲酯 作用下， 反应 42.0h， 生成 Bis[2-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl] benzene-1,4-dicarboxylate
  参考文献：
  名称：

  A Novel and Effective Synthetic Approach to 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) Derivatives

  摘要：

  DOPO and its derivatives generally exhibit an outstanding performance as flame retardants in various polymers. Starting from trivalent 10-alkoxy-10H-9-oxa-10-phosphaphenanthrenes, a broad range of DOPO derivatives was synthesized via transesterification with aliphatic alcohols and subsequent Michaelis-Arbuzou rearrangement using catalytic amounts of p-toluenesulfonic acid methylester. Due to the considerable differences in the nature of the alcohols employed, several procedures for processing them are presented.

  DOI：

  10.1080/10426500701407417

文献信息

• GLOW-WIRE RESISTANT POLYAMIDES
  申请人：Roth Michael

  公开号：US20120157589A1

  公开（公告）日：2012-06-21

  Thermoplastic molding compositions comprising A) from 29 to 97.5% by weight of a thermoplastic polyamide, B) from 1 to 20% by weight of melamine cyanurate, C) from 0.5 to 10% by weight of an organic phosphorus compound based on 9,10-dihydro-9-oxa-10-phosphaphenanthrene oxide (DOPO) as parent structure, D) from 1 to 50% by weight of a fibrous filler, the aspect ratio (L/D) of which is from 4 to 25, and the arithmetic average fiber length of which is from 40 to 250 μm, and E) from 0 to 50% by weight of further additives, where the total of the percentages by weight of components A) to E) is 100%.

  热塑性聚合物成型组合物，包括： A) 29-97.5重量％的热塑性聚酰胺 B) 1-20重量％的三聚氰酸蜜胺 C) 0.5-10重量％的有机磷化合物，基于9,10-二氢-9-氧杂-10-膦杂菲氧化物（DOPO）作为母体结构 D) 1-50重量％的纤维填料，其长宽比（L/D）为4-25，算术平均纤维长度为40-250μm E) 0-50重量％的进一步添加剂 其中，组分A）到E）的重量百分比总和为100％。
• GLÜHDRAHTBESTÄNDIGE POLYAMIDE
  申请人：BASF SE

  公开号：EP2652032B1

  公开（公告）日：2015-02-25
• US8575295B2
  申请人：——

  公开号：US8575295B2

  公开（公告）日：2013-11-05
• [DE] GLÜHDRAHTBESTÄNDIGE POLYAMIDE<br/>[EN] GLOW WIRE-RESISTANT POLYAMIDES<br/>[FR] POLYAMIDES RÉSISTANTS AU FIL INCANDESCENT
  申请人：BASF SE

  公开号：WO2012080403A1

  公开（公告）日：2012-06-21

  Thermoplastische Formmassen enthaltend A) 29 bis 97,5 Gew.-% eines thermoplastischen Polyamides, B) 1 bis 20 Gew.-% Melamincyanurat, C) 0,5 bis 10 Gew.-% einer organischen Phosphorverbindung basierend auf 9,10-Dihydro-9-oxa-10-phosphaphenanthrenoxid (DOPO) als Grundgerüst, D) 1 bis 50 Gew.-% eines faserförmigen Füllstoffes mit einem Aspektverhältnis (L/D) von 4 bis 25 und einer mittleren arithmetischen Faserlänge von 40 bis 250 μm, E) 0 bis 50 Gew.-% weiterer Zusatzstoffe wobei die Summe der Gewichtsprozente der Komponenten A) bis E) 100 % ergibt.
• A Novel and Effective Synthetic Approach to 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) Derivatives
  作者：Johannes Artner、Michael Ciesielski、Martin Ahlmann、Olaf Walter、Manfred Döring、Raul M. Perez、Volker Altstädt、Jan K. W. Sandler、Bernhard Schartel

  DOI：10.1080/10426500701407417

  日期：2007.7.19

  DOPO and its derivatives generally exhibit an outstanding performance as flame retardants in various polymers. Starting from trivalent 10-alkoxy-10H-9-oxa-10-phosphaphenanthrenes, a broad range of DOPO derivatives was synthesized via transesterification with aliphatic alcohols and subsequent Michaelis-Arbuzou rearrangement using catalytic amounts of p-toluenesulfonic acid methylester. Due to the considerable differences in the nature of the alcohols employed, several procedures for processing them are presented.