lead 1-chloro-2-phenylethane-2,2-dithiolate | 189373-39-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: lead 1-chloro-2-phenylethane-2,2-dithiolate
• 英文别名: lead 1-chloro-2-phenyl-2,2-ethanedithiolate；2-Chloro-1-phenylethane-1,1-dithiolate;lead(2+)
• CAS: 189373-39-5
• 化学式: C₈H₇ClPbS₂
• 分子量: 409.929
• InChiKey: CVXSDEVBWRZIPL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.09
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  lead 1-chloro-2-phenylethane-2,2-dithiolate 在 sulfur 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以75%的产率得到bis(2,2-epidithio-2-phenylethyl) sulfide
  参考文献：
  名称：

  Shagun; Timokhina; Voronkov, Russian Journal of Organic Chemistry, 1996, vol. 32, # 12, p. 1823 - 1824

  摘要：

  DOI：
• 作为产物：
  描述：

  lead acetate 、 1,1-dimercapto-1-phenyl-2-chloroethane 以 甲醇 为溶剂， 以80%的产率得到lead 1-chloro-2-phenylethane-2,2-dithiolate
  参考文献：
  名称：

  Reaction of 1-chloro-2-phenylethane-2,2-dithiol with divalent metal (Cu, Hg, Pb, Fe, Co, and Ni) salts

  摘要：

  Reactions of 1-chloro-2-phenylethane-2,2-dithiol with lead(II) acetate and mercury(II) chloride lead to 1-chloro-2-phenylethane-2,2-dithiolates of lead and mercury. The reactions with copper(II) chloride, iron(II) sulfate hydrate, cobalt (II) chloride hydrate, and nickel(II) acetate give metal-containing compounds C16H18S4M. The H-1 NMR, IR, and ESR spectra of the obtained compounds were recorded; their specific dark electroconductivities and activation energies of dark conductivity were determined, and their film-forming ability was studied.

  DOI：

  10.1007/bf02496224

文献信息

• Reaction of 1-chloro-2-phenylethane-2,2-dithiol with divalent metal (Cu, Hg, Pb, Fe, Co, and Ni) salts
  作者：L. G. Shagun、M. G. Voronkov、G. I. Sarapulova、G. F. Myachina、T. I. Vakul'skaya、I. A. Dorofeev

  DOI：10.1007/bf02496224

  日期：1997.6

  Reactions of 1-chloro-2-phenylethane-2,2-dithiol with lead(II) acetate and mercury(II) chloride lead to 1-chloro-2-phenylethane-2,2-dithiolates of lead and mercury. The reactions with copper(II) chloride, iron(II) sulfate hydrate, cobalt (II) chloride hydrate, and nickel(II) acetate give metal-containing compounds C16H18S4M. The H-1 NMR, IR, and ESR spectra of the obtained compounds were recorded; their specific dark electroconductivities and activation energies of dark conductivity were determined, and their film-forming ability was studied.
• Shagun; Timokhina; Voronkov, Russian Journal of Organic Chemistry, 1996, vol. 32, # 12, p. 1823 - 1824
  作者：Shagun、Timokhina、Voronkov、Dorofeev、Usova、Sarapulova、Klyba

  DOI：——

  日期：——