menthylbenzenesulphonate | 93157-15-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: menthylbenzenesulphonate
• 英文别名: benzenesulfonic acid menthyl ester；Benzolsulfonsaeure-menthylester；5-Methyl-2-(propan-2-yl)cyclohexyl benzenesulfonate；(5-methyl-2-propan-2-ylcyclohexyl) benzenesulfonate
• CAS: 93157-15-4
• 化学式: C₁₆H₂₄O₃S
• 分子量: 296.431
• InChiKey: JKHRVEWNCCTSDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  menthylbenzenesulphonate 在 barium dihydroxide 作用下， 生成 对薄荷-3-烯
  参考文献：
  名称：

  Patterson; McAlpine, Journal of the Chemical Society, 1928, p. 2470

  摘要：

  DOI：
• 作为产物：
  描述：

  薄荷脑 、 苯磺酰氯 在 吡啶 作用下， 生成 menthylbenzenesulphonate
  参考文献：
  名称：

  Patterson; Frew, Journal of the Chemical Society, 1906, vol. 89, p. 333

  摘要：

  DOI：

文献信息

• Hydrophilic and biologically safe polymer foam as well as preparation method and application thereof
  申请人：Zhang Jianli

  公开号：US10745511B2

  公开（公告）日：2020-08-18

  The present invention provides a method for preparing hydrophilic polymer foam. The method comprises a step of providing an isocyanate functionalized prepolymer (A) and a step of foaming and curing the prepolymer (A). The prepolymer (A) is prepared by reacting diisocyanate (A1) and polyether polyol (A2), wherein the diisocyanate (A1) is selected from any one and a combination of 1,4-butyl diisocyanate (BDI), lysine diisocyanate (LDI) and 1,5-pentyl diisocyanate (PDI); the polyether polyol (A2) is a copolymer of ethylene oxide (EO) and propylene oxide (PO) and/or butylene oxide (BO); the ethylene oxide has a weight percentage of about 50%-100% in the polyether polyol, and has an OH functionality degree of 3-6, a hydroxyl value of about 21 mg KOH/g-168 mg KOH/g and a number-average molecular weight of about 1000 g/mol to about 8000 g/mol; and NCO content in the prepolymer (A) is 1%-10%.

  本发明提供了一种制备亲水性聚合物泡沫的方法。该方法包括提供异氰酸酯官能化预聚物（A）的步骤，以及发泡和固化预聚物（A）的步骤。预聚物 (A) 通过二异氰酸酯 (A1) 和聚醚多元醇 (A2) 反应制备，其中二异氰酸酯 (A1) 选自 1,4-丁基二异氰酸酯 (BDI)、赖氨酸二异氰酸酯 (LDI) 和 1,5-戊基二异氰酸酯 (PDI) 中的任意一种或其组合；聚醚多元醇（A2）是环氧乙烷（EO）和环氧丙烷（PO）和/或环氧丁 烷（BO）的共聚物；环氧乙烷在聚醚多元醇中的重量百分比约为 50%-100%，其羟基官能度为 3-6，羟基值约为 21 毫克 KOH/g-168 毫克 KOH/g，数均分子量约为 1000 克/摩尔至约 8000 克/摩尔；预聚物（A）中的 NCO 含量为 1%-10%。
• The Reaction of Primary and Secondary Alkylaryl and Alkyl Sulfonates with Potassium t-Butoxide in Dimethyl Sulfoxide¹
  作者：Carl H. Snyder、Aida R. Soto

  DOI：10.1021/jo01026a055

  日期：1964.3
• Patterson; McAlpine, Journal of the Chemical Society, 1927, p. 351
  作者：Patterson、McAlpine

  DOI：——

  日期：——
• Dharmaratne, H. R. W.; Gunatilaka, A. A. Leslie; Sotheeswaran, S., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1982, vol. 21, # 1, p. 39 - 41
  作者：Dharmaratne, H. R. W.、Gunatilaka, A. A. Leslie、Sotheeswaran, S.

  DOI：——

  日期：——
• HYDROPHILIC AND BIOLOGICALLY SAFE POLYMER FOAM AS WELL AS PREPARATION METHOD AND APPLICATION THEREOF
  申请人：ZHANG JIANLI

  公开号：US20180155484A1

  公开（公告）日：2018-06-07

  The present invention provides a method for preparing hydrophilic polymer foam. The method comprises a step of providing an isocyanate functionalized prepolymer (A) and a step of foaming and curing the prepolymer (A). The prepolymer (A) is prepared by reacting diisocyanate (A1) and polyether polyol (A2), wherein the diisocyanate (A1) is selected from any one and a combination of 1,4-butyl diisocyanate (BDI), lysine diisocyanate (LDI) and 1,5-pentyl diisocyanate (PDI); the polyether polyol (A2) is a copolymer of ethylene oxide (EO) and propylene oxide (PO) and/or butylene oxide (BO); the ethylene oxide has a weight percentage of about 50%-100% in the polyether polyol, and has an OH functionality degree of 3-6, a hydroxyl value of about 21 mg KOH/g-168 mg KOH/g and a number-average molecular weight of about 1000 g/mol to about 8000 g/mol; and NCO content in the prepolymer (A) is 1%-10%.