N-dodecyl srearamide | 50354-87-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N-dodecyl srearamide
• 英文别名: N-dodecyl-stearamide；N-Dodecyl-stearamid；Stearinsaeure-dodecylamid；N-Dodecyl-stearinamid；N-dodecyloctadecanamide
• CAS: 50354-87-5
• 化学式: C₃₀H₆₁NO
• 分子量: 451.82
• InChiKey: WYZSGZLUHOZOIN-UHFFFAOYSA-N

物化性质

• 熔点：
  90-91 °C
• 沸点：
  472.3±13.0 °C(Predicted)
• 密度：
  0.852±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  13.5
• 重原子数：
  32
• 可旋转键数：
  27
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 危险性防范说明：
  P261,P264,P270,P271,P280,P301+P312,P302+P352,P304+P340,P305+P351+P338,P330,P332+P313,P337+P313,P362,P403+P233,P405,P501
• 危险性描述：
  H302,H315,H319,H335
• 储存条件：
  2-8°C

反应信息

• 作为产物：
  描述：

  十二烷基伯胺 、 硬脂酸 在 nano sulfated-TiO₂ 作用下， 115.0 ℃ 、101.33 kPa 条件下， 反应 2.5h， 以98%的产率得到N-dodecyl srearamide
  参考文献：
  名称：

  Nano Sulfated Titania as Solid Acid Catalyst in Direct Synthesis of Fatty Acid Amides

  摘要：

  Nanosized sulfated titania was prepared by a sol gel hydrothermal process. X-ray diffraction (XRD), transmission electron, and scanning electron micrographs (TEM and SEM), FT-IR specific surface area, and BET N(2) adsorption were employed to characterize the properties of the synthesized sulfated TiO(2). The results indicate that both anatase and rutile TiO(2) are obtainable. This prepared sulfated titania showed high catalytic activity in direct amidation of fatty acids as well as benzoic acids with various amines under solvent-free conditions.

  DOI：

  10.1021/jo2002769

文献信息

• Novel olefin polymer compositions and foamed articles prepared therefrom having improved elevated temperature dimensional stability
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0041234A1

  公开（公告）日：1981-12-09

  Elevated temperature distortion characteristics of freshly prepared olefin polymer foams are substantially improved by employing in the preparation thereof a small amount (e.g., from about 0.15 to about 10 weight percent based on the olefin polymer) of N-substituted fatty acid amide of the formula: wherein R1 represents an alkyl group of from 11 to 17 carbon atoms and R2 represents an alkyl group of from 12 to 18 carbon atoms and wherein the R2 alkyl group is no more than one carbon atom larger than the R1 alkyl group.

  在制备新制备的烯烃聚合物泡沫时，通过使用少量（例如，基于烯烃聚合物，约 0.15 至约 10 重量％）式中的 N-取代脂肪酸酰胺，可大大改善其升温变形特性： 其中 R1 代表 11 至 17 个碳原子的烷基，R2 代表 12 至 18 个碳原子的烷基，R2 烷基比 R1 烷基大不超过一个碳原子。
• Synthèse d'amides gras N-substitués par catalyse enzymatique
  申请人：SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES ( S.E.P.P.I.C.)

  公开号：EP0298796A1

  公开（公告）日：1989-01-11

  La présente invention concerne un procédé pour la synthèse d'amides gras N-substitués par réaction d'un composé organique présentant une fonction acide terminale et un composé organique présentant une fonction amine terminale caractérisé en ce que ladite réaction est effectuée en présence d'une enzyme de la classe des acyltransférases.

  本发明涉及一种通过具有末端酸功能的有机化合物和具有末端胺功能的有机化合物反应合成 N-取代脂肪酰胺的工艺，其特征在于上述反应是在酰基转移酶类酶的存在下进行的。
• Method for producing expandable thermoplastic polymer particles
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0396046A2

  公开（公告）日：1990-11-07

  The present invention provides a method for producing expandable thermoplastic polymer particles which comprises conducting polymerization by adding a polymerizable monomer either continuously or intermittently to thermoplastic polymer particles having a uniform particle size suspended in water,characterized in that an amide compound is added when the added amount of the polymerizable monomer is not more than one half of the total amount to be added in the course of polymerization and resulting polymer particles are impregnated with an easily volatile blowing agent after completion of addition of the amide compound and the polymerizable monomer. According to the present invention, expandable thermoplastic particles which are capable of giving cells, fine and uniform in size, are obtainable even by expanding immediately after production without any aging period.

  本发明提供了一种生产可膨胀热塑性聚合物颗粒的方法，该方法包括通过连续或间歇地向悬浮在水中的粒度均匀的热塑性聚合物颗粒中加入可聚合单体进行聚合，其特征在于，当加入的可聚合单体量不超过聚合过程中加入总量的一半时，加入酰胺化合物，在完成酰胺化合物和可聚合单体的加入后，用易挥发性发泡剂浸渍得到的聚合物颗粒。根据本发明，即使在生产后立即膨胀，也无需任何老化期，即可获得可膨胀热塑性粒子，这种粒子能够形成细小均匀的细胞。
• Thermochromic microencapsulated pigments
  申请人：THE PILOT INK CO., LTD.

  公开号：EP1084860A2

  公开（公告）日：2001-03-21

  Disclosed is a thermochromic microencapsulated pigment which comprises as four essential components (a) an electron-donating chromatic organic compound, (b) an electron-accepting compound, (c) a reaction medium determining the temperatures at which the color reactions of component (a) with component (b) take place, and (d) a color change temperature regulator, the color change temperature regulator (d) comprising one or more compounds selected from the group consisting of esters, alcohols, ketones, acid amides, hydrocarbons, and fatty acids and having a melting point Y (°C) satisfying the relationship (X+30)°C≤Y≤200°C, wherein X (°C) is the melting point of component (c), and the four essential components being microencapsulated.

  本发明公开了一种热致变色微胶囊颜料，它由四种基本成分组成：(a) 一种电子供色有机化合物；(b) 一种电子受色化合物；(c) 一种决定成分(a)与成分(b)发生颜色反应的温度的反应介质；(d) 一种变色温度调节剂、变色温度调节剂(d)包括一种或多种从酯、醇、酮、酸酰胺、烃和脂肪酸组成的组中选出的化合物，其熔点 Y(℃)满足(X+30)℃≤Y≤200℃的关系，其中 X(℃)是组分(c)的熔点，四种基本组分被微胶囊化。
• REVERSIBLY THERMOCHROMIC COMPOSITION, AND REVERSIBLY THERMOCHROMIC MICROCAPSULE PIGMENT HAVING SAME ENCLOSED THEREIN
  申请人：The Pilot Ink Co., Ltd

  公开号：EP3608386A1

  公开（公告）日：2020-02-12

  [Problems] The present invention provides a highly marketable reversibly color changeable composition which provides a vivid yellow to orange color during color development, turns colorless during decoloration, and improves light resistance and a reversibly thermochromic microcapsule pigment encapsulating the same. [Solution] Disclosed are a reversibly thermochromic composition including: (a) a specific pyridine derivative as an electron-donating color-developing organic compound; (b) an electron-accepting compound; and (c) a reaction medium which reversibly induces an electron transfer reaction between the component (a) and the component (b) in a specific temperature range, and a reversibly thermochromic microcapsule pigment encapsulating the same.

  问题 本发明提供了一种高度市场化的可逆变色组合物，该组合物在显色过程中提供鲜艳的黄色至橙色，在脱色过程中变成无色，并提高了耐光性，还提供了封装该组合物的可逆热变色微胶囊颜料。 [解决方案］ 本发明公开了一种可逆热致变色组合物，包括：（a）作为电子捐赠显色有机化合物的特定吡啶衍生物；（b）电子接受化合物；和（c）在特定温度范围内可逆地诱导组分（a）和组分（b）之间发生电子转移反应的反应介质，以及封装该组合物的可逆热致变色微胶囊颜料。