4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol | 59501-41-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol
• 英文别名: 4-(2-(4-(Allyloxy)phenyl)propan-2-yl)phenol；4-[2-(4-prop-2-enoxyphenyl)propan-2-yl]phenol
• CAS: 59501-41-6
• 化学式: C₁₈H₂₀O₂
• 分子量: 268.356
• InChiKey: ICYLQBLDJGYLEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol 以 邻二氯苯 为溶剂， 反应 8.0h， 生成 2-allyl-4-(2-(4-hydroxyphenyl)propane-2-yl)phenol
  参考文献：
  名称：

  EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING THE SAME, COMPOSITION AND CURED PRODUCT COMPRISING THE SAME, AND USES THEREOF

  摘要：

  揭示了一种具有烷氧基硅基团的环氧化合物，其复合材料具有良好的耐热性能和/或其固化产物具有良好的阻燃性能，以及其制备方法，包括该化合物的组合物，固化产物和组合物的用途。所述的烷氧基硅化环氧化合物包括至少一种化学式S1取代基和至少两个环氧基团在核心中，通过烯丙基化、克莱森重排、环氧化和烷氧基硅化制备环氧化合物的方法，包括该环氧化合物的环氧组合物，固化产物和组合物的用途。所述的复合材料具有改善的化学键合、良好的耐热性能、低CTE、高玻璃转变温度或Tg-less。该组合物的固化产物具有良好的阻燃性能。

  公开号：

  US20140179836A1
• 作为产物：
  描述：

  双酚A 、 3-溴丙烯 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol
  参考文献：
  名称：

  了解烯醇醚自由基阳离子的反应性：阳极四元碳环形成的研究

  摘要：

  在阳极四元碳环形成中研究了烯醇醚自由基阳离子的反应性，从而提高了对这些反应的机理理解。含单环的芳族阳离子通过分子间或分子内电子转移而还原，分别得到含单环或双环的化合物。束缚两个芳环的烃连接基的小结构变化对这种电子转移事件的效率产生了强大的影响。

  DOI：

  10.1021/jo3028246

文献信息

• 둘 이상의 알콕시실릴기를 갖는 알콕시 실릴 화합물, 이를 포함하는 조성물, 경화물, 이의 용도 및 알콕시실릴 화합물의 제조방법
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY 한국생산기술연구원(319999029382) BRN ▼119-82-01008

  公开号：KR101644531B1

  公开（公告）日：2016-08-02

  본 발명은 복합체에서 우수한 내열특성을 나타내는 둘 이상의 알콕시실릴기를 갖는 알콕시실릴 화합물(이하, '알콕시실릴 화합물'이라 함), 이를 포함하는 조성물, 경화물, 및 이의 용도 및 알콕시실릴 화합물의 제조방법에 관한 것이다. 본 발명에 의한 새로운 알콕시실릴 화합물을 포함하는 알콕시실릴 조성물은 복합체에서, 알콕시실릴기와 충진제(섬유 및/또는 입자)와의 화학 결합 형성으로, 향상된 내열특성, 즉, 알콕시실릴 조성물의 CTE가 감소되고 유리전이온도 상승 또는 유리전이온도를 나타내지 않는(이하, 'Tg 리스'라 함) 효과를 나타낸다. 나아가, 본 발명에 의한 알콕시실릴 화합물을 포함하는 경화물은 알콕시실릴기로 인하여 우수한 난연성을 나타낸다. 더욱이, 본 발명에 의한 알콕시실릴 조성물을 기판의 금속필름에 적용하는 경우에, 금속필름 표면의 작용기와 알콕시실릴기의 화학결합에 의해 금속필름에 대하여 우수한 접착력을 나타낸다.

  本发明涉及具有两个或两个以上的烷氧基硅基团，表现出优异耐热特性的烷氧基硅化合物（以下简称为“烷氧基硅化合物”），以及包含该化合物的组合物、固化物，以及其用途和烷氧基硅化合物的制备方法。包含新的烷氧基硅化合物的烷氧基组合物根据本发明在复合体中，通过烷氧基基与填料（纤维和/或颗粒）的化学结合形成，表现出改善的耐热特性，即，烷氧基组合物的CTE降低并且不显示玻璃化转变温度的升高或玻璃化转变温度不变（以下简称为“Tg失效”）。此外，包含本发明的烷氧基硅化合物的固化物由于烷氧基基表现出优异的阻燃性。此外，将根据本发明的烷氧基组合物应用于基板的金属薄膜时，金属薄膜表面的官能团与烷氧基的化学结合表现出对金属薄膜具有优异的粘附力。
• THERMOSETTING ALKOXYSILYL COMPOUND HAVING TWO OR MORE ALKOXYSILYL GROUPS, COMPOSITION AND CURED PRODUCT COMPRISING SAME, USE THEREOF, AND METHOD FOR PREPARING ALKOXYSILYL COMPOUND
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20180155370A1

  公开（公告）日：2018-06-07

  The present invention relates to: a thermosetting alkoxysilyl compound (hereinafter, referred to as “alkoxysilyl compound”)having two or more alkoxysilyl groups showing excellent heat-resistance characteristics in a composite; a composition and a cured product comprising the same; a use thereof; and a method for preparing an alkoxysilyl compound. The composition of an alkoxysilyl compound, comprising a novel alkoxysilyl compound according to the present invention shows, in a composite, improved heat-resistance characteristics, i.e., an effect of decreasing the CTE of the composition of an alkoxysilyl compound and not showing a glass transition temperature (hereinafter, referred to as “Tg-less”). Further, the cured product comprising an alkoxysilyl compound according to the present invention shows excellent flame retardant properties due to the alkoxysilyl groups.

  本发明涉及一种热固性烷氧基硅基化合物（以下简称“烷氧基硅基化合物”），其具有两个或两个以上的烷氧基硅基团，在复合材料中表现出优异的耐热特性；包括该烷氧基硅基化合物的组合物和固化产物；其用途；以及制备烷氧基硅基化合物的方法。根据本发明的一种烷氧基硅基化合物的组合物显示出改善的耐热特性，即降低烷氧基硅基化合物组合物的CTE并且不显示玻璃转变温度（以下简称“Tg-less”）的效果。此外，根据本发明的一种烷氧基硅基化合物的固化产物由于烷氧基硅基团表现出优异的阻燃性能。
• COMPOSITION AND CURED ARTICLE COMPRISING INORGANIC PARTICLES AND EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, USE FOR SAME, AND PRODUCTION METHOD FOR EPOXY COMPOUND HAVING ALKOXYSILYL GROUP
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20150148452A1

  公开（公告）日：2015-05-28

  There is provided a composition including an alkoxysilylated epoxy compound, a composition of which exhibits good heat resistance properties, low CTE and high glass transition temperature or Tg-less and not requiring a separate coupling agent, and inorganic particles, a cured product formed of the composition, and a use of the cured product. An epoxy composition including an alkoxysilylated epoxy compound and inorganic particles, an epoxy composition including an epoxy compound, inorganic particles and a curing agent, a cured product of the composition, and a use of the composition are provided. Since chemical bonds may be formed between the alkoxysilyl group and the inorganic particles and between the alkoxysilyl groups, a composition of the composition including the alkoxysilylated epoxy compound and the inorganic particles exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg less.

  提供一种包括烷氧硅基化环氧化合物的组合物，该组合物的性质具有良好的耐热性能，低CTE和高玻璃转变温度或Tg-无需单独的偶联剂，并且包括无机颗粒，所述组合物形成的固化产物，以及所述固化产物的用途。提供一种包括烷氧硅基化环氧化合物和无机颗粒的环氧组合物，一种包括环氧化合物、无机颗粒和固化剂的环氧组合物，所述组合物的固化产物，以及所述组合物的用途。由于烷氧硅基团与无机颗粒之间以及烷氧硅基团之间可能形成化学键，因此包括烷氧硅基化环氧化合物和无机颗粒的组合物具有改善的耐热性能、降低的CTE和增加的玻璃转变温度或Tg less。
• Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom
  申请人：Dow Global Technologies Inc.

  公开号：US06646102B2

  公开（公告）日：2003-11-11

  A process for manufacturing an &agr;-dihydroxy derivative from an aryl allyl ether wherein such &agr;-dihydroxy derivative can be used to prepare an &agr;-halohydrin intermediate and an epoxy resin prepared therefrom including epoxidizing an &agr;-halohydrin intermediate produced from a halide substitution of an &agr;-dihydroxy derivative which has been obtained by a dihydroxylation reaction of an aryl allyl ether in the presence of an oxidant or in the presence of an oxidant and a catalyst.

  从芳基烯丙基醚制备α-二羟基衍生物的制造过程，其中该α-二羟基衍生物可用于制备α-卤代醇中间体和由此制备的环氧树脂，包括在氧化剂存在下或在氧化剂和催化剂存在下通过卤代物取代从α-二羟基衍生物脱氢反应中获得的α-卤代醇中间体的环氧化。
• Process for preparing aryl allyl ethers
  申请人：——

  公开号：US20040024263A1

  公开（公告）日：2004-02-05

  A process for preparing an allyl ether including reacting (a) a phenolic compound with (b) an allyl carboxylate or an allyl carbonate in the presence of (c) a transition metal or rare earth metal catalyst complexed with at least one strongly bonded, non-replaceable stable ligand whereby an allyl ether is formed. The ligand of the transition metal or rare earth metal catalyst complex may be (i) an olefinic-containing ligand or aromatic-containing ligand; or (ii) a polymeric ligand or a heteroatom-containing multidentate ligand.

  制备烯丙基醚的过程包括在（c）过渡金属或稀土金属催化剂的存在下，通过反应（a）酚类化合物和（b）烯丙酸酯或烯丙基碳酸酯来形成烯丙基醚，其中过渡金属或稀土金属催化剂的配体可以是（i）含有烯丙基或芳香基的配体；或（ii）聚合配体或含有杂原子的多齿配体。