Bis(2-phenylphen-1-oxy)chlorphosphan | 105281-82-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis(2-phenylphen-1-oxy)chlorphosphan
• 英文别名: bis(o-biphenylyl) chlorophosphite；Chloro-bis(2-phenylphenoxy)phosphane
• CAS: 105281-82-1
• 化学式: C₂₄H₁₈ClO₂P
• 分子量: 404.832
• InChiKey: FSAUETDIQBGZOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-nonadecylphenol 、 Bis(2-phenylphen-1-oxy)chlorphosphan 在 甲基锂 作用下， 生成 4-nonadecylphenyl bis(o-bifenylyl) phosphite
  参考文献：
  名称：

  Use of functionalized ethylene oligomers to prepare recoverable, recyclable nickel(0) diene cyclooligomerization catalysts

  摘要：

  DOI：

  10.1021/jo00375a002
• 作为产物：
  描述：

  邻苯基苯酚 在 N,N-二异丙基乙胺 、 三氯化磷 作用下， 以 甲苯 为溶剂， 反应 14.0h， 生成 三(2-苯基苯基)亚磷酸酯 、 Bis(2-phenylphen-1-oxy)chlorphosphan
  参考文献：
  名称：

  Solid-Phase Parallel Synthesis of Phosphite Ligands

  摘要：

  Various routes for the synthesis of polymer-bound phosphites and phosphoramidites have been investigated. In the presence of a suitable activator the supported phosphoramidites react cleanly with alcohols to give the corresponding monodentate phosphite ligands in solution. We have applied this novel solid-phase route in the parallel synthesis of several monodentate chiral and achiral phosphite ligands.

  DOI：

  10.1021/ol703070x

文献信息

• Maringgele, Walter; Meller, Anton, Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 90, # 1-4, p. 235 - 242
  作者：Maringgele, Walter、Meller, Anton

  DOI：——

  日期：——
• Process for preparation of polymeric, phosphorus-containing compositions
  申请人：INVISTA Technologies S.à.r.l.

  公开号：EP1586598B1

  公开（公告）日：2009-09-09
• Use of functionalized ethylene oligomers to prepare recoverable, recyclable nickel(0) diene cyclooligomerization catalysts
  作者：David E. Bergbreiter、Rama Chandran

  DOI：10.1021/jo00375a002

  日期：1986.12
• Solid-Phase Parallel Synthesis of Phosphite Ligands
  作者：Bert H. G. Swennenhuis、Ruifang Chen、Piet W. N. M. van Leeuwen、Johannes G. de Vries、Paul C. J. Kamer

  DOI：10.1021/ol703070x

  日期：2008.3.1

  Various routes for the synthesis of polymer-bound phosphites and phosphoramidites have been investigated. In the presence of a suitable activator the supported phosphoramidites react cleanly with alcohols to give the corresponding monodentate phosphite ligands in solution. We have applied this novel solid-phase route in the parallel synthesis of several monodentate chiral and achiral phosphite ligands.