N,N',N''-tri(4-methylphenyl)-1,3,5-triaminobenzene | 104216-55-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N',N''-tri(4-methylphenyl)-1,3,5-triaminobenzene
• 英文别名: N,N',N''-tri-p-tolyl-benzene-1,3,5-triyltriamine；N,N',N''-Tri-p-tolyl-benzen-1,3,5-triyltriamin；1.3.5-Tri-p-toluidino-benzol；N,N',N''-tri-p-tolyl-1,3,5-benzenetriamine；1,3,5-tris(p-tolyl)aminobenzene；1,3,5-tris(p-tolylamino)benzene；1-N,3-N,5-N-tris(4-methylphenyl)benzene-1,3,5-triamine
• CAS: 104216-55-9
• 化学式: C₂₇H₂₇N₃
• 分子量: 393.531
• InChiKey: FRRRHKZBCWHKAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  36.1
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N,N',N''-tri(4-methylphenyl)-1,3,5-triaminobenzene 生成 乙烷,三氯氟-
  参考文献：
  名称：

  Minunni, Gazzetta Chimica Italiana, 1890, vol. 20, p. 343

  摘要：

  DOI：
• 作为产物：
  描述：

  间苯三酚 、 乙烷,三氯氟- 在 碘 作用下， 以52%的产率得到N,N',N''-tri(4-methylphenyl)-1,3,5-triaminobenzene
  参考文献：
  名称：

  1,3,5-三（二芳基氨基）苯的阳离子自由基

  摘要：

  循环伏安法和ESR研究揭示了一些1,3,5-三（二芳基氨基）苯的阳离子自由基的性质。结果表明，有效离域的自由基阳离子在冷介质中具有长的溶液寿命，但在环境温度下的动态稳定性比其单体三芳基铵阳离子自由基对应物要小得多。分子内邻位偶合，可能是通过歧化，是一种假定的阳离子自由基衰变模式。

  DOI：

  10.1016/0040-4039(95)00094-s

文献信息

• Organo-electronic functional material and use thereof
  申请人：Akashi Nobutaka

  公开号：US20070066848A1

  公开（公告）日：2007-03-22

  The invention provides an organo-electronic functional material comprising a tris(arylamino)benzene represented by the general formula (I) wherein A and B are each a group represented by the general formula (II) in which R is an alkyl group of 1-6 carbons or a cycloalkyl group of 5 or 6 carbon atoms and n is 0, 1, 2 or 3, and A and B may be the same or different from each other, and exhibiting a cyclic voltamogram in which a deviation of peak current of cyclic curves as measured 50 times at a sweep rate of 20 mV/s falls within ±10% of the average of peak current. The organo-electronic functional material has an opto-electronic exchanging function, a reversible oxidation-reduction property and a high glass transition temperature, and can form amorphous film in itself. In addition, it is stable and exhibits only slight variation of peak current in repeated oxidation-reduction process so that it is suitable for use as, for example, a hole transporting material among others in various electronic devices including an organic electroluminescence element.

  该发明提供了一种有机电子功能材料，包括由通式（I）表示的三(芳基氨基)苯，其中A和B分别是由通式（II）表示的基团，其中R是1-6碳原子的烷基基团或5或6碳原子的环烷基基团，n为0、1、2或3，A和B可以相同也可以不同，并且在循环伏安图中表现出峰电流的偏差，该偏差是在以20 mV/s扫描速率进行50次测量的循环曲线中，其峰电流的偏差在±10%内，与峰电流的平均值相匹配。该有机电子功能材料具有光电交换功能、可逆氧化还原性和高玻璃化转变温度，并且可以自身形成非晶膜。此外，它稳定性高，在重复氧化还原过程中仅表现出轻微的峰电流变化，因此适用于用作各种电子设备中的孔传输材料，包括有机电致发光元件。
• Novel 1,3,5-tris(arylamino)benzene
  申请人：Akashi Nobutaka

  公开号：US20050090692A1

  公开（公告）日：2005-04-28

  The invention provides 1,3,5-tris(arylamino)benzenes represented by the general formula (I) wherein A is naphthyl, anthryl, phenanthryl, biphenylyl or terphenylyl group, and R is alkyl having 1-6 carbon atoms or cycloalkyl group having five or six carbon atoms. The 1,3,5-tris(arylamino)benzenes have oxidation potentials in the range of about 0.5-0.6V, excellent reversibility in oxidation-reduction process and high glass transition temperatures and in addition, they are capable of forming stable and durable amorphous film useful as high performance organic semiconductors at normal temperatures or higher with no aid of binder resins, that is, by themselves.

  本发明提供的是以通式（I）表示的1,3,5-三（芳基氨基）苯的化合物，其中A是萘基、蒽基、菲基、联苯基或三苯基基团，R是具有1-6个碳原子的烷基或具有五或六个碳原子的环烷基。这些1,3,5-三（芳基氨基）苯的氧化电位在约0.5-0.6V范围内，氧化还原过程中具有优异的可逆性和高玻璃转移温度，此外，它们能够在常温或更高温度下自行形成稳定耐久的非晶膜，用作高性能有机半导体，无需使用粘合剂树脂。
• 1,3,5-tris(arylamino)benzenes
  申请人：Bando Chemical Industries, Ltd.

  公开号：US07196224B2

  公开（公告）日：2007-03-27

  The invention provides 1,3,5-tris(arylamino)benzenes represented by the general formula (I) wherein A is naphthyl, anthryl, phenanthryl, biphenylyl or terphenylyl group, and R is alkyl having 1–6 carbon atoms or cycloalkyl group having five or six carbon atoms. The 1,3,5-tris(arylamino)benzenes have oxidation potentials in the range of about 0.5–0.6V, excellent reversibility in oxidation-reduction process and high glass transition temperatures and in addition, they are capable of forming stable and durable amorphous film useful as high performance organic semiconductors at normal temperatures or higher with no aid of binder resins, that is, by themselves.

  本发明提供了由通式（I）表示的1,3,5-三（芳基氨基）苯，其中A是萘基，蒽基，菲基，联苯基或三苯基基团，R是具有1-6个碳原子的烷基或具有五个或六个碳原子的环烷基。1,3,5-三（芳基氨基）苯的氧化电位在约0.5-0.6V范围内，具有优异的氧化还原过程可逆性和高玻璃化转变温度，并且它们能够在常温或更高温度下自行形成稳定耐久的非晶膜，可用作高性能有机半导体，无需使用粘合树脂。
• METHOD OF MAKING ELECTRET ARTICLES BASED ON ZETA POTENTIAL
  申请人：Sebastian John M.

  公开号：US20090293279A1

  公开（公告）日：2009-12-03

  A method of making an electret article, from a polymeric article that has a zeta potential of greater than or less than −7.5 millivolts. The article is charged by contacting it with an aqueous liquid that has a pH and conductivity as follows: (i) if the article has a zeta potential of −7.5 mV or less, then the contacting liquid has pH greater than 7 and a conductivity of 5 to 9,000 microSiemens per centimeter; and (ii) if the article has a zeta potential of greater than −7.5 mV, then the contacting liquid has a pH of 7 or less and a conductivity of 5 to 5,500 microSiemens per centimeter. An electret article made in this manner can provide improved electret performance, particularly in electret filtration articles.

  一种制造静电纤维的方法，使用具有大于或小于-7.5毫伏的ζ电位的聚合物纤维。将该纤维与具有以下pH和电导率的水性液体接触，以使纤维带电：（i）如果纤维的ζ电位小于或等于-7.5毫伏，则接触液体的pH大于7，电导率为5至9,000微西门子/厘米；（ii）如果纤维的ζ电位大于-7.5毫伏，则接触液体的pH为7或更低，电导率为5至5,500微西门子/厘米。使用这种方法制造的静电纤维可以提供改进的静电性能，特别是在静电过滤器中。
• ORGANO-ELECTRONIC FUNCTIONAL MATERIAL AND USE THEREOF
  申请人：Bando Chemical Industries, Ltd.

  公开号：EP1696709A1

  公开（公告）日：2006-08-30

  The invention provides an organo-electronic functional material comprising a tris(arylamino)benzene represented by the general formula (I) wherein A and B are each a group represented by the general formula (II) in which R is an alkyl group of 1-6 carbons or a cycloalkyl group of 5 or 6 carbon atoms and n is 0, 1, 2 or 3, and A and B may be the same or different from each other, and exhibiting a cyclic voltamogram in which a deviation of peak current of cyclic curves as measured 50 times at a sweep rate of 20 mV/s falls within ±10% of the average of peak current. The organo-electronic functional material has an opto-electronic exchanging function, a reversible oxidation-reduction property and a high glass transition temperature, and can form amorphous film in itself. In addition, it is stable and exhibits only slight variation of peak current in repeated oxidation-reduction process so that it is suitable for use as, for example, a hole transporting material among others in various electronic devices including an organic electroluminescence element.

  本发明提供了一种有机电子功能材料，包括通式 (I) 所代表的三(芳基氨基)苯 其中 A 和 B 分别为通式（II）所代表的基团 其中 R 是 1-6 个碳原子的烷基或 5 或 6 个碳原子的环烷基，n 是 0、1、2 或 3，A 和 B 可以相同或不同，并显示出循环伏安图，其中在 20 mV/s 的扫描速率下测量 50 次循环曲线的峰值电流偏差在峰值电流平均值的 ±10% 以内。 该有机电子功能材料具有光电交换功能、可逆氧化还原特性和较高的玻璃化转变温度，本身可形成无定形薄膜。此外，它还很稳定，在反复的氧化还原过程中峰值电流变化很小，因此适合用作各种电子设备（包括有机电致发光元件）中的空穴传输材料等。