1,4-bis(o-carbomethoxyphenoxymethyl)benzene | 66012-49-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(o-carbomethoxyphenoxymethyl)benzene
• 英文别名: Dimethyl 2,2'-[1,4-phenylenebis(methyleneoxy)]dibenzoate；methyl 2-[[4-[(2-methoxycarbonylphenoxy)methyl]phenyl]methoxy]benzoate
• CAS: 66012-49-5
• 化学式: C₂₄H₂₂O₆
• 分子量: 406.435
• InChiKey: PVOFWKCSYMMMRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  30
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,4-bis(o-carbomethoxyphenoxymethyl)benzene 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 以95%的产率得到2-[[4-[(2-Carboxyphenoxy)methyl]phenyl]methoxy]benzoic acid
  参考文献：
  名称：

  Synthesis, characterization and ion transportation studies of some novel cyclophane amides

  摘要：

  Various novel cyclophane amides with a large cavity have been synthesized. The structures of cyclophane amides 14 and 15 were resolved using XRD studies. Cyclophane amide 28 shows a shift in lambda(max) in the UV/Vis. spectra when treated with Cu (II) ion as well as with Ph(II) ion. Ion transportation studies were carried out with cyclophane amide 14 which proved that the Na+ ion passes through the cavity while K+ ions are retained. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.03.064
• 作为产物：
  描述：

  1,4-二(溴甲基)苯 、 水杨酸甲酯 在 potassium carbonate 、 potassium iodide 作用下， 以 乙腈 为溶剂， 反应 8.0h， 以90%的产率得到1,4-bis(o-carbomethoxyphenoxymethyl)benzene
  参考文献：
  名称：

  Synthesis, characterization and ion transportation studies of some novel cyclophane amides

  摘要：

  Various novel cyclophane amides with a large cavity have been synthesized. The structures of cyclophane amides 14 and 15 were resolved using XRD studies. Cyclophane amide 28 shows a shift in lambda(max) in the UV/Vis. spectra when treated with Cu (II) ion as well as with Ph(II) ion. Ion transportation studies were carried out with cyclophane amide 14 which proved that the Na+ ion passes through the cavity while K+ ions are retained. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.03.064

文献信息

• New compounds and their application
  申请人：Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo

  公开号：US04855482A1

  公开（公告）日：1989-08-08

  The present invention provides a novel bis(phenoxymethyl)benzene derivative or bis(naphthoxymethyl)benzene derivative, which improves the stability of image on a heat sensitive recording paper composed of a leuco dye and a developer.

  本发明提供了一种新颖的双(苯氧甲基)苯衍生物或双(萘氧甲基)苯衍生物，可以提高由变色染料和显影剂组成的热敏感记录纸上图像的稳定性。
• US4855482A
  申请人：——

  公开号：US4855482A

  公开（公告）日：1989-08-08
• US4894359A
  申请人：——

  公开号：US4894359A

  公开（公告）日：1990-01-16
• Synthesis, characterization and ion transportation studies of some novel cyclophane amides
  作者：Perumal Rajakumar、A. Mohammed Abdul Rasheed

  DOI：10.1016/j.tet.2005.03.064

  日期：2005.5

  Various novel cyclophane amides with a large cavity have been synthesized. The structures of cyclophane amides 14 and 15 were resolved using XRD studies. Cyclophane amide 28 shows a shift in lambda(max) in the UV/Vis. spectra when treated with Cu (II) ion as well as with Ph(II) ion. Ion transportation studies were carried out with cyclophane amide 14 which proved that the Na+ ion passes through the cavity while K+ ions are retained. (c) 2005 Elsevier Ltd. All rights reserved.