4-Dodecyloxybenzenethiol | 97412-69-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: 4-Dodecyloxybenzenethiol
• 英文别名: 4-Dodecoxybenzenethiol
• CAS: 97412-69-6
• 化学式: C₁₈H₃₀OS
• 分子量: 294.502
• InChiKey: YEMHFVOVKZFCCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  10.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-Dodecyloxybenzenethiol 、 1-Carboxyphenyl-4-decan-1'-one 生成
  参考文献：
  名称：

  Neubert, M. E.; Sharma, R. B.; Citano, C., Molecular Crystals and Liquid Crystals (1969-1991), 1991, vol. 196, p. 145 - 155

  摘要：

  DOI：
• 作为产物：
  描述：

  十二烷氧基苯 生成 4-Dodecyloxybenzenethiol
  参考文献：
  名称：

  Neubert, M. E.; Sharma, R. B.; Citano, C., Molecular Crystals and Liquid Crystals (1969-1991), 1991, vol. 196, p. 145 - 155

  摘要：

  DOI：

文献信息

• Novel sulfonyldiazomethanes, photoacid generations, resist compositions, and patterning process
  申请人：——

  公开号：US20030180653A1

  公开（公告）日：2003-09-25

  A chemical amplification type resist composition contains as a photoacid generator a sulfonyldiazomethane compound of formula (1) wherein R is H or C 1-4 alkyl or alkoxy, G is SO 2 or CO, R 3 is C 1-10 alkyl or C 6-14 aryl, p is 1 or 2, q is 0 or 1, p+q=2, n is 0 or 1, m is 3 to 11, and k is 0 to 4. The composition is suited for microfabrication, especially by deep UV lithography because of many advantages including improved resolution and improved pattern profile after development. 1

  一种化学放大型光刻胶组合物包含一种化学放大型光酸发生剂，其化学式为（1），其中R为H或C1-4烷基或烷氧基，G为SO2或CO，R3为C1-10烷基或C6-14芳基，p为1或2，q为0或1，p+q=2，n为0或1，m为3至11，k为0至4。该组合物适用于微细加工，尤其是通过深紫外光刻技术，因为具有许多优点，包括提高分辨率和在显影后改善图案轮廓。
• Color photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0127162A2

  公开（公告）日：1984-12-05

  A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having at least one layer containing at least one 2-equivalent magenta coupler of the 5-pyrazolone type represented by the following general formula (I): wherein W represents a phenyl group substituted with at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z represents a group capable of being released upon coupling, and at least one compound represented by the following general formula (II): wherein R' and RZ, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group, provided that both R' and R' do not represent hydrogen atoms atthe same time; Z' represents a methine group, a substituted methine group orthe group-N=; and Q represents an atomic group which contains a nitrogen atom, a sulfur atom or an oxygen atom and is necessary to form a 5-membered ora 6-membered heterocyclic ring together with the group-C=Z1-. The silver halide color photographic light-sensitive material can provide an excellent magenta color image without the occurrence of stain, even when the color photographic material is processed in a processing solution under the running condition.

  一种卤化银彩色感光材料，包括一个支撑体，该支撑体上涂覆有至少一层卤化银乳剂层，该彩色感光材料至少有一层含有至少一种由以下通式(I)表示的5-吡唑酮型2当量品红耦合剂： 其中 W 代表至少一个被选自卤素原子、烷基、烷氧基、烷氧羰基和氰基的取代基取代的苯基；Y 代表酰氨基或苯胺基；Z 代表在偶联时能被释放的基团，以及至少一种由下式通式（II）代表的化合物： 其中 R' 和 RZ 可以相同或不同，各自代表氢原子、烷基或芳基，但 R' 和 R' 不能同时代表氢原子；Z' 代表甲基、取代的甲基或基团-N=；Q 代表含有氮原子、硫原子或氧原子的原子团，必须与基团-C=Z1-一起形成 5 元或 6 元杂环。 这种卤化银彩色感光材料可以提供极佳的品红色图像，即使在运行状态下用冲洗液冲洗彩色感光材料，也不会出现染色现象。
• Color light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0351860A2

  公开（公告）日：1990-01-24

  A color light-sensitive material comprising a support having provided thereon a light-sensitive silver halide, a binder, a reducible dye donating compound, and at least one reducing agent selected from the group consisting of a compound represented by formula (IA) and a compound represented by formula (IB): wherein R1, R2, R3, R4, R5, and R6, wihch may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxy group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acryl group, a substituted or unsubstituted sulfonyl group, a substituted or unsubstituted carbamoyl group, or a substituted or unsubstituted sulfamoyl group, provided that at least one of R1 and R3 and at least one of R4 and R6 represent a hydroxyl group; or any adjacent two of R1, R2, R3, R4, R5, and R6 are connected to each other to form a carbocyclic ring; X represents a divalent linking group; and t represents 0 or 1; wherein R" and R12, wihch may be the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acyl group, a substituted or unsubstituted sulfonyl group, a substituted or unsubstituted carbamoyl group, or a substituted or unsubstituted sulfamoyl group, or R" and R12 are taken together to form a carbocyclic ring; R13 represents an unsubstituted or alkyl-substituted alkylene group; R14, R15, R16, R17, and R18, wihch may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted amino group, a substituted or unsubstituted acyl group, a substituted or unsubstituted acyloxy group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted carbamoylamino group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted sulfamoylamino group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryloxycarbonyl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkoxysulfonyl group, or a substituted or unsubstituted aryloxysulfonyl group; R14, R15, and R16 each may further represent a hydroxyl group; or any adjacent two of R14, R15, R16, R17, and R18 are connected to each other to form a carbocyclic or heterocyclic ring; X represents -CO- or -S02-; m and n each represents 0 or 1; and the total number of carbon atoms in R", R12, R'3, R14, R15, R'6, R17, and R'8 is 8 or more.

  一种彩色光敏材料，包括在其上提供有光敏卤化银的支持物、粘合剂、可还原染料捐赠化合物和至少一种选自由式(IA)代表的化合物和由式(IB)代表的化合物组成的组的还原剂： 其中 R1、R2、R3、R4、R5 和 R6 可以相同或不同，各自代表氢原子、卤素原子、羟基、取代或未取代的烷基、取代或未取代的芳基、取代或未取代的酰氨基、取代或未取代的烷氧基、取代或未取代的芳氧基、取代或未取代的烷硫基、取代或未取代的芳硫基、取代或未取代的丙烯基、取代或未取代的磺酰基、取代或未取代的氨基甲酰基或取代或未取代的氨基磺酰基，条件是 R1 和 R3 中的至少一个以及 R4 和 R6 中的至少一个代表羟基；或 R1、R2、R3、R4、R5 和 R6 中任意相邻的两个相互连接形成碳环；X 代表二价连接基团；t 代表 0 或 1； 其中 R "和 R12 可以相同或不同，各自代表氢原子、卤素原子、取代或未取代的烷基、取代或未取代的芳基、取代或未取代的酰氨基、取代或未取代的烷氧基、取代或未取代的芳氧基、取代或未取代的烷硫基、取代或未取代的芳硫基、取代或未取代的酰基、取代或未取代的磺酰基、取代或未取代的氨基甲酰基或取代或未取代的氨基磺酰基，或 R "和 R12 共同形成碳环；R13 代表未取代或烷基取代的亚烷基；R14、R15、R16、R17 和 R18 可以相同或不同，各自代表氢原子、卤素原子、氰基、硝基、取代或未取代的烷基、取代或未取代的酰氨基、取代或未取代的磺酰胺基、取代或未取代的烷氧基、取代或未取代的芳氧基、取代或未取代的烷硫基、取代或未取代的芳硫基、取代或未取代的氨基、取代或未取代的酰基、一个取代或未取代的酰氧基， 一个取代或未取代的氨基甲酰基， 一个取代或未取代的氨基甲酰胺基， 一个取代或未取代的氨基磺酰基， 一个取代或未取代的氨基磺酰胺基、取代或未取代的烷氧羰基、取代或未取代的芳氧羰基、取代或未取代的杂环基、取代或未取代的烷氧基磺酰基或取代或未取代的芳氧基磺酰基；R14、R15 和 R16 可各自进一步代表羟基；或 R14、R15、R16、R17 和 R18 中任意相邻的两个相互连接以形成碳环或杂环；X 代表 -CO- 或 -S02-；m 和 n 各自代表 0 或 1；且 R"、R12、R'3、R14、R15、R'6、R17 和 R'8 中的碳原子总数为 8 或更多。
• Diffusion transfer type silver halide photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0559048A1

  公开（公告）日：1993-09-08

  A diffusion transfer type silver halide photographic light-sensitive material contains a dye-providing compound having a dye portion temporarily shifted to a shorter wavelength. The light-sensitive material contains the dye-providing compound represented by the following Formula (I):         REDOX-NuP-E-G-Dye'   (I) wherein G represents an auxochrome of a dye; Dye' represents a group of atoms which remains after the auxochrome is removed from the dye; -G-Dye' represents a group of atoms which is converted to a diffusible dye by cleavage of the bond between G and E; REDOX represents an oxidative group or a reductive group which allows the bond between REDOX-NuP to be cleaved by an oxidation-reduction reaction; NuP represents a nucleophilic group which is released by a bond cleavage reaction between REDOX and NuP triggered by the oxidation-reduction reaction; E represents an electrophilic group which will react with the nucleophilic group NuP and cause the bond between G and E to be cleaved; and REDOX-NuP-E provides the compound represented by Formula (I) with a diffusibility.

  一种扩散转移型卤化银感光材料含有一种染料提供化合物，其染料部分暂时转移到较短的波长。该感光材料含有由下式（I）表示的染料提供化合物： REDOX-NuP-E-G-Dye' (I) 其中，G 代表染料的辅助色素；Dye' 代表从染料中去除辅助色素后残留的原子团；-G-Dye' 代表通过裂解 G 和 E 之间的键而转化为可扩散染料的原子团；REDOX 代表氧化基团或还原基团，可通过氧化还原反应裂解 REDOX-NuP 之间的键；NuP 代表亲核基团，通过由氧化还原反应引发的 REDOX 与 NuP 之间的键裂解反应释放出来；E 代表亲电基团，将与亲核基团 NuP 反应并导致 G 与 E 之间的键裂解；REDOX-NuP-E 可提供具有扩散性的式 (I) 所代表的化合物。
• Photographic coupler and silver halide color photographic material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0571959A2

  公开（公告）日：1993-12-01

  A 1H-pyrazolo[1,5-b][1,2,4]triazole magenta coupler having a t-alkyl group at the position-6 and an amido group-substituted phenyl group at the position-2 is disclosed. There is also disclosed a silver halide color photographic material containing the same.

  本发明公开了一种 1H-吡唑并[1,5-b][1,2,4]三唑品红色耦合剂，其第 6 位是一个 t-烷基，第 2 位是一个氨基取代的苯基。此外，还公开了一种含有相同成分的卤化银彩色感光材料。