| 100293-84-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 100293-84-3
• 化学式: C₂H₄CoNO₂
• 分子量: 133.052
• InChiKey: XXZJUHLVAZTNAC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.31
• 重原子数：
  6.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  66.15
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  N-benzenesulphonyl-l-cysteine 、 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Mukherjee; Ghosh, Journal of the Indian Chemical Society, 1997, vol. 74, # 1, p. 8 - 11

  摘要：

  DOI：

文献信息

• Method for preparation of metal organic acid chelates
  申请人：JH Biotech, Inc.

  公开号：EP1529775B1

  公开（公告）日：2006-04-19
• Nature of the metal(II) complexes formed in the reactions of formaldehyde with the bis(glycinato) complexes of nickel(II), cobalt(II) and copper(II) at pH 4.5
  作者：So'on-Beng Teo、Siang-Guan Teoh

  DOI：10.1016/s0020-1693(00)81775-2

  日期：1984.2
• Tikhonov, V. P., Koordinatsionnaya Khimiya, 1991, vol. 17, p. 581 - 587
  作者：Tikhonov, V. P.

  DOI：——

  日期：——
• Vasil'ev, V. P.; Zaitseva, G. A., Russian Journal of Inorganic Chemistry, 1989, vol. 34, p. 1761 - 1763
  作者：Vasil'ev, V. P.、Zaitseva, G. A.

  DOI：——

  日期：——
• Physical Grinding of Prefabricated Co3O4 and MCM-22 Zeolite for Fischer–Tropsch Synthesis: Impact of Pretreatment Procedure on the Dispersion and Catalytic Performance
  作者：Hua-Ping Ren、Zhi-Xia Xie、Shao-Peng Tian、Si-Yi Ding、Qiang Ma、Yu-Zhen Zhao、Zhe Zhang、Jiao-Jiao Fu、Qing-Qing Hao

  DOI：10.3390/molecules29061283

  日期：——

  To improve the mess-specific activity of Co supported on zeolite catalysts in Fischer–Tropsch (FT) synthesis, the Co-MCM-22 catalyst was prepared by simply grinding the MCM-22 with nanosized Co3O4 prefabricated by the thermal decomposition of the Co(II)-glycine complex. It is found that this novel strategy is effective for improving the mess-specific activity of Co catalysts in FT synthesis compared to the impregnation method. Moreover, the ion exchange and calcination sequence of MCM-22 has a significant influence on the dispersion, particle size distribution, and reduction degree of Co. The Co-MCM-22 prepared by the physical grinding of prefabricated Co3O4 and H+-type MCM-22 without a further calcination process exhibits a moderate interaction between Co3O4 and MCM-22, which results in the higher reduction degree, higher dispersion, and higher mess-specific activity of Co. Thus, the newly developed method is more controllable and promising for the synthesis of metal-supported catalysts.