bis(6-pyrrolidinonaphthal-2-yl)ketone | 860265-35-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(6-pyrrolidinonaphthal-2-yl)ketone
• 英文别名: Bis(6-pyrrolidin-1-ylnaphthalen-2-yl)methanone；bis(6-pyrrolidin-1-ylnaphthalen-2-yl)methanone
• CAS: 860265-35-6
• 化学式: C₂₉H₂₈N₂O
• 分子量: 420.554
• InChiKey: XHLPCGBZVWLCLD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bis(6-pyrrolidinonaphthal-2-yl)ketone 、 N-对溴苯吡咯烷 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 4.5h， 生成
  参考文献：
  名称：

  Synthesis and spectral characterization of bisnaphthylmethyl and trinaphthylmethyl cations

  摘要：

  Cationic triarylmethane dyes containing one, two or three naphthalene moieties have been prepared. Their synthesis and preliminary spectral, nonlinear optical and theoretical characterization tire reported here. The major electronic and steric hindrance effects of the 1.4-linked naphthalene have been examined by comparison of the UV-vis absorption of the 1,4-linked and 2,6-linked series. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.05.138
• 作为产物：
  描述：

  6-溴-2-氨基萘 在 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 正己烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 72.5h， 生成 bis(6-pyrrolidinonaphthal-2-yl)ketone
  参考文献：
  名称：

  Synthesis and spectral characterization of bisnaphthylmethyl and trinaphthylmethyl cations

  摘要：

  Cationic triarylmethane dyes containing one, two or three naphthalene moieties have been prepared. Their synthesis and preliminary spectral, nonlinear optical and theoretical characterization tire reported here. The major electronic and steric hindrance effects of the 1.4-linked naphthalene have been examined by comparison of the UV-vis absorption of the 1,4-linked and 2,6-linked series. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.05.138

文献信息

• Synthesis and spectral characterization of bisnaphthylmethyl and trinaphthylmethyl cations
  作者：Lionel Sanguinet、Robert J. Twieg、Greg Wiggers、Guilin Mao、Kenneth D. Singer、Rolfe G. Petschek

  DOI：10.1016/j.tetlet.2005.05.138

  日期：2005.8

  Cationic triarylmethane dyes containing one, two or three naphthalene moieties have been prepared. Their synthesis and preliminary spectral, nonlinear optical and theoretical characterization tire reported here. The major electronic and steric hindrance effects of the 1.4-linked naphthalene have been examined by comparison of the UV-vis absorption of the 1,4-linked and 2,6-linked series. (c) 2005 Elsevier Ltd. All rights reserved.