5,5,6-trifluoro-6-(trifluoromethyl)bicyclo[2.2.1]hept-2-ene | 426-08-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 5,5,6-trifluoro-6-(trifluoromethyl)bicyclo[2.2.1]hept-2-ene
• 英文别名: 5-trifluoromethyl-5,6,6-trifluorobicyclo[2,2,1]hept-2-ene；2,2,3-Trifluor-3-trifluormethyl-bicyclo<2.2.1>hepten-(5)；2,2,3-Trifluor-3-trifluormethyl-bicyclo[2.2.1]hepten-(5)
• CAS: 426-08-4
• 化学式: C₈H₆F₆
• 分子量: 216.126
• InChiKey: RNVJDIGFTGLKCE-UHFFFAOYSA-N

物化性质

• 沸点：
  140-140.5 °C
• 密度：
  1.4066 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5,5,6-trifluoro-6-(trifluoromethyl)bicyclo[2.2.1]hept-2-ene 在 镍 氢气 作用下， 以 乙醇 为溶剂， 生成 5,5,6-trifluoro-6-trifluoromethylnorbornene
  参考文献：
  名称：

  Stereochemistry of the Diels-Alder Reaction. IV. Adducts between Cyclopentadiene and Fluorinated Olefins

  摘要：

  DOI：

  10.1021/ja00870a023
• 作为产物：
  描述：

  六氟丙烯 、 环戊二烯 在 对苯二酚 作用下， 生成 5,5,6-trifluoro-6-(trifluoromethyl)bicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  Stereochemistry of the Diels-Alder Reaction. IV. Adducts between Cyclopentadiene and Fluorinated Olefins

  摘要：

  DOI：

  10.1021/ja00870a023

文献信息

• Polycyclic fluoroalkanes
  申请人：E. I du Pont de Nemours and Company

  公开号：US07084314B1

  公开（公告）日：2006-08-01

  Polycyclic fluoroalkanes that are highly transparent to UV wavelengths ranging from about 190 nm to 260 nm are provided. The polycyclic fluoroallkanes are suitable for use in a variety of applications, particularly in the vacuum UV and deep UV region of the electromagnetic spectrum. For example, the polycyclic fluoroalkanes are useful in optical couplants, optical cements, optical elements, optical inspection media for semiconductor wafers and devices, and immersion photolithography, particularly at 193 and 248 nm exposure wavelength.

  提供了对紫外波长范围从约190纳米到260纳米高度透明的多环氟烷。这些多环氟烷适用于各种应用，特别是在电磁波谱的真空紫外和深紫外区域。例如，这些多环氟烷在光学耦合剂、光学水泥、光学元件、半导体晶圆和器件的光学检测介质以及浸没光刻等方面非常有用，特别是在193和248纳米的曝光波长下。
• Processes for preparing high purity polycyclic fluoroalkanes
  申请人：E. I. du Pont de Nemours and Company

  公开号：US07078575B1

  公开（公告）日：2006-07-18

  Processes for preparing high purity polycyclic fluoroalkanes are provided. The polycyclic fluoroalkanes are useful as solvents, cleaning agents, heat transfer fluids, refrigerants, lubricants, and, in a preferred embodiment, by virtue of high refractive index and high transparency to UV wavelengths, optical applications in the vacuum ultraviolet (VUV).

  提供了制备高纯度多环氟烷的过程。多环氟烷可用作溶剂、清洁剂、传热流体、制冷剂、润滑剂，而在首选实施例中，由于其高折射率和对紫外波长的高透明度，可用于真空紫外光学应用。
• Thermoplastic norbornene resin based optical film
  申请人：——

  公开号：US20040242823A1

  公开（公告）日：2004-12-02

  An optical film is provided, which displays a positive wavelength dependency across the entire wavelength region from 400 to 800 nm, and is capable of imparting a specified retardation to transmitted light with a single sheet of film. The optical film particularly, includes a thermoplastic norbornene-based resin with a specified structure formed of a structural unit (I) which imparts a positive birefringence and a structural unit (II) which imparts a negative birefringence, and which satisfies particular conditions with respect to &Dgr;N I (&lgr;), &Dgr;N II (&lgr;), &Dgr;N I (800) and &Dgr;N II (800) wherein &Dgr;N I (&lgr;) and &Dgr;N II (&lgr;) represent the difference between a refractive index Nx(&lgr;) in an x axis direction at a wavelength &lgr;, and a refractive index Ny(s) in a y axis direction, and &Dgr;N I (800) and &Dgr;N II (800) represent the difference in refractive indexes at a wavelength of 800 nm, and the x axis represents the stretching direction and the y axis represents the in-plane direction perpendicular to the x direction.

  提供了一种光学薄膜，其在整个波长范围从400到800纳米内显示正波长依赖性，并能够通过单张薄膜赋予传输光以指定的延迟。该光学薄膜特别包括一种热塑性诺本烯基树脂，其具有特定的结构，由赋予正双折射的结构单元（I）和赋予负双折射的结构单元（II）组成，并满足与&Dgr;NI(&lgr;)、&Dgr;NII(&lgr;)、&Dgr;NI(800)和&Dgr;NII(800)相关的特定条件，其中&Dgr;NI(&lgr;)和&Dgr;NII(&lgr;)表示在波长&lgr;处x轴方向上的折射率Nx(&lgr;)与y轴方向上的折射率Ny(s)之间的差异，而&Dgr;NI(800)和&Dgr;NII(800)表示在波长为800纳米时的折射率差异，其中x轴代表拉伸方向，y轴代表垂直于x方向的平面方向。
• Method for producing an olefin type copolymer having a cyclic structure
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20020058767A1

  公开（公告）日：2002-05-16

  A method for producing an olefin type copolymer having a cyclic structure, which comprises copolymerizing ethylene (M1) and dicyclopentadiene or tricyclopentadiene (M2), and, as optionally introduced, a cyclic olefin (M3), wherein, as a catalyst, a catalyst comprising a metallocene compound (A) of the following formula [1]: H 2 C(R′ m CP)(R″ n Cp)Mx 2 [1] wherein M is zirconium or hafnium, Cp is a group having a cyclopentadienyl skeleton, each of R′ and R″ is a hydrocarbon group having 1 to 10 carbon atoms, each of two X's which may be the same or different from each other, is a halogen atom, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkylamino group, an alkoxy group, an aryloxy group of the formula —O—Ar—Y p (wherein Ar is an aromatic ring, Y is a halogen atom, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkoxy group, an alkylamino group, a cyano group or a nitro group, and p is an integer of from 1 to 5), a thioalkyl group, or a thioaryl group of the formula —S—Ar—Y p (wherein Ar, Y and p are as defined above), and each of m and n is an integer of from 0 to 4, provided that m and n are not equal, and m+n is an integer of from 3 to 6, and an aluminoxane (B), is used.

  一种制备具有环状结构的烯烃共聚物的方法，包括共聚乙烯（M1）和二环戊二烯或三环戊二烯（M2），以及作为可选引入的环状烯烃（M3），其中，作为催化剂使用以下式子（1）的金属茂化合物（A）：H2C(R′mCP)(R″nCp)Mx2（1），其中M为锆或铪，Cp为具有环戊二烯基骨架的基团，R′和R″各自为具有1至10个碳原子的碳氢基团，两个X可以相同也可以不同，是卤素原子、氢原子、具有1至20个碳原子的碳氢基团、卤代碳氢基团、烷基氨基基团、烷氧基、苯氧基（式中Ar为芳香环，Y为卤素原子、氢原子、具有1至20个碳原子的碳氢基团、卤代碳氢基团、烷氧基、烷基氨基基团、氰基或硝基，p为1至5的整数），硫代烷基团或硫代芳基团（式中Ar、Y和p如上所述），m和n各自为0至4的整数，但m和n不相等，且m+n为3至6的整数，并使用铝烷氧化物（B）。
• POLYMERIZABLE COMPOSITION, CYCLOOLEFIN-BASED POLYMER, CYCLOOLEFIN-BASED RESIN MOLDED BODY, AND LAMINATE
  申请人：ZEON CORPORATION

  公开号：US20160002490A1

  公开（公告）日：2016-01-07

  The present invention pertains to: a polymerizable composition comprising a cycloolefin-based monomer represented by a formula (I), and a polymerization catalyst, wherein R 1 is a hydrocarbon group having 1 to 10 carbon atoms, a halogen atom, etc, m is an integer from 0 to 6n+6, and n is an integer from 1 to 3. As a result of the present invention, a polymerizable composition that is useful as a material for producing a cycloolefin-based resin formed article that exhibits excellent adhesion to a metal, a cycloolefin-based polymer obtained from the polymerizable composition, a cycloolefin-based resin formed article, and a laminate that includes a metal foil and a cycloolefin-based resin layer that is situated adjacent to the metal foil are provided.

  本发明涉及一种聚合物组合物，包括一种由式(I)表示的环氧烷基单体和一种聚合催化剂，其中R1是具有1至10个碳原子的烃基、卤素原子等，m是0至6n+6的整数，n是1至3的整数。本发明提供了一种聚合物组合物，可用作制备表现出对金属优异粘附性的环氧烷基树脂成型品的材料，以及由该聚合物组合物得到的环氧烷基聚合物、环氧烷基树脂成型品和包括金属箔和靠近金属箔的环氧烷基树脂层的层压板。