dimethylaluminum isopropoxide | 6063-89-4

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机铝
• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: dimethylaluminum isopropoxide
• 英文别名: Dimethyl-aluminium-isopropylat；AlMe2(O(i)Pr)；aluminium dimethylisopropoxide；dimethylalumanylium;propan-2-olate
• CAS: 6063-89-4
• 化学式: C₅H₁₃AlO
• 分子量: 116.139
• InChiKey: HJYACKPVJCHPFH-UHFFFAOYSA-N

物化性质

• 沸点：
  186 °C
• 密度：
  0.824 g/mL at 25 °C
• 闪点：
  5°C (41°F)
• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  1.66
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 危险品标志：
  F+
• 安全说明：
  S43
• 危险类别码：
  R12,R14/15
• 海关编码：
  2915900090
• 危险品运输编号：
  UN 3399 4.3/PG 1
• 储存条件：
  存放于阴凉干燥处。

反应信息

• 作为反应物：
  描述：

  dimethylaluminum isopropoxide 以 neat (no solvent) 为溶剂， 生成 aluminum oxide
  参考文献：
  名称：

  Chemical, morphological and nano-mechanical characterizations of Al2O3 thin films deposited by metal organic chemical vapour deposition on AISI 304 stainless steel

  摘要：

  Amorphous alumina coatings of different thickness have been deposited on AISI 304 stainless steel substrates by MOCVD in a hot wall reactor at 380 degrees C under O-2/H2O atmosphere. The used aluminium precursor was the high volatile and easy to prepare dimethyl-aluminum-isopropoxide. Selected films were annealed in N-2 and O-2 atmosphere at 500 and 700 degrees C to evaluate the effects of the thermal treatments on the morphology and on the nano-mechanical properties of the coatings. X-ray diffraction and Rutherford backscattering spectroscopy measurements indicated that both the as grown and annealed films were amorphous and very pure with the correct Al2O3 stoichiometry. The surface morphology, investigated by atomic force microscopy, was free of cracks with a roughness of the films that increases with deposition time and with annealing in oxygen atmosphere. The hardness and the elastic modulus of the films and of the AISI 304 stainless steel substrate were measured by load-depth nano-indentation tests. The results highlighted a significant increase in the Berkovich hardness of the coated samples compared to that of the bulk AISI 304 stainless steel. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2004.10.097

文献信息

• Chiral (1,2)-Diphenylethylene-Salen Complexes of Triel Metals: Coordination Patterns and Mechanistic Considerations in the Isoselective ROP of Lactide
  作者：Nicolas Maudoux、Thierry Roisnel、Vincent Dorcet、Jean-François Carpentier、Yann Sarazin

  DOI：10.1002/chem.201304788

  日期：2014.5.12

  All these alkyl complexes, as well as the [AlOiPr(ONNO)] derivatives, catalyse the ring‐opening polymerisation (ROP) of racemic lactide (rac‐LA). The [AlMe(ONNO)] complexes require additional alcohol to afford controlled reactions, but [AlOiPr(ONNO)] complexes are single‐component catalysts for the isoselective ROP of rac‐LA, with values of Pm in the range 0.80–0.90. Experimental evidence unexpectedly

  手性（R，R）-（HH ONNO HH）（1），（R，R）-（MeH ONNO HMe）（2），（R，R）-支持的对映体纯铝，镓和铟配合物的合成（吨卜吨卜ONNO吨卜吨卜）（3），（[R ，- [R ）- （MeNO2 ONNO MeNO2）（4），（- [R ，- [R） - （HOMe来ONNO HOMe来）（5）和（- [R ，- [R ） - （CLCL ONNO CLCL）（6）（1,2）-diphenylethylene沙仑配体进行说明。这些配合物中的几种已经通过晶体学鉴定，这突出了配位模式的多样性。而所有Ga络合物均形成[Ga 2（CH 2 SiMe 3）4（ONNO）]双金属物质（ONNO = 1 – 3），铝[AlR（ONNO）]（R = Me，CH 2 SiMe 3）和铟[In （CH 2 SiMe 3）（ONNO）]衍生物是单金属为ONNO = 1，2和4 - 6，并且仅形成所述双金属配合物[铝2
• Aluminum Complexes of Fluorinated β-Diketonate Ligands: Syntheses, Structures, Intramolecular Reduction, and Use in Ring-Opening Polymerization of Lactide
  作者：Miloud Bouyahyi、Thierry Roisnel、Jean-François Carpentier

  DOI：10.1021/om9009312

  日期：2010.1.25

  of pro-ligands (acacR1,R2)H (R1 = R2 = CF3, “(hfacac)H”; R1 = CF3, R2 = tBu) with 0.5 equiv of AlMe3 or AlMe2Cl systematically yielded the corresponding homoleptic complexes Al(hfacac)3 (1) and Al(acacCF3,tBu)3 (2). Compound 2 exists in CD2Cl2 solution as a mixture of fac- and mer-isomers. Heteroleptic complexes [Al(acacR1,R2)2(OiPr)]n (R1 = R2 = CF3, 3; R1 = CF3, R2 = tBu, 4) were cleanly prepared from

  已经研究了由氟化β-二酮酸酯配体支撑的杂配Al络合物的途径。原配体（acac R1，R2）H（R 1 = R 2 = CF 3，“（（hfacac）H”； R 1 = CF 3，R 2 = t Bu））与0.5当量的AlMe 3或AlMe 2的反应Cl系统地产生相应的均相络合物Al（hfacac）3（1）和Al（acac CF3，t Bu）3（2）。化合物2存在于CD 2 Cl 2中溶液作为混合物FAC -和聚体异构体。杂络合物[铝（ACAC R1，R2）2（O我PR）] Ñ（R 1 = R 2 = CF 3，3 ; R 1 = CF 3，R 2 =吨卜，4）被干净地从反应制备相应的（acac R 1，R 2）H原配体和0.5当量的AlMe 2（O i Pr）。（hfacac）H与0.5当量的Al（O i Pr）3的反应在室温下，得到3由其他制品，污染的其中[κ 2：μ 2 - （hfacac）5（O我PR）4的Al
• Ring‐opening polymerization of <i>rac</i> ‐lactide catalyzed by Al(III) and Zn(II) complexes incorporating Schiff base ligands derived from pyrrole‐2‐carboxaldehyde
  作者：Ernesto Rufino‐Felipe、Nazario Lopez、Fabio A. Vengoechea‐Gómez、Luis‐Guillermo Guerrero‐Ramírez、Miguel‐Ángel Muñoz‐Hernández

  DOI：10.1002/aoc.4315

  日期：2018.6

  series of Al(III) chloride [LAl‐Cl]; Al(III) alkoxide [LAl‐OR]2; and Zn(II) [LZn]2 complexes with Schiff base ligands were obtained. 1H NMR and X‐ray diffraction studies indicate that [LAl‐Cl] complexes have Cs symmetry and the Al center is penta‐coordinated. The Al(III) alkoxide complex [L5Al‐OiPr]2 is a dimer bridged by OiPr− with the Al center in a distorted octahedral environment. Zn complexes [LZn]2

  一系列的氯化铝（LAl-Cl）；Al（III）醇盐[LAl-OR] 2；得到具有席夫碱配体的Zn（II）[LZn] 2配合物。1 H NMR和X射线衍射研究表明[LAl-Cl]配合物具有C s对称性，且Al中心是五配位的。所述Al（III）醇盐络合物[L 5的Al-O我镨] 2是二聚体桥接被O我镨-与一个扭曲的八面体环境所述Al中心。锌配合物[LZn] 2是具有四配位Zn中心的双螺旋二聚体。rac开环聚合的催化活性对丙交酯进行了评估。该系列中活性最好的是带有柔性三碳桥的氯化铝配合物。更灵活的四碳桥降低了活动性。
• Discrete <i>O</i>-Lactate and β-Alkoxybutyrate Aluminum Pyridine–Bis(naphtholate) Complexes: Models for Mechanistic Investigations in the Ring-Opening Polymerization of Lactides and β-Lactones
  作者：Joice S. Klitzke、Thierry Roisnel、Evgeny Kirillov、Osvaldo de L. Casagrande、Jean-François Carpentier

  DOI：10.1021/om401214q

  日期：2014.10.27

  Methyl aluminum(III) complexes ONOSiR3}AlMe (SiR3 = SiPh3 (2a), SiMe2tBu (2b)) were synthesized by reaction of AlMe3 with pyridine–bis(naphthol) proligands ONOSiR3}H2 (1a,b) having bulky o-SiR3 substituents on the naphthol groups. Complexes 2a,b were converted into the Al isopropoxide, O-lactate, and β-alkoxybutyrate complexes ONOSiR3}AlOR′ (R′ = iPr (3a), (S)-CH(Me)CO2iPr (4a,b), (R)-CH(Me)CH2CO2Me

  甲基铝（III）络合物ONO SIR3 }阿尔梅（SIR 3 = SIPH 3（图2a），森2吨BU（图2b））通过阿尔梅的反应合成3用吡啶-双（萘酚）前配体ONO SIR3 }ħ 2（1a，b）在萘酚基团上具有庞大的o- SiR 3取代基。络合物图2a，b被转换成铝，异丙醇Ó乳酸盐，和β-alkoxybutyrate络合物ONO SIR3 }阿洛'（R'=我PR（3a），（S）-CH（Me）CO 2 i Pr（4a，b），（R）-CH（Me）CH 2 CO 2 Me（5a），rac -CH（CF 3）CH 2 CO 2 Et （6a））通过与相应的醇以及α-和β-羟基酯R'OH反应。X射线衍射研究表明，SiPh 3苯基与次甲基，亚甲基和烷基酯基团的氢之间存在C– H ···π紧密接触（对于2a和4a – 6a））并通过溶液NMR进行分析。与（S）-4b的情况相反，在20°C下，（S）-4a与外消旋丙交酯（rac
• Process for preparing a limo2 type heterometallic oxide film
  申请人：Korea Research Institute of Chemical Technology

  公开号：US06409830B1

  公开（公告）日：2002-06-25

  An organometallic compound of formula LiOR′.(R′O)MR2 is vaporized at a low temperature and employed in a CVD process of a heterometallic oxide film of the LiMO2 type, wherein M is a Group 13 element such as Al or Ga; R is a C1-10 alkyl group; and R′ is a C2-10 alkyl group.

  一种化学物质的化学式为LiOR′.(R′O)MR2，其中M代表13族元素如铝或镓，R代表C1-10烷基，R′代表C2-10烷基，该化学物质在低温下被蒸发并用于制备LiMO2型异金属氧化物薄膜的化学气相沉积过程。