N,N'-dithiobis(diisopropylamine) | 51981-26-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-dithiobis(diisopropylamine)
• 英文别名: Bisdisulfid；Bis(diisopropylamino)-disulfid；Bis(diisopropylamino)disulfid；N,N'-Disulfanediylbis[N-(propan-2-yl)propan-2-amine]；N-[[di(propan-2-yl)amino]disulfanyl]-N-propan-2-ylpropan-2-amine
• CAS: 51981-26-1
• 化学式: C₁₂H₂₈N₂S₂
• 分子量: 264.5
• InChiKey: QQNBEFPPTZBSMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  57.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  邻苯二甲酸亚胺 、 bis(1-methylethyl)-amidosulfenyl chloride 、 N,N'-dithiobis(diisopropylamine) 在 氯 、 三乙胺 作用下， 以 四氢呋喃 、 四氯化碳 、 sodium hydroxide 、 正己烷 、 水 为溶剂， 以64.5 grams (45.6%)的产率得到n-(diisopropylaminothio)-phthalimide
  参考文献：
  名称：

  N,N'-bisimidothio-diamines

  摘要：

  N-(吗啉硫基)邻苯二甲酰亚胺等亚胺类化合物被用来影响硫硫化可硫化聚合物的硫化特性，通过增加硫化程度和/或改善爆裂抗性和/或增加硫化速率。

  公开号：

  US03944552A1
• 作为产物：
  描述：

  二异丙胺 在 二氯化二硫 作用下， 生成 N,N'-dithiobis(diisopropylamine)
  参考文献：
  名称：

  Nitrogen-centered free radicals. IX. The ease of formation of thionitroxide radicals

  摘要：

  DOI：

  10.1021/ja00418a031

文献信息

• Self-healing coatings for oil and gas applications
  申请人：Chilukuri Anusha

  公开号：US10316413B2

  公开（公告）日：2019-06-11

  A coated article comprises a substrate and a self-healing coating disposed on a surface of the substrate, the self-healing coating comprising a metallic matrix; and a plurality of micro- or nano-sized particles dispersed in the metallic matrix; the micro- or nano-sized particles comprising an active agent disposed in a carrier comprising a micro- or nano-sized metallic container, a layered structure, a porous structure, or a combination comprising at least one of the foregoing.

  一种涂层制品包括基底和设置在基底表面的自愈合涂层，自愈合涂层包括金属基质；以及分散在金属基质中的多个微米级或纳米级颗粒；微米级或纳米级颗粒包括设置在载体中的活性剂，载体包括微米级或纳米级金属容器、分层结构、多孔结构或包括上述至少一种结构的组合。
• Organoaminosilanes and methods for making same
  申请人：Versum Materials US, LLC

  公开号：US10294250B2

  公开（公告）日：2019-05-21

  Organoaminosilanes, such as without limitation di-iso-propylaminosilane (DIPAS), are precursors for the deposition of silicon containing films such as silicon-oxide and silicon-nitride films. Described herein are methods to make organoaminosilane compounds, or other compounds such as organoaminodisilanes and organoaminocarbosilanes, via the catalytic hydrosilylation of an imine by a silicon source comprising a hydridosilane.

  有机氨基硅烷，例如但不限于二异丙氨基硅烷（DIPAS），是沉积氧化硅和氮化硅薄膜等含硅薄膜的前体。本文描述了通过包含氢基硅烷的硅源对亚胺进行催化氢硅烷化来制造有机氨基硅烷化合物或其他化合物如有机氨基二硅烷和有机氨基碳硅烷的方法。
• Synthesis and antimicrobial activities of structurally novel S,S′-bis(heterosubstituted) disulfides
  作者：Praveen Ramaraju、Danielle Gergeres、Edward Turos、Sonja Dickey、Daniel V. Lim、John Thomas、Burt Anderson

  DOI：10.1016/j.bmcl.2012.04.056

  日期：2012.6

  The central focus of this study is on the antibacterial and antifungal properties of synthetically produced S,S'-bis(heterosubstituted) disulfides as a means to control the growth of various infection-causing pathogens. Staphylococcus aureus, Francisella tularensis and Candida albicans were each found to be highly susceptible to several of these compounds by agar or broth dilution and Kirby-Bauer diffusion assays. These structurally simple, low molecular weight disulfides have shown promising bioactivities and may serve as leads to the development of effective new antibacterials for pathogenic bacteria such as methicillinresistant S. aureus and F. tularensis. (C) 2012 Elsevier Ltd. All rights reserved.
• SELF-HEALING COATINGS FOR OIL AND GAS APPLICATIONS
  申请人：Baker Hughes Incorporated

  公开号：EP3337917A1

  公开（公告）日：2018-06-27
• INHIBITING CORROSION CAUSED BY AQUEOUS ALDEHYDE SOLUTIONS
  申请人：Keenan Stephen R.

  公开号：US20130090271A1

  公开（公告）日：2013-04-11

  Aldehydes useful as H 2 S sulfide scavengers may be corrosive to some metals such as steel, iron and aluminum, but the corrosive effect of the aldehydes may be mitigated by employing a corrosion inhibitor selected from the group consisting of a di-basic soluble phosphate salt, a tri-basic soluble phosphate salt, a phosphate ester, a thiophosphate ester, a thioamine, and combinations thereof.