N'-[[ethenyl(dimethyl)silyl]methyl]-N,N,N'-trimethylethane-1,2-diamine | 1198803-52-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N'-[[ethenyl(dimethyl)silyl]methyl]-N,N,N'-trimethylethane-1,2-diamine
• CAS: 1198803-52-9
• 化学式: C₁₀H₂₄N₂Si
• 分子量: 200.399
• InChiKey: WKTABGAEMJJLNA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.45
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N'-[[ethenyl(dimethyl)silyl]methyl]-N,N,N'-trimethylethane-1,2-diamine 、 甲基锂 以 乙醚 、 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Low-Temperature Addition of Organolithiums to Functionalized Vinylsilanes under Formation of Secondary α-Lithiated Alkylsilanes

  摘要：

  At -78 degrees C and in apolar solvents, the presence and quality of a coordinating side arm in vinylsilanes dictates both their reactivity toward alkyllithiums and the structural motif in the solid state, deciding whether a defined carbolithiation, slow polymerization or no reaction at all occurs. The crystal structures of the carbolithiation products of two vinylsitanes and methyllithium are presented, and the energetic barriers of the addition step with different alkyllithiums are investigated.

  DOI：

  10.1021/ja9076167
• 作为产物：
  描述：

  四甲基乙二胺 、 二甲基乙烯基氯硅烷 在 叔丁基锂 作用下， 以 正戊烷 、 四氢呋喃 为溶剂， 生成 N'-[[ethenyl(dimethyl)silyl]methyl]-N,N,N'-trimethylethane-1,2-diamine
  参考文献：
  名称：

  Low-Temperature Addition of Organolithiums to Functionalized Vinylsilanes under Formation of Secondary α-Lithiated Alkylsilanes

  摘要：

  At -78 degrees C and in apolar solvents, the presence and quality of a coordinating side arm in vinylsilanes dictates both their reactivity toward alkyllithiums and the structural motif in the solid state, deciding whether a defined carbolithiation, slow polymerization or no reaction at all occurs. The crystal structures of the carbolithiation products of two vinylsitanes and methyllithium are presented, and the energetic barriers of the addition step with different alkyllithiums are investigated.

  DOI：

  10.1021/ja9076167

文献信息

• Low-Temperature Addition of Organolithiums to Functionalized Vinylsilanes under Formation of Secondary α-Lithiated Alkylsilanes
  作者：Christian Unkelbach、Carsten Strohmann

  DOI：10.1021/ja9076167

  日期：2009.12.2

  At -78 degrees C and in apolar solvents, the presence and quality of a coordinating side arm in vinylsilanes dictates both their reactivity toward alkyllithiums and the structural motif in the solid state, deciding whether a defined carbolithiation, slow polymerization or no reaction at all occurs. The crystal structures of the carbolithiation products of two vinylsitanes and methyllithium are presented, and the energetic barriers of the addition step with different alkyllithiums are investigated.