2-(3,5-dimethylphenylthio)ethylamine | 936562-73-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-(3,5-dimethylphenylthio)ethylamine
• 英文别名: {2-[(3,5-Dimethylphenyl)thio]ethyl}amine；2-(3,5-dimethylphenyl)sulfanylethanamine
• CAS: 936562-73-1
• 化学式: C₁₀H₁₅NS
• 分子量: 181.302
• InChiKey: KETWFWXRRMLYRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  51.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  iron(II) chloride tetrahydrate 、 2-(mesitylimino)acenaphthylene-1-one 、 2-(3,5-dimethylphenylthio)ethylamine 以 not given 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Oligomerization of Ethylene Using New Tridentate Iron Catalysts Bearing α-Diimine Ligands with Pendant S and P Donors

  摘要：

  Stoichiometric Schiff base condensations of sterically bulky primary amines with acenaphthene quinone yield isolable monoimines In the presence of iron(II) chloride the remaining ketone reacts with a second primary amine bearing a pendant donor atom to give asymmetric tridentate a diimine complexes that possess remarkable structural variability A series of NNP and NNS tridentate iron(II) complexes are prepared these coordination compounds become active catalysts for ethylene oligomerization when activated with methylalumoxanes X ray crystallographic studies of the precatalyst complexes confirm that the ligand binds in a tridentate fashion Correlations between the precatalyst solid state structures and catalyst activity and a olefin product distribution are explored

  DOI：

  10.1021/om1007743
• 作为产物：
  描述：

  3,5-二甲基苯硫酚 、 2-溴乙胺氢溴酸盐 在 potassium carbonate 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 以41.7%的产率得到2-(3,5-dimethylphenylthio)ethylamine
  参考文献：
  名称：

  吡啶二亚胺配体的替代物：供体修饰的α-二亚胺配体支持的金属配合物的合成和结构。

  摘要：

  该报告描述了由新的侧链供体修饰的α-二亚胺配体家族支持的金属卤化物配合物（M = Mn，Fe，Co）的合成和表征。供体（N，O，P，S）取代基通过短烃间隔基连接到α-二亚胺，形成一个三齿，mer-coordinating配体结构。三齿配体由单亚胺前体组装而成，后者通过与α-二酮的一个羰基选择性反应合成。虽然尝试单独分离纯净形式的三齿配体是不成功的，但通过在金属卤化物的存在下形成配体，很容易就地合成由三齿配体支撑的金属配合物，从而导致金属配合物随后从四氯化碳中结晶出来。反应混合物。具有NNN，NNO，已制备了NNP和NNS供体，并已对NNN，NNP和NNS配体支持的实例进行了结构表征。在固态下，NNN和NNP配体以mer方式配位，并且金属络合物具有扭曲的方锥结构和高自旋（S = 2）电子构型。具有NNS配位环境的化合物显示出各种固态结构，范围从具有未结合硫原子的化合物（包括氯桥联和溶剂连接的

  DOI：

  10.1039/b702197f

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
  申请人：Small L. Brooke

  公开号：US20070112150A1

  公开（公告）日：2007-05-17

  Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.

  本发明揭示了一种具有苯基硫醇或取代苯基硫醇金属配位基团的新型α-二亚胺金属配合物，特别是铁配合物。该α-二亚胺金属配合物具有苯基硫醇或取代苯基硫醇金属配位基团，是通过在金属盐或α-酰基亚胺金属配合物存在下形成α-二亚胺金属配合物亚胺键之一来制备的。具有苯基硫醇或取代苯基硫醇金属配位基团的α-二亚胺金属配合物对于聚合或寡聚烯烃非常有用。
• Diimine Metal Complexes, Methods of Synthesis, and Methods of Using in Oligomerization and Polymerization
  申请人：Small Brooke L.

  公开号：US20100222577A1

  公开（公告）日：2010-09-02

  Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.

  本发明揭示了一种具有苯基硫醇或取代苯基硫醇金属配合基的 Novel α-二亚胺金属配合物，特别是铁配合物。通过在金属盐或α-酰亚胺金属配合物的存在下形成α-二亚胺金属配合物之一的亚胺键来制备具有苯基硫醇或取代苯基硫醇金属配合基的α-二亚胺金属配合物。具有苯基硫醇或取代苯基硫醇金属配合基的α-二亚胺金属配合物可用于聚合或寡聚烯烃。
• Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins
  申请人：Chevron Phillips Chemical Company LP

  公开号：US10144752B2

  公开（公告）日：2018-12-04

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物。还公开了制造 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的方法。还公开了利用 N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的催化剂体系，以及 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物在烯烃的低聚和/或聚合中的用途。
• PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP2519532B1

  公开（公告）日：2017-03-08