3,6,9,12-tetrathiatetradecane-1,14-diol | 99868-22-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 3,6,9,12-tetrathiatetradecane-1,14-diol
• 英文别名: 2-[2-[2-[2-(2-hydroxyethylsulfanyl)ethylsulfanyl]ethylsulfanyl]ethylsulfanyl]ethanol
• CAS: 99868-22-1
• 化学式: C₁₀H₂₂O₂S₄
• 分子量: 302.547
• InChiKey: OMNOPAUWOXOADS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  16
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  142
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3,6,9,12-tetrathiatetradecane-1,14-diol 在 吡啶 、 sodium hydride 作用下， 以 乙醇 、 二氯甲烷 、 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 24.17h， 生成
  参考文献：
  名称：

  Synthesis, characterisation and ion-binding properties of oxathiacrown ethers appended to [Ru(bpy)₂]²⁺. Selectivity towards Hg²⁺, Cd²⁺and Pb²⁺

  摘要：

  氧硫杂冠醚修饰的钌配合物2能够方便地裸眼检测到Hg²⁺，仪器检测限为68 ppm。

  DOI：

  10.1039/c7ra13589k
• 作为产物：
  描述：

  1,2-二乙烷 在 碳酸氢钠 作用下， 生成 3,6,9,12-tetrathiatetradecane-1,14-diol
  参考文献：
  名称：

  Stein; Fruton; Bergmann, Journal of Organic Chemistry, 1946, vol. 11, p. 703

  摘要：

  DOI：

文献信息

• Substituted diether diols by ring-opening of carbocyclic and stannylene acetals
  作者：Rolando Martínez-Bernhardt、Peter P. Castro、Gayane Godjoian、Carlos G. Gutiérrez

  DOI：10.1016/s0040-4020(98)00563-8

  日期：1998.7

  Reduction of malonaldehyde bis(ethylene and propylene acetals) with borane or monochloroborane produces diether diols 1 and 2 in high yield. Similar reduction of glyoxal bis(ethylene acetals) has only limited utility for the preparation of tetrasubstituted triethylene glycols 3. Organotin chemistry is complementary: stannylene acetals prepared from disubstituted vicinal diols can be alkylated with half

  用硼烷或一氯硼烷还原丙二醛双（乙烯和丙烯缩醛）可以高收率生产二醚二醇1和2。乙二醛双（乙缩醛）的类似还原仅有限地用于制备四取代的三乙二醇3。有机锡化学是互补的：由二取代邻位二醇制得的亚锡乙缩醛可以与一半当量的1,2-二溴乙烷烷基化以生产四取代三乙二醇3，或与两当量的2-氯乙醇烷基化以生产二取代三乙二醇4。
• Photographic bleach compositions containing bleach-accelerating compounds and their use in a method of processing an image-wise exposed photographic silver halide material
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0001852A1

  公开（公告）日：1979-05-16

  The processing of exposed photographic silver halide colour materials is described whilst using a bleach or bleach-fixing bath containing better bleach-accelerating compounds. The bleach-accelerating compounds are polyoxyethylene compounds comprising at least 20 mol % of recurring oxyethylene units, which carry a thioether group in a side-chain.

  描述了使用含有更好的漂白加速化合物的漂白剂或漂白固定浴处理曝光的卤化银彩色材料。漂白促进化合物是聚氧乙烯化合物，由至少 20 摩尔%的重复氧乙烯单元组成，在侧链中带有硫醚基团。
• PROCESS FOR PREPARING A HYDROXY GROUP FUNCTIONALIZED THIOETHER
  申请人：BASF SE

  公开号：EP3945105A1

  公开（公告）日：2022-02-02

  A process for preparing a compound A having n groups of formula is provided, wherein X is C2-C12-alkylene or C2-C12-alkylene substituted with C1-C4-alkoxy, C1-C4-alkylthio and/or interrupted with O or S; R1, R2 and R3 are independently of one another hydrogen or C1-C4-alkyl; n is an integer of 1, 2, 3, 4, 5 or 6; which process comprises the step of reacting a compound B having n -SH groups with a compound C of formula in the presence of a free radical generator.

  一种制备具有 n 个式基团的化合物 A 的工艺 的化合物 A 的制备方法，其中 X是C2-C12-烯或被C1-C4-烷氧基、C1-C4-烷硫基和/或被O或S间断取代的C2-C12-烯； R1、R2 和 R3 相互独立地为氢或 C1-C4- 烷基； n 是 1、2、3、4、5 或 6 的整数； 该工艺包括以下步骤：使具有 n 个 -SH 基团的化合物 B 与式 C 的化合物 C 反应 在自由基发生器存在下进行反应。
• Structurally original oxathioethers macrocycles containing an exocyclic double-bond: synthesis, characterization, reactivity, and coordination
  作者：Guillaume Carel、Alina Saponar、Nathalie Saffon、Marc Vedrenne、Stéphane Massou、Gabriela Nemes、Ghassoub Rima、David Madec、Annie Castel

  DOI：10.1016/j.tet.2014.06.082

  日期：2014.9

  New oxathioethers macrocycles have been synthesized and characterized. Each macrocycle consists in structurally defined ether and thioether moieties and an exocyclic double-bond (2a-c) or a hydroxymethyl group (3a-c). Macrocycles (2a-c) have been synthesized by reaction of dianions of thioethers dials (1a-c) with 3-chloro-2-chloromethylprop-1-ene. Their hydroboration/oxidation led to corresponding primary alcohols (3a-c). Structures of compounds (2b) and (3a) have been determined by X-ray diffraction. The reactivity of the hydroxyl group allowed the preparation of oxathioethers macrocycles bearing a polyether chain or a benzyl group (4a,b) and the synthesis of new bicyclic sandwich-type compounds (5a,b). The ability of these functionalized macrocycles to coordinate to palladium has been investigated. (C) 2014 Elsevier Ltd. All rights reserved.
• US3960560A
  申请人：——

  公开号：US3960560A

  公开（公告）日：1976-06-01