(2-Ethylphenyl) diphenyl phosphite | 100814-87-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-Ethylphenyl) diphenyl phosphite
• CAS: 100814-87-7
• 化学式: C₂₀H₁₉O₃P
• 分子量: 338.343
• InChiKey: WREGBFZLBIFYIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  苯酚 、 alkaline earth salt of/the/ methylsulfuric acid 在 <(PhO)3P>4Ru 、 2,6-二乙基苯酚 、 potassium phenolate 、 三乙胺 、 三氯化磷 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 177.0 ℃ 、655.0 kPa 条件下， 反应 4.5h， 生成 (2-Ethylphenyl) diphenyl phosphite
  参考文献：
  名称：

  Catalytic carbon-carbon bond formation via ortho-metalated complexes

  摘要：

  DOI：

  10.1021/ja00270a036

文献信息

• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Lubricating oil compositions having excellent thermal stabilty, extreme pressure resistance and anti-wear performance
  申请人：Chevron Oronite Japan Limited

  公开号：EP1148114A2

  公开（公告）日：2001-10-24

  The present invention relates to a lubricating oil composition for use in industrial oils such as hydraulic oils, bearing oils, industrial gear oils and sliding surface lubricating oils. In its broadest aspect, the present invention comprises a lubricating oil composition having a major amount of a base oil of lubricating viscosity and a minor, but effective amount, of A. at least one a compound selected from the group consisting of a phosphoric acid ester, a thiophosphoric acid ester, and amine salts thereof; B. a phosphorus acid ester and/or an amine thereof; and C. at least one compound selected from the group consisting of an alkenyl succinimide, an alkenyl succinic acid ester, benzylamine, and derivatives thereof. The lubricating oil composition of the present invention provides excellent thermal stability, extreme pressure resistance and anti-wear performance.

  本发明涉及一种用于液压油、轴承油、工业齿轮油和滑动表面润滑油等工业用油的润滑油组合物。 从最广泛的方面来说，本发明包括一种润滑油组合物，其主要成分是具有润滑粘度的基础油，以及少量但有效的以下成分 A. 至少一种选自磷酸酯、硫代磷酸酯及其胺盐组成的组的化合物； B. 磷酸酯和/或其胺盐；以及 C. 至少一种选自烯基琥珀酰亚胺、烯基琥珀酸酯、苄胺及其衍生物的化合物。 本发明的润滑油组合物具有优异的热稳定性、极压抗性和抗磨损性能。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP3144064A2

  公开（公告）日：2017-03-22

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons.

  一种由钯和有机磷化合物组成的载体加氢催化剂组成的组合物，该载体加氢催化剂能选择性地将高度不饱和烃加氢为不饱和烃。
• Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines
  申请人：ExxonMobil Research and Engineering Company

  公开号：US10119090B2

  公开（公告）日：2018-11-06

  A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that contains (i) a lubricating oil base stock comprising at least one ester including at least one group selected from the group consisting of Formula (1), Formula (2), and Formula (3): The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.

  一种在使用润滑油润滑的高压缩火花点火发动机中防止或减少发动机爆震或预燃的方法，其方法是使用一种配制油作为润滑油。配制油的成分包含：(i) 润滑油基础油，包含至少一种酯，其中至少有一个基团选自由式（1）、式（2）和式（3）组成的组： 本公开的润滑油可用作乘用车发动机油（PVEO）产品。
• Method and composition for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines
  申请人：ExxonMobil Research and Engineering Company

  公开号：US10604720B2

  公开（公告）日：2020-03-31

  A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by introducing to a combustion chamber of the engine from 0.1 to 5% by volume of the gasoline used a lubricating oil as a formulated oil, said formulated oil having a composition comprising (i) a major amount of a lubricating oil base stock comprising at least 80% by weight of one branched ester having at least 15% of the total carbons in the form of methyl groups, and (ii) a minor amount of at least one ashless amine phosphate antiwear additive. Also provided is a lubricating engine oil for high compression spark ignition engines including (i) a major amount of a lubricating oil base stock comprising at least 80% by weight formula I below: esterified (per —OH basis) with 25 to 100% isobutyric acid and 0 to 75% 3,5,5-trimethylhexanoic acid, wherein R is a H, methyl, ethyl, isopropyl, or isobutyl, and (ii) a minor amount of at least one amine phosphate ashless antiwear additive.

  一种在使用润滑油润滑的高压缩火花点火发动机中防止或减少发动机爆震或预点火的方法，其方法是在发动机燃烧室中引入 0.1%至5%（按所用汽油体积计）的润滑油作为配制油，所述配制油的成分包括：(i) 主要量的润滑油基础油，该基础油包含至少80%（按重量计）的支链酯，该支链酯中至少15%的碳以甲基形式存在，以及(ii) 少量的至少一种无灰磷酸胺抗磨添加剂。还提供了一种用于高压缩火花点火发动机的润滑机油，包括：(i) 主要量的润滑机油基础油，按重量计至少含有 80% 的下式 I： 其中 R 是 H、甲基、乙基、异丙基或异丁基，以及 (ii) 微量的至少一种无灰磷酸胺抗磨添加剂。