diperoxyadipic acid | 5824-51-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diperoxyadipic acid
• 英文别名: hexanebis(peroxoic acid)；Diperoxyadipinsaeure；Peradipinsaeure；peradipic acid；hexanediperoxoic acid
• CAS: 5824-51-1
• 化学式: C₆H₁₀O₆
• 分子量: 178.142
• InChiKey: GBXAHFXTHNBQRX-UHFFFAOYSA-N

物化性质

• 熔点：
  114-115 °C (decomp)(Solv: ethyl ether (60-29-7))
• 沸点：
  350.6±52.0 °C(Predicted)
• 密度：
  1.375±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  异氰酸酯 、 diperoxyadipic acid 以 1,4-二氧六环 为溶剂， 以95%的产率得到adipoyl bisperoxycarbamate
  参考文献：
  名称：

  Muraeva, N. P.; Lapshin, N. M.; Morozov, O. S., Journal of general chemistry of the USSR, 1982, vol. 52, # 1, p. 173 - 179

  摘要：

  DOI：
• 作为产物：
  描述：

  己二酸 在 双氧水 作用下， 以 硫酸 、 水 为溶剂， 生成 diperoxyadipic acid
  参考文献：
  名称：

  Stabilized diperoxyalkanedioic acids and aromatic peroxycarboxylic acids

  摘要：

  过氧代烷二酸和芳香过氧羧酸是通过将二烷基酸或芳香羧酸与硫酸中的过氧化氢反应而制备的，然后通过添加碱金属氢氧化物、碱金属铝酸盐或碱土金属氢氧化物在原位产生过氧酸的减敏剂，使过滤液不含硫酸。生成的盐包覆过氧酸，产品被减敏并在储存中稳定。

  公开号：

  US04287135A1

文献信息

• Process for the preparation of imidazo[4,5-c]-quinolin-4-amines
  申请人：Dzwiniel Trevor

  公开号：US20070100146A1

  公开（公告）日：2007-05-03

  The present invention is a method for preparing a compound of the formula wherein R is hydrogen, C 1 to C 6 alkyl, C 1 to C 6 alkoxy or halo, R 1 and R 2 are independently hydrogen, C 1 to C 10 alkyl, C 1 to C 10 alkoxy, C 3 to C 10 cycloalkyl, C 3 to C 10 alkenyl, C 5 to C 10 cycloalkenyl, C 2 to C 10 alkynyl, C 6 to C 20 aryl or substituted C 6 to C 20 aryl and n is the integer 1 or 2 by reacting the corresponding N-oxide with an aqueous solution of ammonia and a C 1 to C 6 alkyl, C 6 to C 20 aryl or substituted C 6 to C 20 aryl chloroformate thereby forming said compound formula (1).

  本发明提供了一种制备式（1）化合物的方法，其中R为氢、C1至C6烷基、C1至C6烷氧基或卤素，R1和R2独立地为氢、C1至C10烷基、C1至C10烷氧基、C3至C10环烷基、C3至C10烯基、C5至C10环烯基、C2至C10炔基、C6至C20芳基或取代的C6至C20芳基，n为整数1或2，通过将相应的N-氧化物与氨水和C1至C6烷基、C6至C20芳基或取代的C6至C20芳基氯甲酸酯的水溶液反应，从而形成所述化合物式（1）。
• Use of transition metal complexes with nitrogen-containing polydentate ligands as a bleaching catalyst and bleaching agent composition
  申请人：Kunz Ulrike

  公开号：US20050032661A1

  公开（公告）日：2005-02-10

  The present invention is directed to transition metal complexes that are used as bleaching catalysts for peroxy compounds. The complexes contain a pentadentate ligand, which can be open-chain or cyclic. The ligand has the structure: wherein in cyclic ligands the two R 1 together form Preferred complexes are:

  本发明涉及用作过氧化物漂白催化剂的过渡金属配合物。这些配合物包含一个五齿配体，可以是开链或环状的。该配体的结构为：其中在环状配体中，两个R1一起形成。优选的配合物为：
• Mulls containing chain structure clay suspension aids
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0034387A2

  公开（公告）日：1981-08-26

  A liquid mull is provided having improved physical stability, consisting of a liquid phase, comprising a major proportion of a nonionic surfactant and optionally a minor proportion of a nonaqueous solvent, and a dispersed solid phase comprising a particulate material which is insoluble in the liquid phase of the mull. From 1 % to 15% by weight of the composition of a chain structure type clay is included to aid the physical stability of the mull, so that insoluble particulate materials such as builders having ordinary particle sizes may also be incorporated. Preferred compositions are substantially anhydrous to allowthe optional inclusion of water sensi. tive detergency adjuvants such as enzymes or bleaches. The compositions may optionally contain up to 25% of a further dispersion aid selected from anionic surfactants, cationic surfactants, zwitterionic surfactants and hydrotropic materials. Such mulls have utility, for example, as detergent compositions.

  本发明提供了一种具有更好物理稳定性的液体闷闷不乐剂，它由液相和分散固相组成，液相主要由非离子表面活性剂和少量非水溶剂组成，分散固相由不溶于闷闷不乐剂液相的颗粒材料组成。按重量计，在组合物中加入 1%至 15%的链状结构粘土，以提高泥浆的物理稳定性，这样也可以加入不溶于泥浆的颗粒材料，如具有普通粒度的建筑材料。优选的组合物基本上是无水的，这样就可以选择性地加入对水敏感的去污佐剂，如酶或漂白剂。组合物还可以选择性地含有高达 25% 的其它分散助剂，这些助剂选自阴离子表面活性剂、阳离子表面活性剂、齐聚亚铵盐表面活性剂和亲水材料。例如，这种混合物可用作洗涤剂组合物。
• Detergent bleach compositions
  申请人：UNILEVER N.V.

  公开号：EP0037146A1

  公开（公告）日：1981-10-07

  A solid detergent bleach composition adapted for use at substantially any washing temperature, comprising essentially a detergent active compound and a synergistic mixture of a solid organic peroxy acid compound e.g. diperoxyazelaic acid, an inorganic peroxy compound e.g. sodium perborate and a stabilising sequestering agent. The composition which is preferably presented in the form of a particulate product, shows improved bleaching effect at substantially all washing temperatures. It has also advantages over compositions comprising bleaching activators in that it does not suffer from problems of in situ peroxy acid generation.

  一种适用于任何洗涤温度的固体洗涤漂白剂组合物，主要包括一种洗涤活性化合物和一种固体有机过氧化合物（如二脱氧壬二酸）、一种无机过氧化合物（如过硼酸钠）和一种稳定螯合剂的协同混合物。这种组合物最好以颗粒产品的形式出现，在几乎所有的洗涤温度下都能显示出更好的漂白效果。与含有漂白活化剂的组合物相比，它的优点还在于不会出现过氧酸原位生成的问题。
• Controlled release laundry bleach product
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0070066A1

  公开（公告）日：1983-01-19

  A hydrophilic or hydrotropic peroxyacid laundry bleach plus a surfactant bleach release-delaying agent, contained inside a pouch, bag or substrate, provides a controlled bleach release laundry product.

  亲水性或亲水性过氧乙酸洗衣漂白剂加上表面活性剂漂白释放延缓剂，装在小袋、袋子或基材中，可提供一种可控漂白释放的洗衣产品。