1,6-dioxa-cyclohexadecane-2,5-dione | 82993-72-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 大环内酯类和类似物
• 英文名称: 1,6-dioxa-cyclohexadecane-2,5-dione
• 英文别名: 1,6-Dioxa-cyclohexadecan-2,5-dion；Decamethylene succinate；1,6-dioxacyclohexadecane-2,5-dione
• CAS: 82993-72-4
• 化学式: C₁₄H₂₄O₄
• 分子量: 256.342
• InChiKey: QWUVDMOLNYRJTI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,10-decanediol bis-bromoacetate 在 六甲基磷酰三胺 、 samarium diiodide 作用下， 以 四氢呋喃 为溶剂， 以16%的产率得到3-Oxo-butyric acid 10-hydroxy-decyl ester
  参考文献：
  名称：

  使用碘化sa（II）和HMPA通过α-卤代酸酯的还原偶联合成琥珀二酯

  摘要：

  通过用SmI 2 -HMPA处理，伯和仲α-卤代酸酯以良好的产率转化为琥珀酸二酯。

  DOI：

  10.1016/0040-4039(95)02299-6

文献信息

• Meta and Para Rings¹
  作者：E. W. Spanagel、Wallace H. Carothers

  DOI：10.1021/ja01308a047

  日期：1935.5
• US6846862B2
  申请人：——

  公开号：US6846862B2

  公开（公告）日：2005-01-25
• [EN] BINDER SYSTEM AND METHOD FOR PARTICULATE MATERIAL<br/>[FR] PROCEDE ET SYSTEME DE LIANT POUR MATIERE PARTICULAIRE
  申请人：APEX ADVANCED TECHNOLOGIES LLC

  公开号：WO2002000569A2

  公开（公告）日：2002-01-03

  The present invention relates to a binder composition comprising an aliphatic polyester polymer; an ethylenebisamide wax; and a guanidine wetting agent. The composition may also contain an additive which accelerates or extends debinding of the binder composition, and to a method for forming a sintered part by powder injection molding, including the steps of forming a green composition comprising a binder and an inorganic powder, wherein the binder is a composition comprising an aliphatic polyester polymer, an ethylenebisamide wax, and a guanidine wetting agent, and may further include an additive which accelerates or delays completion of debinding of the binder; melting the composition; injecting the composition into a mold for a part; heating the part to a temperature at which the binder decomposes; heating the part to a temperature at which the inorganic powder is sintered.
• Synthesis of succinic diesters via reductive coupling of α-haloesters using samarium (II) iodide and HMPA
  作者：Élise Balaux、Réjean Ruel

  DOI：10.1016/0040-4039(95)02299-6

  日期：1996.2

  Primary and secondary α-haloesters are converted to succinic diesters in good yield by treatment with SmI2-HMPA.

  通过用SmI 2 -HMPA处理，伯和仲α-卤代酸酯以良好的产率转化为琥珀酸二酯。