4-(10-hydroxydecyl)-2,6-di-tert-butylphenol | 100669-71-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-(10-hydroxydecyl)-2,6-di-tert-butylphenol
• 英文别名: 4-(10-Hydroxydecyl)-2,6-di-t-butylphenol；2,6-ditert-butyl-4-(10-hydroxydecyl)phenol
• CAS: 100669-71-4
• 化学式: C₂₄H₄₂O₂
• 分子量: 362.596
• InChiKey: ADBOIWHPABQNIV-UHFFFAOYSA-N

物化性质

• 沸点：
  439.2±40.0 °C(Predicted)
• 密度：
  0.945±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  26
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,10-癸二醇 、 2,6-二叔丁基苯酚 在 sodium hydroxide 作用下， 反应 5.0h， 以39.3%的产率得到4-(10-hydroxydecyl)-2,6-di-tert-butylphenol
  参考文献：
  名称：

  Synthesis of 4-(ω-hydroxyalkyl)-2,6-di-tert-butylphenols and the properties of related sulfides

  摘要：

  Reaction of 2,6-di-tert-butylphenol with aliphatic linear and branched diols in an alkaline medium at a temperature of 180-220A degrees C leads to the formation of 4-(omega-hydroxyalkyl)-2,6-di-tert-butylphenols. The increase in the product yield and reducing the reaction temperature was reached at the catalysis of this reaction with zinc oxide. The structure of the diphenylalkane derivatives generated in side reaction was proved and the structural influence of the length of the aliphatic residue on the antioxidant effectiveness of the sulfides derived from the corresponding hydroxyalkylphenols was examined.

  DOI：

  10.1134/s1070363210100208

文献信息

• US4020042A
  申请人：——

  公开号：US4020042A

  公开（公告）日：1977-04-26
• Synthesis of 4-(ω-hydroxyalkyl)-2,6-di-tert-butylphenols and the properties of related sulfides
  作者：A. P. Krysin、I. I. Pustovskikh、V. A. Koptyug

  DOI：10.1134/s1070363210100208

  日期：2010.10

  Reaction of 2,6-di-tert-butylphenol with aliphatic linear and branched diols in an alkaline medium at a temperature of 180-220A degrees C leads to the formation of 4-(omega-hydroxyalkyl)-2,6-di-tert-butylphenols. The increase in the product yield and reducing the reaction temperature was reached at the catalysis of this reaction with zinc oxide. The structure of the diphenylalkane derivatives generated in side reaction was proved and the structural influence of the length of the aliphatic residue on the antioxidant effectiveness of the sulfides derived from the corresponding hydroxyalkylphenols was examined.