phthalic acid monotridecyl ester | 21577-81-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phthalic acid monotridecyl ester
• 英文别名: Phthalsaeure-monotridecylester；2-tridecoxycarbonylbenzoic Acid
• CAS: 21577-81-1
• 化学式: C₂₁H₃₂O₄
• 分子量: 348.483
• InChiKey: BKMAEERFCKIKJR-UHFFFAOYSA-N

物化性质

• 沸点：
  477.1±28.0 °C(Predicted)
• 密度：
  1.031±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  25
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯酐 、 十三烷醇 生成 phthalic acid monotridecyl ester
  参考文献：
  名称：

  Monoalkyl Phthalates from Normal Aliphatic Alcohols

  摘要：

  DOI：

  10.1021/ja01265a094

文献信息

• Dicarboxylic diester, process for producing the same, and refrigerating machine lubricating oil comprising the ester
  申请人：Kawahara Yasuyuki

  公开号：US20050038283A1

  公开（公告）日：2005-02-17

  A diester represented by the formula wherein A represents a cyclohexane ring, cyclohexene ring or benzene ring, X is H or methyl group, R X and R Y are the same or different and each is C3-C18 branched-chain alkyl group, C1-C18 straight-chain alkyl group, C2-C18 straight-chain alkenyl or C3-C18 cycloalkyl, provided that when A is a benzene ring, R X and R Y are different from each other and —COOR X and —COOR Y are attached to two adjacent carbon atoms of the benzene ring, and having the following properties: 1) a total acid number of 0.05 mgKOH/g or less, 2) a sulfated ash content of 10 ppm or less, 3) a sulfur content of 20 ppm or less, 4) a phosphorus content of 20 ppm or less, 5) a peroxide value of 1.0 meq/kg or less, 6) a carbonyl value of 10 or less; 7) a volume resistivity of 1×10 11 Ω·cm or more, 8) a hydroxyl value of 3 mgKOH/g or less, and 9) a water content of 100 ppm or less, a process for preparing the same and a refrigerator lubricating oil comprising the diester.

  由以下公式表示的二酯，其中A代表环己烷环、环己烯环或苯环，X为H或甲基基团，RX和RY相同或不同，且每个均为C3-C18支链烷基基团、C1-C18直链烷基基团、C2-C18直链烯基或C3-C18环烷基，前提是当A为苯环时，RX和RY彼此不同，且—COORX和—COORY连接到苯环的两个相邻碳原子，并具有以下特性：1）总酸值为0.05 mgKOH/g或更低，2）硫酸盐灰分含量为10 ppm或更低，3）硫含量为20 ppm或更低，4）磷含量为20 ppm或更低，5）过氧化值为1.0 meq/kg或更低，6）羰基值为10或更低；7）体积电阻率为1×1011Ω·cm或更高，8）羟值为3 mgKOH/g或更低，9）水含量为100 ppm或更低，制备该二酯的方法以及包含该二酯的制冷剂润滑油。
• Lubrication blends
  申请人：ATOCHEM NORTH AMERICA, INC.

  公开号：EP0395875A1

  公开（公告）日：1990-11-07

  A novel lubrication blend useful per se as a lubricant or as an additive to form a novel lubricant composition. The lubrication blend consists essentially of a mixture of: (1) at least one complex sulfide of antimony, represented by the formula: SbxSy wherein, x is a number in the range from about 1.7 to about 2.3, and y is a number in the range from about 3.6 to about 4.4, (2) at least one antimony oxide, and (3) at least one lamellar crystalline solid lubricant.

  一种新型润滑混合物，其本身可用作润滑剂或添加剂以形成新型润滑剂组合物。该润滑混合物主要由以下物质的混合物组成：(1) 至少一种锑的复合硫化物，其代表式为 SbxSy 其中，x 是约 1.7 至约 2.3 范围内的数字，y 是约 3.6 至约 4.4 范围内的数字；(2) 至少一种氧化锑；(3) 至少一种片状结晶固体润滑剂。
• ELECTRONIC/ELECTRIC COMPONENTS USED IN CLEAN ROOM AND SUBSTRATE TREATMENT APPARATUS
  申请人：Tokyo Electron Limited

  公开号：EP0971000A1

  公开（公告）日：2000-01-12

  An electronic/electric part used in a clean room in which the atmosphere is controlled to process a substrate in a semiconductor device industry, which contains a resin base material and additives added to the resin base material. The additives contain one or more materials selected from the group consisting of an anti-electrostatic agent made of a nonionic compound of a molecular weight of 350 or higher, an anti-oxidizing agent made of a phenolic compound of a molecular weight of 300 or higher, a lubricant, a plasticizer, a fire retardant, and a water repellent. The additives hardly releases gaseous organic substances from the resin base material under a condition where the part is used.

  一种在无尘室中使用的电子/电气部件，该无尘室的气氛受控，用于加工半导体设备行业中的基板，该部件包含树脂基材和添加到树脂基材中的添加剂。添加剂包含一种或多种材料，这些材料选自分子量为 350 或更高的非离子化合物制成的抗静电剂、分子量为 300 或更高的酚类化合物制成的抗氧化剂、润滑剂、增塑剂、阻燃剂和防水剂。这些添加剂在部件使用条件下几乎不会从树脂基材中释放出气体有机物质。
• MICROPOROUS FILM
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP1063256A1

  公开（公告）日：2000-12-27

  A microporous membrane is produced by cooling a solution comprising a vinylidene fluoride homopolymer or copolymer having a weight average molecular weight of 1 x 105 or more and a solvent therefor, to form a two-phase gel, said microporous membrane comprising a polymer phase comprising said vinylidene fluoride homopolymer or copolymer, and intercommunicating voids which have an average pore size measured by the half-dry method of 0.005 to 5 µm and range from one side of the membrane to the other side, and said microporous membrane having as its internal structure a percolation structure in which the polymer phase forms an isotropic network structure by three-dimensional branching in arbitrary directions, the voids are formed by surrounding by said polymer phase of the network structure and intercommunicate with one another, and the ratio of the maximum pore size measured by the bubble point method to the average pore size measured by the half-dry method is 2.0 or less.

  一种微孔膜是通过冷却由重量平均分子量为 1 x 105 或更大的偏氟乙烯均聚物或共聚物及其溶剂组成的溶液以形成两相凝胶而制得的，所述微孔膜包括由所述偏氟乙烯均聚物或共聚物组成的聚合物相，以及通过半干法测量的平均孔径为 0.所述微孔膜的内部结构为渗流结构，其中聚合物相通过任意方向的三维分支形成各向同性的网络结构，空隙由所述网络结构的聚合物相包围形成，并相互连通，气泡点法测量的最大孔径与半干法测量的平均孔径之比为 2.0 或更小。
• DICARBOXYLIC DIESTER, PROCESS FOR PRODUCING THE SAME, AND REFRIGERATING MACHINE LUBRICATING OIL COMPRISING THE ESTER
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1227078A1

  公开（公告）日：2002-07-31

  A diester represented by the formula wherein A represents a cyclohexane ring, cyclohexene ring or benzene ring, X is H or methyl group, RX and RY are the same or different and each is C3-C18 branched-chain alkyl group, C1-C18 straight-chain alkyl group, C2-C18 straight-chain alkenyl or C3-C10 cycloalkyl, provided that when A is a benzene ring, RX and RY are different from each other and -COORX and -COORY are attached to two adjacent carbon atoms of the benzene ring, and having the following properties: 1) a total acid number of 0.05 mgKOH/g or less, 2) a sulfated ash content of 10 ppm or less, 3) a sulfur content of 20 ppm or less, 4) a phosphorus content of 20 ppm or less, 5) a peroxide value of 1.0 meq/kg or less, 6) a carbonyl value of 10 or less; 7) a volume resistivity of 1 x 1011 Ω·cm or more, 8) a hydroxyl value of 3 mgKOH/g or less, and 9) a water content of 100 ppm or less, a process for preparing the same and a refrigerator lubricating oil comprising the diester.

  由式表示的二酯 其中 A 代表环己烷环、环己烯环或苯环，X 为 H 或甲基，RX 和 RY 相同或不同，且各自为 C3-C18 支链烷基、C1-C18 直链烷基、C2-C18 直链烯基或 C3-C10 环烷基，条件是当 A 为苯环时，RX 和 RY 彼此不同，且 -COORX 和 -COORY 连接到苯环的两个相邻碳原子上，并具有以下性质： 1) 总酸数不超过 0.05 mgKOH/g、 2) 硫酸盐灰分含量不超过 10 ppm、 3) 硫含量不超过 20 ppm、 4) 磷含量不超过 20 ppm、 5) 过氧化值等于或小于 1.0 meq/kg、 6) 羰基值等于或小于 10； 7) 体积电阻率等于或大于 1 x 1011 Ω-cm、 8) 羟值为 3 mgKOH/g 或更低，以及 9) 含水量等于或小于 100 ppm、 制备该二元酯的工艺和包含该二元酯的冷冻机润滑油。