2-Methyl-N,N-bis[(oxiran-2-yl)methyl]prop-2-enamide | 87406-73-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-Methyl-N,N-bis[(oxiran-2-yl)methyl]prop-2-enamide
• 英文别名: 2-methyl-N,N-bis(oxiran-2-ylmethyl)prop-2-enamide
• CAS: 87406-73-3
• 化学式: C₁₀H₁₅NO₃
• 分子量: 197.23
• InChiKey: SXXWNCNXSWHLQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  45.4
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• N-GLYCIDYL-SUBSTITUTED AMIDE COMPOUNDS
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0094436A1

  公开（公告）日：1983-11-23

  Novel compounds represented by the formula: wherein R1 represent an aliphatic hydrocarbyl group, an aromatic hydrocarbyl group or an alicyclic hydrocarbyl group, X represents hydrogen, a glycidoxy group or an N,N-diglycidylamino group, R2 represents hydrogen or a methyl group, R3 represents an alkyl group, an alkemyl group, or an aryl group, p represents 0 or 1, q represents an integer of 1 to 4; r represents 1 or 2, and s represents an integer of 1 to 4, are obtained by reacting an amide compound with a halide compound such as epihalohydrin or dihalopropanol in the presence of a strongly basic compound. They are useful as starting meterials for reactive diluents, cross-linking agents, etc.

  式所代表的新型化合物： 其中 R1 代表脂肪族烃基、芳香族烃基或脂环族烃基；X 代表氢、缩水甘油基或 N,N-二缩水甘油基氨基；R2 代表氢或甲基；R3 代表烷基、烷酰基或芳基；p 代表 0 或 1；q 代表 1 至 4 的整数；R3 代表烷基、烷基或芳基，p 代表 0 或 1，q 代表 1 至 4 的整数，r 代表 1 或 2，s 代表 1 至 4 的整数。它们可用作活性稀释剂、交联剂等的起始原料。
• Adsorption-desorption method for the separation of water soluble organic compounds from aqueous solution
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0161882A2

  公开（公告）日：1985-11-21

  An adsorbent is obtained by water-insolubilizing a homopolymer of one of N,N-di-substituted (meth)acrylamides represented by the structural formula given herein, a copolymer of two or more of the N,N-di-substituted (meth)-acrylamides or a copolymer of one or more of the N,N-di--substituted (meth)acrylamides and one or more copolymerizable monomers other than the N,N-di-substituted (meth)--acrylamides, said (meth)acrylamides being represented by the formulae: or wherein Rl stands for a hydrogen atom or methyl group, A stands for ―(CH2)n―, n being 4 - 6, or ―(CH2)2 0 ―(CH2)―, and Rz denotes a methyl or ethyl group. The adsorbent has the property that it is hydrophobicized to have higher adsorbability when heated and its adsorbability drops when cooled.

  一种吸附剂是通过将本文给出的结构式所代表的一种 N,N-二取代(甲基)丙烯酰胺的均聚物、两种或两种以上 N、N,N-二取代(甲基)丙烯酰胺的均聚物、两种或多种 N,N-二取代(甲基)丙烯酰胺的共聚物，或一种或多种 N,N-二取代(甲基)丙烯酰胺与一种或多种 N,N-二取代(甲基)丙烯酰胺以外的可共聚单体的共聚物，所述(甲基)丙烯酰胺由以下结构式表示： 或 其中 Rl 表示氢原子或甲基，A 表示-(CH2)n-，n 为 4-6 或-(CH2)2 0-(CH2)-，Rz 表示甲基或乙基。这种吸附剂具有疏水性，加热时吸附性较高，冷却时吸附性下降。
• Method for repeatedly absorbingand holding urine
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0178175A2

  公开（公告）日：1986-04-16

  A urine absorbing and holding material comprises either a homopolymer of at least one monomer selected from certain N-alkyl- or N-alkylene-substituted acrylamides and methacrylamides or a copolymer of two or more of these acrylamides and methacrylamides, or a copolymer of at least one of these acrylamides and methacrylamides with one or more monomers other than the said arcylamides and methacrylamides and copolymerizable therewith, the homopolymer or copolymer being a water-insolubilized product. This material, in the form of powder, granules, flakes, fibers or film, can be combined with a fibrous material in the form of a woven fabric, non-woven fabric or a flocculent material, into a useful urine absorbing composite for making up to into a pad, diaper or drawers.

  一种尿液吸收和保持材料包括至少一种选自某些 N-烷基或 N-烯基取代的丙烯酰胺和甲基丙烯酰胺的单体的均聚物，或两种或两种以上丙烯酰胺和甲基丙烯酰胺的共聚物、或至少一种丙烯酰胺和甲基丙烯酰胺与一种或多种非上述芳基酰胺和甲基丙烯酰胺单体的共聚物，且可与之共聚，均聚物或共聚物为水不溶物。这种粉末状、颗粒状、薄片状、纤维状或薄膜状的材料可以与编织物、无纺布或絮凝材料形式的纤维材料结合成有用的尿液吸收复合材料，用于制作尿垫、尿布或抽屉。
• Cationic acrylamide polymers, a process for manufacturing them, and their uses
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0377313A2

  公开（公告）日：1990-07-11

  This invention provides cationic acrylamide polymers which are highly effective as paper strength agents, drainage agents and suspension flocculants, and which do not show much temporal deterioration; it also provides a method of manufacturing said polymers wherein the manufacturing equipment is compact and can be installed on site, and the cationicity of the polymers can be modified in a short time. This invention comprises a method of manufacturing cationic acrylamide polymers by reaction, with a hypohalogenite,of a (meth)acrylamide homopolymer, a copolymer of (meth)acrylamide and acrylonitrile, a copolymer of (meth)acrylamide and N,N-dimethylacrylamide, in a high temperature range of 50 - 110°C for a short time; the polymers manufactured by said process; and paper strength agents, drainage agents and flocculants having these polymers as their principal constituent.

  本发明提供了作为纸张强度剂、排水剂和悬浮絮凝剂非常有效的阳离子丙烯酰胺聚合物，它不会出现太多的时间劣化；本发明还提供了一种制造上述聚合物的方法，其制造设备结构紧凑，可在现场安装，聚合物的阳离子性可在短时间内改变。 本发明包括一种制造阳离子丙烯酰胺聚合物的方法，该方法是将(甲基)丙烯酰胺均聚物、(甲基)丙烯酰胺与丙烯腈的共聚物、(甲基)丙烯酰胺与N,N-二甲基丙烯酰胺的共聚物在50-110℃的高温范围内与次卤化物进行短时间反应；通过上述工艺制造的聚合物；以及以这些聚合物为主要成分的纸张强度剂、排水剂和絮凝剂。
• PROCESS FOR PRODUCING PARTICULATE POLYMER
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0406432A1

  公开（公告）日：1991-01-09

  The invention provides a process for producing particulate polymer, which comprises polymerizing either one or more of N-alkyl- or N-alkylene-substituted (meth)acrylamides or a mixture of said one or more of N-alkyl- or N-alkylene-substituted (meth)acrylamides with other copolymerizable monomer(s) dispersed in an aqueous solution of an inorganic salt containing inorganic particles suspended therein. This process provides particulate polymer not containing such impurities as a polymer stabilizer or a surfactant. This polymer is useful as a concentrating agent, a base for sustained release, and the like.

  本发明提供了一种生产微粒聚合物的工艺，该工艺包括聚合一种或多种 N-烷基或 N-亚烷基取代的（甲基）丙烯酰胺，或上述一种或多种 N-烷基或 N-亚烷基取代的（甲基）丙烯酰胺与其他可共聚单体的混合物，这些单体分散在无机盐水溶液中，其中含有悬浮的无机微粒。这种工艺可提供不含聚合物稳定剂或表面活性剂等杂质的微粒聚合物。这种聚合物可用作浓缩剂、缓释基质等。