2-(N-(2-bromophenyl)anilino)isoindole-1,3-dione | 262606-95-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 2-(N-(2-bromophenyl)anilino)isoindole-1,3-dione
• CAS: 262606-95-1
• 化学式: C₂₀H₁₃BrN₂O₂
• 分子量: 393.239
• InChiKey: RCZQMPSRNNFIKN-UHFFFAOYSA-N

物化性质

• 沸点：
  521.4±52.0 °C(Predicted)
• 密度：
  1.580±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(N-(2-bromophenyl)anilino)isoindole-1,3-dione 在 三氯化铝 作用下， 以 苯 为溶剂， 反应 17.0h， 以73%的产率得到1-溴咔唑
  参考文献：
  名称：

  Synthesis of Carbazoles from N-(N,N-Diarylamino)phthalimides with Aluminum Chloride via Diarylnitrenium Ions

  摘要：

  Generation of diarylnitrenium ions from N-(N,N-diarylamino)phthalimides by treatment with AlCl3 in benzene or in 1,2-dichloroethane leads to formation of carbazoles by intramolecular C-C bond formation. The reaction proceeds in synthetically useful yields.

  DOI：

  10.1021/jo016124r
• 作为产物：
  描述：

  2-溴苯肼 在 copper diacetate 、 三乙胺 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 24.0h， 生成 2-(N-(2-bromophenyl)anilino)isoindole-1,3-dione
  参考文献：
  名称：

  N-芳基氨基邻苯二甲酰亚胺与三苯基铋和乙酸铜的 N-苯基化：1-Aryl-1-Phenylhydrazines 的便捷合成

  摘要：

  摘要 描述了由 N-芳基-N-苯基氨基邻苯二甲酰亚胺 (1) 合成 1-芳基-1-苯肼 (2)，该化合物通过 1 与三苯基铋和乙酸铜的苯基化反应合成。

  DOI：

  10.1080/00397910008087300

文献信息

• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2521197A1

  公开（公告）日：2012-11-07

  Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. The organic EL device of this invention comprises a light-emitting layer between an anode and a cathode piled one upon another on a substrate wherein the light-emitting layer contains a phosphorescent dopant and a 1,9-substituted carbazole compound as a host material. An example of the 1,9-substituted carbazole compound is represented by the following general formula (1). In formula (1), Ar is an aromatic hydrocarbon group or aromatic heterocyclic group; L is an aromatic hydrocarbon group or aromatic heterocyclic group; each of R1 to R3 is a hydrogen atom, an alkyl group, a cycloalkyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; n is an integer of 1 to 3.

  本发明公开了一种有机电致发光器件（organic EL device），它的发光效率更高，充分保证了驱动稳定性，而且结构简单。本发明的有机电致发光器件包括一个发光层，该发光层位于基底上一个叠着一个的阳极和阴极之间，其中发光层含有磷光掺杂剂和作为主材料的 1，9-取代咔唑化合物。1,9-取代咔唑化合物的一个例子由以下通式（1）表示。式（1）中，Ar 是芳香烃基团或芳香杂环基团；L 是芳香烃基团或芳香杂环基团；R1 至 R3 各为氢原子、烷基、环烷基、芳香烃基团或芳香杂环基团；n 是 1 至 3 的整数。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Ogawa Junya

  公开号：US20120235136A1

  公开（公告）日：2012-09-20

  Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. The organic EL device of this invention comprises a light-emitting layer between an anode and a cathode piled one upon another on a substrate wherein the light-emitting layer contains a phosphorescent dopant and a 1,9-substituted carbazole compound as a host material. An example of the 1,9-substituted carbazole compound is represented by the following general formula (1). In formula (1), Ar is an aromatic hydrocarbon group or aromatic heterocyclic group; L is an aromatic hydrocarbon group or aromatic heterocyclic group; each of R 1 to R 3 is a hydrogen atom, an alkyl group, a cycloalkyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; n is an integer of 1 to 3.
• US8986858B2
  申请人：——

  公开号：US8986858B2

  公开（公告）日：2015-03-24
• US9461250B2
  申请人：——

  公开号：US9461250B2

  公开（公告）日：2016-10-04
• Synthesis of Carbazoles from <i>N</i>-(<i>N</i>,<i>N</i>-Diarylamino)phthalimides with Aluminum Chloride via Diarylnitrenium Ions
  作者：Yasuo Kikugawa、Yutaka Aoki、Takeshi Sakamoto

  DOI：10.1021/jo016124r

  日期：2001.12.1

  Generation of diarylnitrenium ions from N-(N,N-diarylamino)phthalimides by treatment with AlCl3 in benzene or in 1,2-dichloroethane leads to formation of carbazoles by intramolecular C-C bond formation. The reaction proceeds in synthetically useful yields.