N-Phenyl-N'-(trimethylstannyl)carbodiimid | 65332-17-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Phenyl-N'-(trimethylstannyl)carbodiimid
• 英文别名: phenyl(trimethylstannyl)cyanamide
• CAS: 65332-17-4
• 化学式: C₁₀H₁₄N₂Sn
• 分子量: 280.945
• InChiKey: XWXMNDFVHIBHLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.33
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二氯二茂钛 、 N-Phenyl-N'-(trimethylstannyl)carbodiimid 以 四氢呋喃 为溶剂， 以95%的产率得到cyclopenta-1,3-diene;phenyliminomethylideneazanide;titanium(4+)
  参考文献：
  名称：

  Synthesis of Carbodiimidotitanium Complexes by the Reaction of (Trimethylstannyl)carbodiimides with Titanium Chlorides

  摘要：

  Me(3)Sn-N=C=N-R(1) (R(1) = Si(i)Pr(3), SiPh(2)(t)Bu, Ph) reacts with Cp(2)TiCl(2) (Cp = eta(5)-C(5)H(5), or Cp*(2)TiCl(2) (Cp* = eta(5)-C(5)Me(5)) selectively at the Sn-N bond to give the corresponding bis(carbodiimido)titanium complexes (Cp(2)Ti(N=C=N-SiR(3))(2), Cp*(2)Ti(N=C=N-SiR(3))(2), and Cp(2)Ti(N=C=N-Ph)(2)) in moderate to high yields. The structure of Cp(2)Ti(N=C=N-Ph)(2) was determined by X-ray crystallography. Oligomeric complexes were formed by the reaction of Me(3)Sn-N=C=N-X-N=C=N-SnMe(3) (X = -C(6)H(3)Cl-CH(2)-C(6)H(3)Cl-) with Cp*(2)TiCl(2).

  DOI：

  10.1021/om971129t

文献信息

• Synthesis of Carbodiimidotitanium Complexes by the Reaction of (Trimethylstannyl)carbodiimides with Titanium Chlorides
  作者：Guilaine Veneziani、Shigeru Shimada、Masato Tanaka

  DOI：10.1021/om971129t

  日期：1998.6.1

  Me(3)Sn-N=C=N-R(1) (R(1) = Si(i)Pr(3), SiPh(2)(t)Bu, Ph) reacts with Cp(2)TiCl(2) (Cp = eta(5)-C(5)H(5), or Cp*(2)TiCl(2) (Cp* = eta(5)-C(5)Me(5)) selectively at the Sn-N bond to give the corresponding bis(carbodiimido)titanium complexes (Cp(2)Ti(N=C=N-SiR(3))(2), Cp*(2)Ti(N=C=N-SiR(3))(2), and Cp(2)Ti(N=C=N-Ph)(2)) in moderate to high yields. The structure of Cp(2)Ti(N=C=N-Ph)(2) was determined by X-ray crystallography. Oligomeric complexes were formed by the reaction of Me(3)Sn-N=C=N-X-N=C=N-SnMe(3) (X = -C(6)H(3)Cl-CH(2)-C(6)H(3)Cl-) with Cp*(2)TiCl(2).