tricyclo[5.2.1.02,6 ]dec-8-ene | 19398-83-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: tricyclo[5.2.1.02,6 ]dec-8-ene
• 英文别名: endo-tricyclo<4.3.0.1^2,5>dec-3-ene；tricyclo-<5,2,1,0^2.6>dec-3-ene；Tricyclo[5.2.1.0^2,6]dec-4-ene；endo-4,5-Dihydro-dicyclopentadien；exo-4,5-Dihydro-dicyclopentadien；tricyclo[5.2.1.02.6]dec-8-ene；2,3,3a,4,7,7a-Hexahydro-4,7-methano-1H-indene；tricyclo[5.2.1.02,6]dec-8-ene
• CAS: 19398-83-5
• 化学式: C₁₀H₁₄
• 分子量: 134.221
• InChiKey: WHNYVDJJCTVMGO-UHFFFAOYSA-N

物化性质

• 沸点：
  173 °C(Press: 752 Torr)
• 密度：
  1.011±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tricyclo[5.2.1.02,6 ]dec-8-ene 在 吡啶 、 potassium permanganate 、 水 、 sodium hydroxide 作用下， 以 叔丁醇 为溶剂， 反应 0.17h， 生成 C₂₄H₂₄O₄
  参考文献：
  名称：

  [EN] ESTER COMPOUND
  [FR] COMPOSÉ ESTER
  [JA] エステル化合物

  摘要：

  这项发明的酯化合物由以下式（1）表示[式中，R1-R24分别独立地是氢原子、卤素原子、烃基或含有杂原子的烃基。 R1-R10、R23和R24可以相互连接形成环，相邻的取代基也可以直接连接形成多重键。 R11-R24可以相互连接形成环，相邻的取代基也可以相互连接形成多重键。 在R1-R24中，至少有一对相互连接形成环结构。 n2-n5分别独立地表示0-2的整数。 n1和n6分别独立地表示0或1的整数。 L1和L2分别独立地是烃基或含有杂原子的烃基。]。

  公开号：

  WO2022045231A1
• 作为产物：
  描述：

  bicyclo[3.2.1]oct-2-ene 生成 tricyclo[5.2.1.02,6 ]dec-8-ene
  参考文献：
  名称：

  Traction drive fluid, process for producing the same and bicyclo octane

  摘要：

  一种牵引驱动液组合物，包括具有双环辛烷骨架的碳氢化合物，例如双环(3,2,1)辛烷骨架，双环(2,2,2)辛烷骨架或双环(3,3,0)辛烷骨架。该牵引驱动液具有低粘度，并且在广泛的温度范围内具有高牵引系数。

  公开号：

  US05283384A1

文献信息

• Iridium(I) Complexes with Anionic N-Heterocyclic Carbene Ligands as Catalysts for the Hydrogenation of Alkenes in Nonpolar Media
  作者：Eugene L. Kolychev、Sabrina Kronig、Kai Brandhorst、Matthias Freytag、Peter G. Jones、Matthias Tamm

  DOI：10.1021/ja406529c

  日期：2013.8.21

  complexes of anionic N-heterocyclic carbenes that contain a weakly coordinating borate moiety (WCA-NHC) was prepared in one step from free N-heterocyclic carbenes by deprotonation with n-butyl lithium followed by borane addition. The reaction of the resulting lithium-carbene adducts with [M(COD)Cl]2 (M = Rh, Ir; COD = 1,5-cyclooctadiene) afforded zwitterionic rhodium(I) and iridium(I) complexes of the

  一系列包含弱配位硼酸盐部分的阴离子 N-杂环卡宾 (WCA-NHC) 的锂配合物是通过用正丁基锂去质子化然后加入硼烷从游离 N-杂环卡宾一步制备的。所得锂卡宾加合物与 [M(COD)Cl]2 (M = Rh, Ir; COD = 1,5-环辛二烯) 反应得到 [( WCA-NHC)M(COD)]，其中金属原子与卡宾配体的 N-芳基发生分子内相互作用。对于 M = Rh，制备了中性复合物 [(WCA-NHC)Rh(CO)2] 和 ate 复合物 (NEt4)[(WCA-NHC)Rh(CO)2Cl]，后者允许评估通过红外光谱测定配体的供体能力。两性离子铱-COD 络合物作为烯烃均相氢化的催化剂进行了测试，这可以在非极性溶剂或纯烯烃底物存在下进行。因此，活性最高的配合物在低催化剂负载量（低至 10 ppm）的烯烃氢化中表现出优异的稳定性和活性。
• [EN] BICYCLOHEPTANE-BASED COMPOUND, A CETANE NUMBER IMPROVER CONTAINING THE SAME, AND DIESEL FUEL<br/>[FR] COMPOSÉ À BASE DE BICYCLOHEPTANE, ADDITIF PRO-CÉTANE LE CONTENANT, ET CARBURANT
  申请人：KOREA RES INST CHEM TECH

  公开号：WO2010134679A3

  公开（公告）日：2011-07-14
• Ualikhanova, A.; Temirbulatova, A. E.; Dembitskii, A. A., Russian Journal of Physical Chemistry, 1992, vol. 66, # 2, p. 240 - 242
  作者：Ualikhanova, A.、Temirbulatova, A. E.、Dembitskii, A. A.、Mailyubaev, B. T.、Korolev, A. V.

  DOI：——

  日期：——
• Determination of Dicyclopentadiene and Its Derivatives as Compounds Causing Odors in Groundwater Supplies
  作者：Francesc Ventura、Jordi Romero、Joan Parés

  DOI：10.1021/es960987y

  日期：1997.8.1

  A study of organic pollutants causing odor events in the groundwater from the Lower Llobregat aquifer system has been conducted. This aquifer acts as water reserve of Barcelona (northeast Spain) when the quality of the raw water from the Llobregat River is low. Closed-loop stripping analysis (CLSA), purge-and-trap (P&T), sensory GC, and flavor profile analysis (FPA) have been used as analytical methodologies to identify the compounds responsible for the odor events. Industrial organochlorinated solvents-di-to hexa chlorinated saturated and unsaturated hydrocarbons-dicyclopentadiene (DCPD) and its derivatives 8-dihydroDCPD, tetrahydroDCPD, and adamantane (the trimer of DCPD) are among the most significant compounds identified in the groundwater. DCPD with a mean concentration of <1 mu g/L in almost all analyzed wells is the compound causing the odor incidents, regardless that some organochlorinated solvents such as 1,1,2-trichloroethane, trichloroethylene, and perchloroethylene might be even 2 or 3 orders of magnitude more concentrated than DCPD. The synthesis of dihydroDCPD was performed for confirmatory purposes. Trained and untrained panelists have established the threshold odor for this compound in the range of 10-25 ng/L. Although further research is needed, it is possible that an illegal landfill closed in the 1970s could be the origin of the different pollutants found.
• Highly Selective Mono-hydrogenation of Dicyclopentadiene with Pd-nanoparticles
  作者：Arno Behr、Vanessa Manz、Adrian Lux、Andrea Ernst

  DOI：10.1007/s10562-013-0960-3

  日期：2013.3

  In this paper, we present a new protocol to synthesize dihydrodicyclopentadienes (DHDCP), via mono hydrogenation of dicyclopentadiene. With the use of Pd-nanoparticles as catalysts the products are formed highly selective under mild conditions. The ratio between the DHDCP and the tetrahydrodicyclopentadiene (THDCP) can be shifted by variation of the hydrogen pressure from 7:1 to 1:8, with high conversions of over 85 %. The product DHDCP is an essential building block in co-polymerizations. Also we show an easy recycling concept for the nanocatalyst by phase separation. With simple filtration the solid products DHDCP and THDCP can be isolated and the liquid catalyst phase can directly be reused. Over all recycling runs a steady high conversion of about 75 % was observed.Palladium nanoparticles in solution are an efficient catalyst for the selective monohydrogenation of dicyclopentadiene to the two dihydrodicyclopentadienes. High selectivities up to 95 % could be obtained after one hour under mild reaction conditions of 60 A degrees C and 5 bar hydrogen pressure. Besides we could show an easy catalyst recycling concept by the liquid-solid two-phase technique.