diethylmethylphenylammonium iodide | 1007-67-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diethylmethylphenylammonium iodide
• 英文别名: N,N-diethyl-N-methyl-anilinium; iodide；N,N-Diaethyl-N-methyl-anilinium; Jodid；Methyl-diaethyl-phenyl-ammonio-jodid；Diethyl-methyl-phenyl-ammoniumiodid；Methyl-diethylphenylammonium；N,N-Diethyl-N-methylanilinium iodide；diethyl-methyl-phenylazanium;iodide
• CAS: 1007-67-6
• 化学式: C₁₁H₁₈N*I
• 分子量: 291.175
• InChiKey: MRAQWAAICCJGIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.33
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  diethylmethylphenylammonium iodide 以82%的产率得到
  参考文献：
  名称：

  NEWKOME G. R.; MAJESTIC V. K.; SAUER J. D., ORG. PREP. AND PROCED. INT., 1980, 12, NO 6, 345-350

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N-二甲基苯胺 生成 diethylmethylphenylammonium iodide
  参考文献：
  名称：

  v. Braun, Chemische Berichte, 1908, vol. 41, p. 2117

  摘要：

  DOI：

文献信息

• Carbonylation of quaternary ammonium salts to tertiary amides using NaCo(CO)4 catalyst
  作者：Yizhu Lei、Rui Zhang、Qing Wu、Hui Mei、Bo Xiao、Guangxing Li

  DOI：10.1016/j.molcata.2013.10.014

  日期：2014.1

  the catalytic carbonylation of quaternary ammonium salts under anhydrous condition. Quaternary ammonium salts, a kind of versatile reagents that were widely used in organometallic chemistry, can be carbonylated to tertiary amides by an in situ prepared NaCo(CO)4 catalyst. It was found that the counterions (Cl−, Br−, I−, OTf−) in the quaternary ammonium salts played a significant role in the reaction

  我们在这里报道了在无水条件下季铵盐的催化羰基化反应。季铵盐是一种广泛用于有机金属化学的通用试剂，可通过原位制备的NaCo（CO）4催化剂羰基化为叔酰胺。结果发现，该抗衡离子（CL - ，溴- ，我- ，光学传递函数- ）在季铵盐中的反应中发挥了作用显著和碘化四甲基铵可以给的高产率（96％）Ñ，Ñ-仅含0.5摩尔％钴催化剂的-二甲基乙酰胺（DMAc）。在最佳条件下，其他几种季铵碘化物也以中等至极好的收率被羰基化为相应的叔酰胺。显然，这些结果也使我们特别理解，Me 4 NI和其他季铵盐在羰基化反应中可能被羰基化为叔酰胺，在大多数情况下它们被用作促进剂或溶剂。考虑到高活性和中等至优异的选择性，该方法可能是合成某些叔酰胺的潜在方法。此外，详细讨论了CN键的裂解机理和可能的催化中间体。
• Receptivity of Picea sitchensis stumps to infection by Heterobasidion annosum basidiospores
  作者：C.M. Woods

  DOI：10.1093/forestry/73.5.457

  日期：2000.5.1

  Picea sitchensis stumps were inoculated with Heterobasidion annosum basidiospores either immediately or 24 h, 7 days or 28 days after cutting, in order to determine the length of time they remained susceptible to infection. Control stumps were inoculated with sterile water; those that became colonized were presumed to have been infected by natural inoculum. The degree of colonization of inoculated stumps declined when spores were applied more than 24 h after cutting but was still greater than in the control stumps at 7 days. Spores applied at 28 days did not result in stump infection. These data indicate that stump protection measures applied after felling must remain effective for at least 7 days, and that if stump treatment is not applied immediately after cutting, it could still have some protective value up to 7 days later.

  立即或在砍伐后 24 小时、7 天或 28 天将环状异囊杉基生孢子接种到欧洲欧洲杉树桩上，以确定树桩易受感染的时间长度。对照树桩用无菌水进行接种；被定殖的树桩被推定为受到自然接种体的感染。在砍伐后 24 小时以上施用孢子时，接种树桩的定殖程度下降，但在 7 天后仍高于对照树桩。28 天后施用孢子不会导致树桩感染。这些数据表明，砍伐后采取的树桩保护措施必须至少在 7 天内保持有效，如果砍伐后没有立即对树桩进行处理，7 天后仍有一定的保护价值。
• Wedekind–Fock–Havinga salt Me(Et)N+(All)PhI–·CHCl3 as historically the first object for absolute asymmetric synthesis: spontaneous resolution, structure and absolute configuration
  作者：Remir G. Kostyanovsky、Vasilii R. Kostyanovsky、Gul’nara K. Kadorkina、Konstantin A. Lyssenko

  DOI：10.1070/mc2001v011n01abeh001420

  日期：2001.1
• Wedekind; Paschke, Chemische Berichte, 1910, vol. 43, p. 1306
  作者：Wedekind、Paschke

  DOI：——

  日期：——
• Emmert, Chemische Berichte, 1909, vol. 42, p. 1509
  作者：Emmert

  DOI：——

  日期：——