N-(6-hexanol-1-yl) pyrrol | 96625-74-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: N-(6-hexanol-1-yl) pyrrol
• 英文别名: 6-(1H-Pyrrol-1-yl)hexan-1-ol；6-pyrrol-1-ylhexan-1-ol
• CAS: 96625-74-0
• 化学式: C₁₀H₁₇NO
• 分子量: 167.251
• InChiKey: KUKMFTBQDUOSFP-UHFFFAOYSA-N

物化性质

• 沸点：
  277.4±23.0 °C(Predicted)
• 密度：
  0.96±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  25.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(6-hexanol-1-yl) pyrrol 在 ammonium hexafluorophosphate 作用下， 以 吡啶 为溶剂， 生成 1-methyl-1'-(6-(pyrrol-1-yl)hexyl)-4,4'-bipyridinium bis(hexafluorophosphate)
  参考文献：
  名称：

  由1-hydro-1'-（6-（pyrrol-1-yl）己基）-4,4'-联吡啶双（六氟磷酸盐）氧化得到的聚合物的合成和电荷传输性质以及对pH敏感的证明由常规氧化还原中心的氧化还原特性衍生的微电化学晶体管

  摘要：

  DOI：

  10.1021/j100329a031
• 作为产物：
  描述：

  1-(6-bromohexyl)pyrrole 以 六甲基磷酰三胺 、 水 为溶剂， 反应 7.0h， 以76%的产率得到N-(6-hexanol-1-yl) pyrrol
  参考文献：
  名称：

  具有可电聚合侧链的维生素B 12衍生物的合成

  摘要：

  制备了三个新的带有吡咯头基连接至柯林环的维生素B 12衍生物。配体交换反应和还原反应提供了反应性的Co III和Co II复合物。研究了它们的电化学性质和通过电聚合固定在电极表面的潜力。

  DOI：

  10.1002/hlca.19980810525

文献信息

• "Growth from surface" Methodology for the Fabrication of Functional Dual Phase Conducting Polymer polypyrrole/polycarbazole/Polythiophene (CP/polyPyr/polyCbz/PolyTh)-Carbon Nanotube (CNT) Composites of Controlled Morphology and Composition - Sidewall versus End-Selective PolyTh Deposition
  申请人：Lellouche Jean-Paul

  公开号：US20130040049A1

  公开（公告）日：2013-02-14

  A “growth from the surface” method for selectively depositing oxidative Liquid Phase Polymerizations (LPPs) onto the carbon nanotube (CNT) surface, said method comprising steps of: a. obtaining Multi-walled Carbon Nanotubes (MWC-NT); b. oxidized said MWCNTs to obtain oxidized COOH-MWCNTs; thereby (a) carboxylative opening oxidation-sensitive end-caps (polyCOOH end cluster); and, (b) introducing defect carboxylic (COOH) groups onto predetermined areas of said oxidized COOH-MWCNTs; c. COOH activating the polyCOOH shell using various COOH activating species; and, d. executing Liquid Phase Polymerization (LPP) oxidative depositing polymers selected from said polyCOOH polyTh-CP polymers, polyCOOH poly-Th-, polyEDOT (PEDOT)-, polyTh polyCOOH poly(thiophenyl-3 acetic acid, thiophenyl-3 acetic acid/EDOT, polyX, wherein X is elected from COOH, OH, NH2, polyCbz/polyPyr CP polymers and related combinatorial mixtures, polyCOOH PEDOT-poly(thiophenyl-3 acetic acid)′ thereby selectively depositing said oxidative LPPs onto said CNT surface.

  一种用于选择性沉积氧化液相聚合物（LPPs）到碳纳米管（CNT）表面的“从表面生长”方法，所述方法包括以下步骤：a. 获得多壁碳纳米管（MWC-NT）；b. 氧化所述MWCNTs以获得氧化的COOH-MWCNTs；从而（a）羧化开启氧化敏感端盖（polyCOOH端簇）；以及（b）在所述氧化的COOH-MWCNTs的预定区域引入缺陷羧基（COOH）基团；c. 使用各种COOH活化物种对polyCOOH壳进行COOH活化；以及d. 执行液相聚合物化学氧化沉积聚合物，所选聚合物来自所述polyCOOH polyTh-CP聚合物，polyCOOH poly-Th-，polyEDOT（PEDOT）-，polyTh polyCOOH poly（噻吩-3 乙酸，噻吩-3 乙酸/EDOT，polyX，其中X选自COOH，OH，NH2，polyCbz/polyPyr CP聚合物和相关组合物，polyCOOH PEDOT-poly（噻吩-3 乙酸）'，从而选择性地将所述氧化LPPs沉积到所述CNT表面。
• Selective hydroboration of equilibrating allylic azides
  作者：Ruzhang Liu、Yuanyuan Zhang、Jun Xu

  DOI：10.1039/d1cc02520a

  日期：——

  The iridium(I)-catalyzed hydroboration of equilibrating allylic azides is reported to provide only the anti-Markovnikov product of alk-1-ene isomers in good yields and with good functional group tolerance.

  据报道，平衡的烯丙基叠氮化物的铱( I ) 催化硼氢化仅以良好的收率和良好的官能团耐受性提供了烷-1-烯异构体的反马尔科夫尼科夫产物。
• Heterocyclic imino compounds and fungicides and insecticides for agricultural and horitcultural use
  申请人：——

  公开号：US20030212116A1

  公开（公告）日：2003-11-13

  A heterocyclic imino compound of the formula (1) and an agrochemically acceptable salt thereof; and an agricultural chemical, fungicide and insecticide containing at least one member selected from the group of such compounds as an active ingredient: 1 wherein G is 2 or the like, A is a 3- to 13-membered, mono-, di- or tri-cyclic ring which contains at least one hetero atom selected from among oxygen atoms, sulfur atoms and nitrogen atoms, which is composed of from 3 to 13 atoms arbitrarily selected from among carbon atoms, oxygen atoms, sulfur atoms and nitrogen atoms and which may be substituted by from 1 to 13 Ys, provided that when A is a quinolone ring, the nitrogen atom in the quinolone ring is present at the &agr;-position to the imino bond, Z is —OR 1 or the like, B is —CH 2 — or the like, Y is Y′—D—(CH 2 ) p — or the like, D is a single bond or the like, X is halogen or the like, and R 1 is a hydrogen atom, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl or the like.

  一种具有以下化学式（1）的杂环亚胺化合物及其农药可接受的盐；以及至少选择自这类化合物组中的一种作为活性成分的农用化学品、杀菌剂和杀虫剂：其中G为2或类似物，A为3至13个成员的单环、双环或三环环，其中至少包含一种从氧原子、硫原子和氮原子中选择的杂原子，由3至13个从碳原子、氧原子、硫原子和氮原子中任意选择的原子组成，并且可能被1至13个Y取代，前提是当A为喹啉环时，喹啉环中的氮原子位于亚胺键的α-位置，Z为—OR1或类似物，B为—CH2—或类似物，Y为Y′—D—（CH2）p—或类似物，D为单键或类似物，X为卤素或类似物，R1为氢原子、C1-C6烷基、C1-C6卤代烷基或类似物。
• Non-volatile memory
  申请人：Matsushita Electric Industrial Co., LTD.

  公开号：US20040196688A1

  公开（公告）日：2004-10-07

  A nonvolatile memory includes at least a first electrode ( 71 ) and a second electrode ( 72 ) provided on a substrate, the first and second electrodes being separated from each other, and a conductive organic thin film ( 73 ) for electrically connecting the first and second electrodes. The conductive organic thin film ( 73 ) has a first electric state in which it exhibits a first resistance, and a second electric state in which it exhibits a second resistance. A first threshold voltage for a transition from the first electric state to the second electric state, and a second threshold voltage for a transition from the second electric state to the first electric state are different from each other, and either the first electric state or the second electric state is maintained at a voltage in a range between the first threshold voltage and the second threshold voltage. The conductive organic thin film ( 73 ) is bound with a surface of the substrate by conjugate bonds. A diode ( 74 ) may be connected with the conductive organic thin film ( 73 ). This provides a nonvolatile memory that not only allows writing/reading of record to be performed utilizing a change in an electrical resistance of the conductive organic thin film ( 73 ), but also can be densely packaged.

  一种非挥发性存储器包括至少在基板上提供的第一电极（71）和第二电极（72），第一和第二电极相互分离，并且用于电性连接第一和第二电极的导电有机薄膜（73）。导电有机薄膜（73）具有第一电态，其中它表现出第一电阻，以及第二电态，其中它表现出第二电阻。从第一电态到第二电态的转变的第一阈值电压和从第二电态到第一电态的转变的第二阈值电压彼此不同，并且在第一阈值电压和第二阈值电压之间的范围内维持第一电态或第二电态的电压。导电有机薄膜（73）通过共轭键与基板表面结合。二极管（74）可以与导电有机薄膜（73）连接。这提供了一种非挥发性存储器，不仅允许利用导电有机薄膜（73）的电阻变化执行记录的写入/读取，而且还可以密集地打包。
• Organic electronic device and its manufacturing method
  申请人：Yamamoto Shinichi

  公开号：US20050145839A1

  公开（公告）日：2005-07-07

  An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

  本发明的有机电子器件包括基板、形成在基板上的至少两个电极、形成在基板上并电性连接电极的导电有机薄膜以及用于涂覆电极至少一部分的涂层膜。导电有机薄膜是含有共轭键合团的有机分子的聚合物，每个有机分子的一端化学键合在基板表面上，有机分子中的共轭键合团与其他共轭键合团聚合形成共轭键链。涂层膜将电极与导电有机薄膜电性连接，并实现比电极和导电有机薄膜直接连接时更小的连接电阻。涂层膜可以是由金、铂、银等金属制成的膜、导电聚合物膜或化学键合在电极上的单分子膜。