{AgBr(triphenylphosphine)} | 47107-31-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {AgBr(triphenylphosphine)}
• 英文别名: Bromosilver;triphenylphosphane；bromosilver;triphenylphosphane
• CAS: 47107-31-3
• 化学式: C₁₈H₁₅AgBrP
• 分子量: 450.063
• InChiKey: XEILIKRZNYBNQZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.29
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  {AgBr(triphenylphosphine)} 、 mesitylsilver 以 四氢呋喃 为溶剂， 以85%的产率得到(2,4,6-trimethylphenyl)(triphenylphosphanyl)gold
  参考文献：
  名称：

  Uson, Rafael; Laguna, Antonio; Fernandez, Eduardo J., Journal of the Chemical Society, Dalton Transactions, 1989, p. 2127 - 2132

  摘要：

  DOI：
• 作为产物：
  描述：

  Silver, bromobis(triphenylphosphine)- 以 甲醇 为溶剂， 生成 {AgBr(triphenylphosphine)}
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B7, 1.23.3, page 208 - 220

  摘要：

  DOI：

文献信息

• Synthesis, X-ray and solid state NMR studies on silver(I) silanethiolates. Crystal structure of bis[(triphenylphosphine)(tri-o-tolylsilanethiolato)silver(I)]–toluene(1/2), [{Ag[SSi(C6H4Me-o)3](PPh3)}2]·2C6H5Me †
  作者：Jaroslaw Chojnacki、Barbara Becker、Atoni Konitz、Marek J. Potrzebowski、Wieslaw Wojnowski

  DOI：10.1039/a903694f

  日期：——

  A series of silver(I) trialkoxysilanethiolates [Ag(SSiR3)(PPh3)2], R = ButO, BusO or PriO, and triarylsilanethiolates [Ag(SSiR′3)(PPh3)], R′ = o-MeC6H4 or Ph, were obtained by reaction of [Ag(acac)(PPh3)2] with the respective silanethiols. Products were studied by 1H NMR, CP MAS 31P and 29Si NMR in solution and/or in the solid state. A single-crystal X-ray structural analysis was carried on for [Ag[SSi(C6H4Me-o)3](PPh3)}2]·2C6H5Me.

  通过[Ag(acac)(PPh3)2]与相应的硅硫醇反应，获得了一系列三烷氧基硅硫醇银[Ag(SSiR3)(PPh3)2]（R = ButO、BusO 或 PriO）和三芳基硅硫醇银[Ag(SSiRâ²3)(PPh3)]（Râ²Â = o-MeC6H4 或 Ph）。通过 1H NMR、CP MAS 31P 和 29Si NMR 对溶液和/或固体状态下的产物进行了研究。对[Ag[SSi(C6H4Me-o)3](PPh3)}2]Â-2C6H5Me 进行了单晶 X 射线结构分析。
• Functionalised Silver Chalcogenide Clusters
  作者：Robert Langer、Ben Breitung、Linda Wünsche、Dieter Fenske、Olaf Fuhr

  DOI：10.1002/zaac.201100018

  日期：2011.6

  Eight new silver chalcogenide clusters with different functional groups in the ligand shell were synthesised and characterised by single-crystal X-ray diffraction. The optical properties of the isostructural clusters [Ag6(S-C6H4-CN)6(PPh3)6] (1) and [Ag6(S-C6H4-NO2)6(PPh3)6] (2) are described and compared. In addition, the reactivity of 1 towards metal salts and Lewis acids was investigated, which

  合成了八个在配体壳中具有不同官能团的新型银硫属化物簇，并通过单晶 X 射线衍射进行了表征。描述并比较了同构簇 [Ag6(S-C6H4-CN)6(PPh3)6] (1) 和 [Ag6(S-C6H4-NO2)6(PPh3)6] (2) 的光学特性。此外，研究了 1 对金属盐和路易斯酸的反应性，这导致了化合物 [Ag6(S-C6H4-CN)6(PPh3)5] (3) 和 [Ag14S(S-C6H4-CN)12 (PPh3)8][FeCl2(thf)4]3 (4)。硫功能化簇 [Ag14S(S-C6H4-NCS)12(PPh3)8] (5) 具有进一步反应和固定在金表面的前景。羧酸银与O反应，S-双（三甲基甲硅烷基）-4-羟基苯硫酚和双（三甲基甲硅烷基）硫族化物在叔膦存在下导致簇的形成[Ag23S2(S-C6H4-OSiMe3)15(S-C6H4-OH)3(PPh3) 8] (6) 和 [Ag40
• Metal Nitrosyls. I. Triphenylphosphine Nitrosyl Nickel Complexes
  作者：Robert D. Feltham

  DOI：10.1021/ic50011a025

  日期：1964.1
• Teo, Boon K.; Shi, Xiaobo; Zhang, Hong, Journal of the American Chemical Society, 1991, vol. 113, p. 4329 - 4331
  作者：Teo, Boon K.、Shi, Xiaobo、Zhang, Hong

  DOI：——

  日期：——
• A W–Ag–Se cluster compound: (μ₃-bromo)(μ₃-tetraselenidotungstide)tris(triphenylphosphinesilver) ethanol solvate, [(μ₃-Br)(μ₃-WSe₄)(AgPPh₃)₃]^.EtOH
  作者：Q. Zhang、X. Xin、M. Hong、R. Cao、S. Shanmuga Sundara Raj、H.-K. Fun

  DOI：10.1107/s0108270199000207

  日期：1999.5.15

  The title compound, mu 3-bromo-2:3:4 kappa(3)Br-tri-mu(3)-selenido-1:2:3 kappa(3)Se;1:2:4 kappa(3)Se;1:3:4 kappa(3)Se-selenido-1 kappa Se- tris(triphenylphosphine)-2 kappa P,3 kappa P,4 kappa P-trisilvertungsten ethanol solvate, [Ag3WBrSe4(C18H15P)(3)] . C2H5OH, is composed of discrete [(mu(3)-Br)(mu(3)-WSe4)(AgPPh3)(3)] neutral clusters and EtOH molecules. The structure can be described either as (i) a cubane-like [WAg3Se3Br](2+) cluster core with another Se2- ligand bound to the W atom and three PPh3 ligands attached to the three Ag atoms, or as (ii) three Ag(PPh3)(+) fragments linked by one mu(3)-WSe42- and one mu(3)-Br ligand. The average W-Ag bond distance is 3.01(1) Angstrom, which is too long to be considered a metal-metal interaction.