benzoic-3,5-dinitrobenzoic anhydride | 10515-41-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzoic-3,5-dinitrobenzoic anhydride
• 英文别名: Benzoesaeure-<3.5-dinitro-benzoesaeure>-anhydrid；benzoic acid-(3,5-dinitro-benzoic acid )-anhydride；Benzoesaeure-(3,5-dinitro-benzoesaeure)-anhydrid；Benzoyl 3,5-dinitrobenzoate
• CAS: 10515-41-0
• 化学式: C₁₄H₈N₂O₇
• 分子量: 316.227
• InChiKey: VNDSXHWROWDSAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  135
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  benzoic-3,5-dinitrobenzoic anhydride 、 苯胺 以 氯仿 为溶剂， 反应 0.5h， 生成 3,5-二硝基-N-苯基-苯甲酰胺
  参考文献：
  名称：

  Dubey; Vinod Kumar, Journal of the Indian Chemical Society, 2001, vol. 78, # 5, p. 265 - 266

  摘要：

  DOI：
• 作为产物：
  描述：

  Potassium benzoate 、 3,5-二硝基苯甲酰氯 在 苄基三乙基氯化铵 作用下， 以 氯仿 为溶剂， 反应 2.0h， 以95%的产率得到benzoic-3,5-dinitrobenzoic anhydride
  参考文献：
  名称：

  Dubey; Kumar, R. Vinod, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1999, vol. 38, # 1, p. 1 - 3

  摘要：

  DOI：

文献信息

• Phase managed organic synthesis 2. A new polymer assisted synthesis of acid anhydrides.
  作者：Wilmer K. Fife、Zhi-dong Zhang

  DOI：10.1016/s0040-4039(00)85100-x

  日期：1986.1

  A solid-phase copolymer of 4-vinylpyridine is shown to be a highly effective reagent/ catalyst for the synthesis of acid anhydrides from mixtures containing equimolar quantities of carboxylic acids and acid chlorides. The process may be carried out in batch or column mode.

  已显示4-乙烯基吡啶的固相共聚物是用于由包含等摩尔量的羧酸和酰氯的混合物合成酸酐的高效试剂/催化剂。该过程可以以间歇或塔模式进行。
• Sixteen years of old-field succession and reestablishment of a bottomland hardwood forest in the Lower Mississippi Alluvial Valley
  作者：Loretta L. Battaglia、Peter R. Minchin、Davis W. Pritchett

  DOI：10.1672/0277-5212(2002)022[0001:syoofs]2.0.co;2

  日期：2002.3

  In the Lower Mississippi Alluvial Valley (LMAV), losses of bottomland hardwood forests have been severe, with less than 30% of the original 10 million ha remaining. Reforestation of abandoned farmland is occurring, but there has been little research on natural reestablishment of these forests. We examined understory succession and tree establishment patterns in a 3.2-ha field in northeast Louisiana, USA, abandoned in 1984. Relative elevation, strongly correlated with flooding depth and frequency, varied by approximately 1m. Ground-layer composition was monitored from 1985 to 1999 in twenty 1-m(2) quadrats stratified along the elevation gradient. In 2000, shrubs and tree saplings were mapped and their relative elevations determined. Ordination of the ground-layer data revealed that the major trends in species composition were related to time-since-abandonment and elevation. Annual species gradually declined, woody perennials became more abundant, and a shrub and young tree layer emerged from beneath the ground layer, but species composition in low and high elevation plots did not converge. Obligate species were more common at lower elevations, while facultative species were more common at upper elevations. By 16 years after abandonment, a total of 16 tree and shrub species had established in the field; eleven of these had potential local seed sources on levees adjacent to the study site. Abundance of dominant species was significantly related to elevation in most cases. In addition, distance to seed source influenced density and spatial distribution of Celtis laevigata and Fraxinus pennsylvanica. Our study suggests that rate and pattern of secondary succession in LMAV bottomlands are strongly influenced by elevation, dispersal mode of species, and the composition and proximity of forest remnants. Successful restoration of bottomland forests will require an improved understanding of these factors.
• FIFE W. K.; ZHANG ZHI-DONG, TETRAHEDRON LETT., 27,(1986) N 41, 4933-4936
  作者：FIFE W. K.、 ZHANG ZHI-DONG

  DOI：——

  日期：——
• 2-[4-(2,2,-DIHALOCYCLOPROPYL)PHENOXY]-ALKANOIC ACIDS AND ESTERS THEREOF PRODUCTION PROCESS
  申请人：LABORATORIO CHIMICO INTERNAZIONALE S.p.A.

  公开号：EP1387822B1

  公开（公告）日：2005-06-15
• [EN] 2-[4-(2, 2-DIHALOCYCLOPROPYL)PHENOXY]-ALKANOIC ACIDS AND ESTERS THEREOF PRODUCTION PROCESS<br/>[FR] PROCEDE DE PRODUCTION D'ACIDES 2-[4-(2, 2-DIHALOCYCLOPROPYL)PHENOXY]-ALKANOIQUES ET D'ESTERS DE CES DERNIERS
  申请人：LABORATORIO CHIMICO INT SPA

  公开号：WO2002090307A1

  公开（公告）日：2002-11-14

  2-[4-(2,2 Dihalocyclopropyl)phenoxy]-alkanoic acids and esters thereof synthesis process including the Baeyer-Villiger reaction.