2,3;4,5-di-O-isopropylidene-α-D-fructopyranose | 22164-03-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧吡喃
• 英文名称: 2,3;4,5-di-O-isopropylidene-α-D-fructopyranose
• 英文别名: 2,3:4,5-di-O-isopropylidene-D-fructopyranose；DIPF；1-Desoxy-2,3:4,5-di-O-isopropyliden-D-fructose；2,3:4,5-Di-O-isopropyliden-D-fructopyranose；[(1R,2S,6R,9R)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecan-6-yl]methanol
• CAS: 22164-03-0
• 化学式: C₁₂H₂₀O₆
• 分子量: 260.287
• InChiKey: PSSHGMIAIUYOJF-KZFFXBSXSA-N

物化性质

• 熔点：
  120 °C
• 沸点：
  332.6±37.0 °C(Predicted)
• 密度：
  1.181±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.4
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3;4,5-di-O-isopropylidene-α-D-fructopyranose 生成 (1R,2S,6R,9R)-6-(ethenoxymethyl)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecane
  参考文献：
  名称：

  KALUZA, ZBIGNIEW;FUDONG, WANG;BELZECKI, CZESLAW;CHMIELEWSKI, MAREK, TETRAHEDRON LETT., 30,(1989) N8, C. 5171-5172

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(4-methylphenyl)sulfonyl-4-[[(1R,2S,6R,9R)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecan-6-yl]methoxy]azetidin-2-one 、 氨 以45%的产率得到
  参考文献：
  名称：

  KALUZA, ZBIGNIEW;FUDONG, WANG;BELZECKI, CZESLAW;CHMIELEWSKI, MAREK, TETRAHEDRON LETT., 30,(1989) N8, C. 5171-5172

  摘要：

  DOI：

文献信息

• Highly stereoselective synthesis of 2-deoxy-α- glycosides and α-disaccharides
  作者：Halszka Bielawska、Maria Michalska

  DOI：10.1016/s0040-4039(98)02167-4

  日期：1998.12

  Highly stereoselective synthesis of 2-deoxy-α-glycosides including disaccharides is described, using S-(2-deoxyglycosyl)phosphorodithioates as glycosyl donors, in the presence of silver perchlorate in acetonitrile

  描述了使用S-（2-脱氧糖基）磷酸二硫代酯作为糖基供体，在乙腈中存在高氯酸银的情况下，高度立体选择性地合成包括二糖在内的2-脱氧-α-糖苷。
• Monoacryloyl esters of carbohydrates: Synthesis, polymerization and application in ceramic technology
  作者：Paulina Wiecinska、Tadeusz Mizerski、Mikolaj Szafran

  DOI：10.1016/j.carbpol.2014.05.023

  日期：2014.10

  The article presents the interdisciplinary research among organic synthesis, chemistry of polymers and ceramic technology. It presents the synthesis of monoacryloyl esters of fructose and glucose that is 1-O-acryloyl-D-fructose and 3-O-acryloyl-D-glucose, conditions of their polymerization and application in shaping of advanced ceramic powders by the so called gelcasting method. The paper presents the influence of carbohydrate esters on the viscosity of Al2O3 suspensions and microstructure of final ceramic samples. The results showed that synthesized esters of saccharides can play the role of organic monomers able to polymerize in situ and self-cross-linking compounds in gelcasting. The paper presents the proposed structure of polymeric network which is formed from acryloyl ester of glucose during gelcasting process. The paper describes rheological behaviour of slurries composed of synthesized substances and A(2)O(3) powders, wetting angles of alumina substrate by synthesized compounds, differences in glass transition temperatures of polymers and the microstructure of obtained final ceramic samples. (C) 2014 Elsevier Ltd. All rights reserved.
• KALUZA, ZBIGNIEW;FUDONG, WANG;BELZECKI, CZESLAW;CHMIELEWSKI, MAREK, TETRAHEDRON LETT., 30,(1989) N8, C. 5171-5172
  作者：KALUZA, ZBIGNIEW、FUDONG, WANG、BELZECKI, CZESLAW、CHMIELEWSKI, MAREK

  DOI：——

  日期：——
• REITZ, ALLEN B.;TUMAN, ROBERT W.;MARCHIONE, CAROL S.;JORDAN, ALFONZO D. (+, J. MED. CHEM., 32,(1989) N, C. 2110-2116
  作者：REITZ, ALLEN B.、TUMAN, ROBERT W.、MARCHIONE, CAROL S.、JORDAN, ALFONZO D. (+

  DOI：——

  日期：——
• KRASKA, B.;LICHTEL, R., TETRAHEDRON LETT., 1983, 24, N 4, 361-364
  作者：KRASKA, B.、LICHTEL, R.

  DOI：——

  日期：——