1,4-dimethyl-2-(tridecafluorohexyl)benzene | 123524-58-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-dimethyl-2-(tridecafluorohexyl)benzene
• 英文别名: 1,4-dimethyl-2-(perfluorohexyl)benzene；1,4-dimethyl-2-(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)benzene
• CAS: 123524-58-3
• 化学式: C₁₄H₉F₁₃
• 分子量: 424.205
• InChiKey: PTWQEKZPSMBKGD-UHFFFAOYSA-N

物化性质

• 沸点：
  227.8±40.0 °C(Predicted)
• 密度：
  1.449±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  对二甲苯 、 1,1,2,2,3,3,4,4,5,5,6,6,6-十三氟己烷-1-磺酰氯 在 dichlorotris(triphenylphosphine)ruthenium(II) 作用下， 反应 24.0h， 以41%的产率得到1,4-dimethyl-2-(tridecafluorohexyl)benzene
  参考文献：
  名称：

  Kamigata, Nobumasa; Fukushima, Takamasa; Yoshida, Masato, Chemistry Letters, 1990, # 4, p. 649 - 650

  摘要：

  DOI：

文献信息

• Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes
  作者：Mikhail Khrizanforov、Sofia Strekalova、Vera Khrizanforova、Valeriya Grinenko、Kirill Kholin、Marsil Kadirov、Timur Burganov、Aidar Gubaidullin、Tatyana Gryaznova、Oleg Sinyashin、Long Xu、David A. Vicic、Yulia Budnikova

  DOI：10.1039/c5dt03009a

  日期：——

  A new iron-catalyzed reaction for the coupling of perfluoroalkyl iodides with aromatic substrates is described.

  描述了一种新的铁催化的反应，用于偶联全氟烷基碘化物和芳香基底物。
• POLYMER COMPOUND AND COMPOSITION CONTAINING THE SAME
  申请人：Mikami Satoshi

  公开号：US20100033086A1

  公开（公告）日：2010-02-11

  A polymer compound comprising as repeating units an optionally substituted fluorenediyl group and a phenylene group having one or more substituents, and comprising a repeating unit of the following formula (1) and/or a group of the following formula (2): (in the formula (1), Ar 1 and Ar 2 represent an arylene group or di-valent aromatic heterocyclic group, and Ar 1 and may be the same or different.) (in the formula (2), Ar 1 represents the same meaning as described above. Ar 3 represents an aryl group or mono-valent aromatic heterocyclic group.).

  一种聚合物化合物，其重复单元包括一个可选取代的芴基基团和一个具有一个或多个取代基的苯基团，并包括以下式(1)的重复单元和/或以下式(2)的基团： （在式（1）中，Ar1和Ar2表示芳烃基团或双价芳香杂环基团，Ar1和Ar2可以相同或不同。） （在式（2）中，Ar1表示与上述相同的含义。Ar3表示芳基团或单价芳香杂环基团。）
• Redox system for perfluoroalkylation of arenes and α-methylstyrene derivatives using titanium oxide as photocatalyst
  作者：Mari Iizuka、Masato Yoshida

  DOI：10.1016/j.jfluchem.2009.07.010

  日期：2009.10

  Photoirradiation of titanium oxide (TiO2) excites the electrons from the valence band to the conduction band, leaving holes in the valence band. Using these holes and electrons, it is possible to perform one-electron oxidations and reductions. We developed a method for the photocatalytic perfluoroalkylation of aromatic rings such as benzene and its derivatives, naphthalene and benzofuran with perfluoroalkyl iodide by the combination of reduction and oxidation reactions with TiO2. Perfluoroalkyl iodide was reduced to a perfluoroalkyl radical by the excited electrons in the conduction band of TiO2, and the resulting radical reacted with an aromatic ring to form an arenium radical that was successively oxidized to a cation by the holes in the valence band of TiO2. Similarly, the photocatalytic reaction of alpha-methylstyrene with perfluoroalkyl iodide afforded perfluoroalkylated alpha-methylstyrene, in which the perfluoroalkyl group is on a methyl carbon. (C) 2009 Elsevier B.V. All rights reserved.
• Kamigata, Nobumasa; Ohtsuka, Takeshi; Fukushima, Takamasa, Journal of the Chemical Society. Perkin transactions I, 1994, # 10, p. 1339 - 1346
  作者：Kamigata, Nobumasa、Ohtsuka, Takeshi、Fukushima, Takamasa、Yoshida, Masato、Shimizu, Toshio

  DOI：——

  日期：——
• Kamigata Nobumasa, Ohtsuka Takeshi, Fukushima Takamasa, Yoshida Masato, S+, J. Chem. Soc. Perkin Trans, (1994) N 10, S 1339-1346
  作者：Kamigata Nobumasa, Ohtsuka Takeshi, Fukushima Takamasa, Yoshida Masato, S+

  DOI：——

  日期：——