<2,2,2-Trifluor-1-(bis-fluormethyl)-aethyl>-cyclohexan | 883-67-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: <2,2,2-Trifluor-1-(bis-fluormethyl)-aethyl>-cyclohexan
• 英文别名: Hexafluorisopropyl-cyclohexan；1-[2,2,2-Trifluoro-1-(trifluoromethyl)ethyl]cyclohexane；1,1,1,3,3,3-hexafluoropropan-2-ylcyclohexane
• CAS: 883-67-0
• 化学式: C₉H₁₂F₆
• 分子量: 234.185
• InChiKey: NIKZGRVKCNDRAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  六氟丙酮吖嗪 在 环己烷 作用下， 生成 <2,2,2-Trifluor-1-(bis-fluormethyl)-aethyl>-cyclohexan
  参考文献：
  名称：

  Anomalous reactions of bis(trifluoromethyl)diazomethane and bis(trifluoromethyl)diazirine with saturated hydrocarbons

  摘要：

  DOI：

  10.1021/ja01026a044

文献信息

• Preparation and properties of bistrifluoromethylamino-mercurials and iodobistrifluoromethylamine
  作者：R. C. Dobbie、H. J. Emeléus

  DOI：10.1039/j19660000367

  日期：——

  mercurials, R2Hg (R = CH3 or SCF3) to give the mixed mercury derivatives, (CF3)2NHgR. Some reactions of the mixed mercurials with halogen-containing compounds have been investigated, leading to the preparation of the new compound N-iodobistrifluoromethylamine.

  与相应的卤化磷相反，N-溴-或N-氯-双三氟甲胺与对称汞R 2 Hg（R = CH 3或SCF 3）反应，得到混合的汞衍生物（CF 3）2 NHgR。已研究了混合汞与含卤素化合物的某些反应，从而导致了新化合物N-碘代双三氟甲胺的制备。
• [EN] PROCESSES AND COMPOUNDS FOR THE DECARBOXYLATIVE AMINATION OF REDOX-ACTIVE ESTERS WITH DIAZIRINES<br/>[FR] PROCÉDÉS ET COMPOSÉS POUR L'AMINATION DÉCARBOXYLATIVE D'ESTERS À ACTIVITÉ REDOX AVEC DES DIAZIRINES
  申请人：H LEE MOFFITT CANCER CT & RES

  公开号：WO2020252457A1

  公开（公告）日：2020-12-17

  The invention described herein relates generally to processes for the synthesis of amine-containing organic compounds. More specifically, described herein relates to processes for the decarboxylative amination of redox-active esters with diazirines and the products formed thereof. Compounds for use in the above processes are also described.

  本发明涉及一般用于合成含胺有机化合物的过程。更具体地，本发明涉及一种使用重氮丙烷对氧化还原活性酯进行脱羧胺化的过程，以及由此形成的产物。还描述了用于上述过程的化合物。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.8, 3, page 55 - 151
  作者：

  DOI：——

  日期：——
• [EN] MATERIALS FOR FORMING A NUCLEATION-INHIBITING COATING AND DEVICES INCORPORATING SAME<br/>[FR] MATÉRIAUX POUR FORMATION DE REVÊTEMENT INHIBANT LA NUCLÉATION ET DISPOSITIFS LES INCORPORANT
  申请人：OTI LUMIONICS INC

  公开号：WO2020225778A1

  公开（公告）日：2020-11-12

  An opto-electronic device includes a nucleating inhibiting coating (NIC) disposed on a first layer surface of the device in a first portion of a lateral aspect thereof; and a conductive coating disposed on a second layer surface of the device in a second portion of the lateral aspect thereof; wherein an initial sticking probability for forming the conductive coating onto a surface of the NIC in the first portion, is substantially less than the initial sticking probability for forming the conductive coating onto the surface in the second portion, such that the surface of the NIC in the first portion is substantially devoid of the conductive coating.