acetic acid-(1,3,3-trimethyl-butyl ester) | 60388-83-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acetic acid-(1,3,3-trimethyl-butyl ester)
• 英文别名: Essigsaeure-(1,3,3-trimethyl-butylester)；2-Acetoxy-4,4-dimethylpentan；1,3,3-Trimethylbutylacetat；1,3,3-Trimethylbutyl ethanoate；4,4-dimethylpentan-2-yl acetate
• CAS: 60388-83-2
• 化学式: C₉H₁₈O₂
• 分子量: 158.241
• InChiKey: YNZHMOJBQUFQMY-UHFFFAOYSA-N

物化性质

• 沸点：
  76-76.5 °C(Press: 47 Torr)
• 密度：
  0.874±0.06 g/cm3(Predicted)
• 保留指数：
  960

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-二溴-4,4-二甲基-戊烷 在 乙醇 、 硫酸 、 锌 作用下， 生成 acetic acid-(1,3,3-trimethyl-butyl ester)
  参考文献：
  名称：

  Whitmore; Homeyer, Journal of the American Chemical Society, 1933, vol. 55, p. 4558

  摘要：

  DOI：

文献信息

• Steric Effects in Elimination Reactions. II. The Effect of the Steric Requirements of Alkyl Substituents upon the Extent and Direction of Unimolecular Elimination in the Solvolysis of Tertiary Alkyl Bromides
  作者：Herbert C. Brown、M. Nakagawa

  DOI：10.1021/ja01618a055

  日期：1955.7
• Loiseau, Andre-Michel; Luft, Robert; Zunino, Serge, Bulletin de la Societe Chimique de France, 1982, vol. 2, # 5-6, p. 144 - 152
  作者：Loiseau, Andre-Michel、Luft, Robert、Zunino, Serge

  DOI：——

  日期：——
• LOISEAU, A. -M.;LUFT, R.;ZUNINO, S., BULL. SOC. CHIM. FRANCE, 1982, N 5-6, 144-152
  作者：LOISEAU, A. -M.、LUFT, R.、ZUNINO, S.

  DOI：——

  日期：——
• Method for the Preparation of Enantiomerically Enriched Secondary Alcohols by the Addition of Organoaluminium Reagents to Carbonyl Compounds
  申请人：Woodward Simon

  公开号：US20080227978A1

  公开（公告）日：2008-09-18

  A process for converting a carbonyl group within a substrate to a chiral alcohol moiety comprising reacting the carbonyl containing substrate with an organoaluminium reagent in the presence of a Group 5-12 transition metal based catalyst which is complexed with a chiral ligand; novel chiral ligands and organoluminium reagents, a chiral ligand or organoaluminium reagent for use in the process.
• BINDER FOR ELECTRIC DOUBLE-LAYER CAPACITOR ELECTRODE, ELECTRIC DOUBLE-LAYER CAPACITOR ELECTRODE COMPRISING SAME BINDER, ELECTRIC DOUBLE-LAYER CAPACITOR USING SAME ELECTRODE, AND ELECTRIC APPARATUS
  申请人：Sumitomo Seika Chemicals Co., Ltd.

  公开号：US20170025230A1

  公开（公告）日：2017-01-26

  A binder for an electric double-layer capacitor electrode according to the present invention includes a copolymer of vinyl alcohol and an alkali metal-neutralized product of ethylene-unsaturated carboxylic acid.