[1,1,2,2-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)ethyl] hypofluorite | 1277191-66-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 磺酰卤
• 英文名称: [1,1,2,2-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)ethyl] hypofluorite
• CAS: 1277191-66-8
• 化学式: C₄F₁₀O₄S
• 分子量: 334.092
• InChiKey: GWQZLVVVDUUSSE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  61
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  1,2-二氯-1,2-二氟乙烯 、 [1,1,2,2-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)ethyl] hypofluorite 反应 24.0h， 以73.3%的产率得到2-[2-(1,2-Dichloro-1,2,2-trifluoroethoxy)-1,1,2,2-tetrafluoroethoxy]-1,1,2,2-tetrafluoroethanesulfonyl fluoride
  参考文献：
  名称：

  Syntheses of a Perfluoroethanesulfonyl Fluoride Vinyl Ether

  摘要：

  The target monomer, perfluoroethanesulfonyl fluoride vinyl ether 8, was obtained from the starting material, iodoperfluoroethanesulfonyl fluoride 1, through the intermediate, acyl fluoride 4. Two different synthetic routes were utilized in the conversion of 4 to 8.

  DOI：

  10.1021/jo102409s
• 作为产物：
  描述：

  5-fluorosulfonylhexafluoro-3-oxapentanoyl fluoride 在 fluorine 、 cesium fluoride 作用下， 反应 36.0h， 以89.2%的产率得到[1,1,2,2-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)ethyl] hypofluorite
  参考文献：
  名称：

  Syntheses of a Perfluoroethanesulfonyl Fluoride Vinyl Ether

  摘要：

  The target monomer, perfluoroethanesulfonyl fluoride vinyl ether 8, was obtained from the starting material, iodoperfluoroethanesulfonyl fluoride 1, through the intermediate, acyl fluoride 4. Two different synthetic routes were utilized in the conversion of 4 to 8.

  DOI：

  10.1021/jo102409s

文献信息

• Syntheses of a Perfluoroethanesulfonyl Fluoride Vinyl Ether
  作者：Changqing Lu、Wanchao Jiang、Tom Hickman、Darryl D. DesMarteau

  DOI：10.1021/jo102409s

  日期：2011.4.15

  The target monomer, perfluoroethanesulfonyl fluoride vinyl ether 8, was obtained from the starting material, iodoperfluoroethanesulfonyl fluoride 1, through the intermediate, acyl fluoride 4. Two different synthetic routes were utilized in the conversion of 4 to 8.