1-chloro-2,3-epoxy-cyclohexane | 51918-80-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 1-chloro-2,3-epoxy-cyclohexane
• 英文别名: 1-Chlor-2,3-epoxy-cyclohexan；2-Chloro-7-oxabicyclo[4.1.0]heptane
• CAS: 51918-80-0
• 化学式: C₆H₉ClO
• 分子量: 132.59
• InChiKey: CHBHHVKAAFZYEQ-UHFFFAOYSA-N

物化性质

• 沸点：
  72 °C(Press: 15 Torr)
• 密度：
  1.168 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-chloro-2,3-epoxy-cyclohexane 在 硫酸 作用下， 生成 (+/-)-3c-chloro-cyclohexanediol-(1r.2t)
  参考文献：
  名称：

  Mousseron; Jacquier, Bulletin de la Societe Chimique de France, 1950, p. 698,705

  摘要：

  DOI：
• 作为产物：
  描述：

  过氧化氢苯甲酰 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1-chloro-2,3-epoxy-cyclohexane
  参考文献：
  名称：

  Mousseron; Jacquier, Bulletin de la Societe Chimique de France, 1950, p. 698,705

  摘要：

  DOI：

文献信息

• Poly(glycidyl ether) block copolymers and process for their preparation
  申请人：The B.F. GOODRICH Company

  公开号：EP0103297A2

  公开（公告）日：1984-03-21

  57 Under particular conditions, a cationic ring-opening polymerization of a first oxirane monomer selected from the group consisting of an acyclic glycidyl ether, a cyclic glycidyl ether, and a haloalkyl epoxide, in the presence of a hydroxyl-containing organic material ("HCM"), for example a polymer (referred to herein as a "hydroxyl-prepolymer"), and a particular catalyst, produces a polymerization having "living polymerization" characteristics. The result is that molecular weight (mol wt) of the resulting polymer is directly proportional to the conversion of the monomer to said resulting polymer. This HCM serves as a chain propagator which initially furnishes OH groups as propagation sites. Subsequently, a second oxirane monomer, different from said first, is sequentially polymerized to yield a block copolymer. Branched block copolymers, or linear block copolymers of a HCM and (a) one or more glycidyl ethers, or (b) a haloalkyl epoxide and at least one glycidyl ether, may be prepared. Halogen containing segments of the block copolymers of the invention may be aminated to produce amphophilic polymers.

  57 在特定条件下，在含羟基有机物（"HCM"），例如聚合物（此处称为 "羟基预聚物"） 和特定催化剂的存在下，选自无环缩水甘油醚、环缩水甘油醚和卤代烷基环氧化物组成的 组的第一环氧乙烷单体进行阳离子开环聚合，可产生具有 "活聚合 "特性的聚合反应。其结果是，所得聚合物的分子量（mol wt）与单体转化为所述所得聚合物的转化率成正比。这种 HCM 可作为链延伸剂，最初提供 OH 基团作为链延伸位点。随后，与第一种不同的第二种环氧乙烷单体依次聚合，生成嵌段共聚物。可制备支链嵌段共聚物，或 HCM 和 (a) 一个或多个缩水甘油醚，或 (b) 卤代环氧烷和至少一个缩水甘油醚的线性嵌段共聚物。本发明嵌段共聚物中的含卤素段可进行胺化处理，生成亲两性聚合物。
• Block copolymers and process for their preparation
  申请人：The B.F. GOODRICH Company

  公开号：EP0106218A1

  公开（公告）日：1984-04-25

  Under particular conditions, a cationic ring-opening polymerization of an (single) oxirane monomer selected from the group consisting of an acyclic glycidyl ether, a cyclic glycidyl ether, and a haloalkyl epoxide, in the presence of a hydroxyl-terminated prepolymer ("HTP") and a particular catalyst, produces a polymerization having 'living polymerization' characteristics, provided that the OH groups are aliphatic OH groups and not aromatic OH groups. The result is an AB or ABA type block copolymer the molecular weight (mol wt) of which is directly proportional to the conversion of the monomerto the block copolymer. The HTP which may be a mono-, di-, tri-, or tetra-hydroxyl-terminated prepolymer, serves as a chain propagator which initially furnishes OH groups as propagation sites. Linear block copolymers or branched block copolymers are formed, depending upon the structure of the HTP. Where one segment of an AB or ABA type block contains halogen, the segment may be aminated. If the other segment is hydrophobic, the aminated block copolymer is amphiphilic.

  在特定条件下，在羟基封端预聚物（"HTP"）和特定催化剂的存在下，从无环缩水甘油醚、环缩水甘油醚和卤代烷基环氧化物组成的组中选出的（单一）环氧乙烷单体进行阳离子开环聚合，产生一种具有 "活聚合 "特性的聚合，条件是羟基是脂肪族羟基而不是芳香族羟基。其结果是 AB 或 ABA 型嵌段共聚物，其分子量（mol wt）与单体到嵌段共聚物的转化率成正比。HTP 可以是单羟基、二羟基、三羟基或四羟基封端预聚物，可作为链延伸剂，最初提供 OH 基团作为链延伸位点。根据 HTP 的结构，可形成线性嵌段共聚物或支化嵌段共聚物。如果 AB 型或 ABA 型嵌段的一个区段含有卤素，则可对该区段进行胺化处理。如果另一部分是疏水性的，则胺化嵌段共聚物是两亲性的。
• Polymeric battery separators
  申请人：The B.F. GOODRICH Company

  公开号：EP0161623A2

  公开（公告）日：1985-11-21

  Configurations of cross-linked or vulcanized amphophilic or quaternized block copolymer of haloalkyl epoxides and hydroxyl terminated alkadiene polymers are useful as battery separators in both primary and secondary batteries, particularly nickel-zinc batteries. The quaternized block copolymers are prepared by polymerizing a haloalkyl epoxide in the presence of a hydroxyl terminated 1,3-alkadiene to form a block copolymer that is then reacted with an amine to form the quaternized or amphophilic block copolymer that is then cured or cross-linked with sulfur, polyamines, metal oxides, organic peroxides and the like.

  卤代烷基环氧化物和羟基封端烷二烯聚合物的交联或硫化两性或季铵化嵌段共聚物配置可用作一次和二次电池，特别是镍锌电池的电池隔膜。 季铵化嵌段共聚物的制备方法是在羟基封端 1,3- 烷二烯存在下聚合卤代烷基环氧化物，形成嵌段共聚物，然后与胺反应，形成季铵化或两性嵌段共聚物，再与硫、多胺、金属氧化物、有机过氧化物等固化或交联。
• Allyl terminated macromolecular monomers of polyethers
  申请人：The B.F. GOODRICH Company

  公开号：EP0218079A2

  公开（公告）日：1987-04-15

  A cationic ring-opening polymerization of a cylic ether ("CE") in conjunction with an unsaturated alcohol (propagator) having an allyl double bond, produces a polyether macromer having an allylic group near one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the CE to the OH group which is the propagating species. The CE is an alkylene oxide or an aliphatic or aromatic glycidyl ether; the propa­gator is a primary or secondary alcohol which, if cyclic may have a single internal double bond in one ring. The catalyst is a Friedel-Crafts acid, strong protic organic or inorganic acid, oxonium salt, or the like. The macromer formed may be homopolymerized to yield a poly­vinyl homomacromer with pendant chains of polymerized CE; or the CE may be copolymerized with a wide variety of olefinically unsaturated monomers to form a macromer copolymer; or, plural cyclic ethers may be (a) sequenti­ally polymerized to form macromer block copolyethers, or, (b) polymerized randomly to form macromer copoly­ether copolymers. The cationically ring-opened macromer formed always contains a trace of a cyclic oligomer of the CE.

  环状醚（"CE"）与具有烯丙基双键的不饱和醇（促进剂）进行阳离子开环聚合，可产生一种聚醚大分子，其一端附近具有烯丙基，另一端具有羟基。聚合反应是通过 CE 与羟基的加成反应进行的。CE 是环氧亚烷基或脂肪族或芳香族缩水甘油醚；繁殖体是伯醇或仲醇，如果是环状的，可能在一个环上有一个内部双键。催化剂为 Friedel-Crafts 酸、强质子有机酸或无机酸、羰基鎓盐或类似物质。形成的大单体可进行均聚，生成具有聚合 CE 下垂链的聚乙烯均大单体；或将 CE 与多种烯烃不饱和单体共聚，形成大单体共聚物；或将多个环醚 (a) 顺序聚合，形成大单体嵌段共聚物，或 (b) 随机聚合，形成大单体共聚醚共聚物。形成的阳离子开环大单体总是含有微量的 CE 环状低聚物。
• Styryl terminated macromolecular monomers of polyethers
  申请人：The B.F. GOODRICH Company

  公开号：EP0221551A2

  公开（公告）日：1987-05-13

  A cationic ring-opening polymerization of a cylic ether ("CE") in conjunction with an unsaturated alcohol (propagator) having a styryl or substituted styryl group, produces a polyether macromer having the styryl group near one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the CE to the OH group which is the propagating species. The CE is an alkylene oxide or an aliphatic or aromatic gly­cidyl ether; the propagator is a primary or secondary alcohol. The catalyst is a Friedel-Crafts acid, strong protic organic or inorganic acid, oxonium salt, or the like. Plural cyclic ethers may be (a) sequentially polymerized to form macromer block copolyethers, or, (b) polymerized randomly to form macromer copolyether co­polymers. The cationically ring-opened macromer formed always contains a trace of a cyclic oligomer of the CE. The macromer formed may be homopolymerized to yield a homopolymer of the macromer with pendant chains of poly­merized CE; or the macromer may be copolymerized with a wide variety of olefinically unsaturated monomers to form a copolymer of macromer.

  环状醚（"CE"）与具有苯乙烯基或取代苯乙烯基的不饱和醇（促进剂）进行阳离子开环聚合，可产生一种聚醚大单体，其一端附近具有苯乙烯基，另一端具有羟基。聚合是通过 CE 与羟基的加成反应进行的。CE 是环氧亚烷基或脂肪族或芳香族缩水甘油醚；促进剂是伯醇或仲醇。催化剂为 Friedel-Crafts 酸、强质子有机酸或无机酸、羰基鎓盐或类似物质。多元环醚可以 (a) 顺序聚合形成大单体嵌段共聚物，或 (b) 无规聚合形成大单体共聚醚共聚物。形成的阳离子开环大单体总是含有微量的 CE 环状低聚物。形成的大孔聚合体可进行均聚，生成大孔聚合体与聚合 CE 的垂链的均聚物；或将大孔聚合体与多种烯烃不饱和单体进行共聚，形成大孔聚合体的共聚物。