1,4-cyclohexadiene diepoxide | 285-52-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 1,4-cyclohexadiene diepoxide
• 英文别名: cyclohexa-1,4-diene epoxide；1,2;4,5-diepoxy-cyclohexane；4,8-Dioxatricyclo[5.1.0.03,5]octane
• CAS: 285-52-9
• 化学式: C₆H₈O₂
• 分子量: 112.128
• InChiKey: XOAKQCOPHMCADA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2932999099

反应信息

• 作为反应物：
  描述：

  1,4-cyclohexadiene diepoxide 在 lithium aluminium tetrahydride 、 sodium hydride 作用下， 生成 cyclohex-3-enyl-methyl ether
  参考文献：
  名称：

  Factors influencing conformational preferences in cyclohexenes

  摘要：

  DOI：

  10.1021/ja00312a030
• 作为产物：
  描述：

  1,4-环己二烯 在 间氯过氧苯甲酸 作用下， 以35%的产率得到1,4-cyclohexadiene diepoxide
  参考文献：
  名称：

  Factors influencing conformational preferences in cyclohexenes

  摘要：

  DOI：

  10.1021/ja00312a030

文献信息

• Efficient and Stereospecific Synthesis of (z)-Hex-3-Enedioic Acid, a Key Intermediate for Gly-Gly <i>cis</i> Olefin Isostere
  作者：Nurit Perlman、Amnon Albeck

  DOI：10.1080/00397910008087071

  日期：2000.12.1

  Abstract (z)-Hex-3-enedioic acid, a key intermediate in the synthesis of (z)-5-amino-3-pentenoic acid (a Gly-Gly cis olefin isostere), was synthesized by a short and efficient procedure of sequential oxidations. Thus, selective mono epoxidation of 1,4-cyclohexadiene was followed by periodate oxidation to the appropriate dialdehyde. Finally, Jones oxidation of the dialdehyde afforded the corresponding

  摘要 (z)-Hex-3-enedioic acid 是 (z)-5-amino-3-pentenoic 酸（一种 Gly-Gly 顺式烯烃等排体）合成的关键中间体顺序氧化。因此，1,4-环己二烯的选择性单环氧化之后是高碘酸盐氧化成合适的二醛。最后，二醛的琼斯氧化得到相应的二酸产物。
• Heterocyclic multifunctional amine adducts and curable compositions containing the same
  申请人：HEXCEL CORPORATION (a California corporation)

  公开号：EP0071197A1

  公开（公告）日：1983-02-09

  A compound prepared by reacting at least one aromatic or aliphatic polyamine compound having at least two amine groups, which are separated by no more than one carbon atom, with at least one carbonyl-containing compound selected from the group consisting of aldehydes and ketones, wherein said polyamine compound is selected from: aliphatic polyamines having 2-20 carbon atoms corresponding to the formula: wherein A is a direct carbon-carbon bond or -CH2- and R3 and R4 are independently hydrogen or alkyl which may be branched or unbranched and which may be unsubstituted or substituted with amine groups; wherein said aldehydes correspond to the formula: wherein R represents alkyl of 1-20 carbon atoms, which may be branched or unbranched, and which may be unsubstituted or substituted with -CHO or -COOH; -CHO; -COOH; or phenyl which may be unsubstituted or substituted with -CHO, -OH OR lower alkoxy, of 1-5 carbon atoms, and wherein said ketones correspond to the formula: wherein R, and R2 independently represent alkyl of 1-20 carbon atoms, which may be branched or unbranched, and whose chain may be interrupted by one or more groups; phenyl; or R1 and R2 may together form a cycloaliphatic ring which may be interrupted by a group; or R, and R2 may together form an 0-heterocyclic ring which may be substituted with lower alkyl of 1-5 carbon atoms, -OH or acetyl; a method of making the same; curable compositions containing the same; a method of curing; and composite articles are disclosed.

  一种化合物，由至少一种芳香族或脂肪族多胺化合物与至少一种选自由醛和酮组成的组中的含羰基化合物反应制备而成，所述多胺化合物具有至少两个胺基团，这两个胺基团之间相隔不超过一个碳原子，其中所述多胺化合物选自以下物质： 1： 具有 2-20 个碳原子的脂肪族多胺，其化学式如下 其中 A 是直接的碳-碳键或-CH2-，R3 和 R4 独立地为氢或烷基，烷基可以是支链或非支链的，可以是未取代的或被胺基取代的； 其中所述醛符合以下式子 其中 R 代表 1-20 个碳原子的烷基，可以是支链或未支链的，可以未被取代或被 -CHO 或 -COOH 取代；-CHO；-COOH；或代表 1-5 个碳原子的苯基，可以未被取代或被 -CHO、-OH OR 低级烷氧基取代；其中所述酮符合式 其中 R 和 R2 独立地代表 1-20 个碳原子的烷基，可以是支链或非支链，其链可被一个或多个 苯基；或 R1 和 R2 可共同形成环脂族环，该环可被一个或多个基团打断。 或 R 和 R2 可共同形成一个可被 1-5 个碳原子的低级烷基、-OH 或乙酰基取代的 0-杂环；公开了相同物质的制造方法；含有相同物质的可固化组合物；固化方法；以及复合物品。
• Novel polymers based on bicyclic amide acetals/polyepoxides/polyisocyanates
  申请人：Ashland Oil, Inc.

  公开号：EP0185933A1

  公开（公告）日：1986-07-02

  Novel polymers having excellent physical properties including heat distortion temperatures and izod impact strengths are prepared by the interaction of bicyclic amide acetals with epoxide resins and polyisocyanates.

  通过双环酰胺醋酸酯与环氧树脂和多异氰酸酯的相互作用，制备出了具有优异物理特性（包括热变形温度和 izod 冲击强度）的新型聚合物。
• High performance two-component epoxy structural adhesives with chemical thixotropy
  申请人：Ashland Oil, Inc.

  公开号：EP0199889A2

  公开（公告）日：1986-11-05

  A two component adhesive formulation comprising a mixture of A. an epoxy component comprising an epoxy resin and as an additive (a) a poylisocyanate, (b) a carboxylic anhydride and/or (c) a compound having unsaturated carbon-carbon bonds capable of undergoing Michael addition reaction with amines, and B. a hardner component for curing component A comprising a mixture of amido amines, primary and secondary amines having tertiary amine groups or ether groups in their backbone, and bisphenol-A is described.

  描述了一种双组分粘合剂配方，包括以下物质的混合物：A. 环氧组分，包括环氧树脂和添加剂 (a) 月桂异氰酸酯、(b) 羧酸酐和/或 (c) 具有不饱和碳碳键并能与胺发生迈克尔加成反应的化合物；B. 用于固化组分 A 的硬化剂组分，包括氨基胺、骨架中具有叔胺基团或醚基团的伯胺和仲胺以及双酚 A 的混合物。
• Sag resistant two-component epoxy structural adhesive
  申请人：Ashland Oil, Inc.

  公开号：EP0238058A2

  公开（公告）日：1987-09-23

  A two-component structural adhesive comprising a first epoxy component composed of an epoxy resin containing from 0.5 to 8% by weight based on the weight of the epoxy resin of fumed silica and a second hardener component composed of an amido amine, primary and secondary amines having tertiary amine groups or alkylene ether groups in the backbone, and a phenolic compound is disclosed.

  本发明公开了一种双组分结构粘合剂，包括由环氧树脂组成的第一环氧组分（按环氧树脂重量计算，气相二氧化硅的含量为 0.5%至 8%）和由氨基胺、骨架中具有叔胺基团或亚烷基醚基团的伯胺和仲胺以及酚类化合物组成的第二固化剂组分。