申请人:PROMERUS, LLC
公开号:US11230566B2
公开(公告)日:2022-01-25
Embodiments in accordance with the present invention encompass compositions encompassing a latent organo-ruthenium compound and a pyridine compound along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is exposed to suitable actinic radiation to form a substantially transparent film. Surprisingly, the compositions are very stable at ambient conditions to temperatures up to 80° C. for several days and undergo mass polymerization when subject only to actinic radiation. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as 3D printing materials, coatings, encapsulants, fillers, leveling agents, among others.
根据本发明的实施方案,本发明的组合物包括一种潜在的有机钌化合物和一种吡啶化合物,以及一种或多种单体,当所述组合物暴露于适当的光辐射下形成基本透明的薄膜时,这些单体会发生开环偏聚(ROMP)。令人惊奇的是,这种组合物在环境条件下非常稳定,温度最高可达 80 摄氏度,可持续数天,而且仅在光辐射下就会发生大规模聚合。因此,本发明的组合物可用于各种光电子应用,包括用作 3D 打印材料、涂层、封装剂、填料、流平剂等。