Trifluoro-[tris(trifluoromethyl)-lambda4-tellanyl]methane | 95776-70-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: Trifluoro-[tris(trifluoromethyl)-lambda4-tellanyl]methane
• 英文别名: trifluoro-[tris(trifluoromethyl)-λ4-tellanyl]methane
• CAS: 95776-70-8
• 化学式: C₄F₁₂Te
• 分子量: 403.625
• InChiKey: WSQJPXFVDJPTBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.84
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  Trifluoro-[tris(trifluoromethyl)-lambda4-tellanyl]methane 生成 双(三氟甲基)二氟化碲
  参考文献：
  名称：

  On fluoro-organo tellurium, iodine and xenon derivatives

  摘要：

  The syntheses, thermal and chemical stabilities as well as the reactivities of an isovalent series of CF3 and C6F5 compounds of Te, I and Xe have been compared.In the isovalent series Te(CF3)(2), ICF3 and Xe, an increase in stability is observed from the Te compound to elemental xenon. Te(CF3)(2) and ICF3 can be prepared via thermal reactions from Hg(CF3)(2) and TeCl4 and I-2, respectively. A variation in stability is observed in oxidation reactions. Xenon is only oxidized by elemental fluorine, ozone is required for the oxidation of ICF3, while elemental oxygen suffices for the oxidation of Te(CF3)(2). This variation raises the question as to whether the neutral compounds Te(CF3)(4), I(CF3)(3) and Xe(CF3)(2) or the cations [Te(CF3)(3)](+), [I(CF3)(2)](+) and [XeCF3](+) exist.

  DOI：

  10.1016/0022-1139(94)06013-c
• 作为产物：
  描述：

  bis(trifluoromethyltellurium) dichloride 、 alkaline earth salt of/the/ methylsulfuric acid 生成 Trifluoro-[tris(trifluoromethyl)-lambda4-tellanyl]methane
  参考文献：
  名称：

  Preparations and properties of tetrakis(perfluoroorgano)-tellurium compounds

  摘要：

  DOI：

  10.1016/s0022-1139(00)83262-5

文献信息

• Tetrakis(trifluormethyl)tellur (CF3)4Te [1]
  作者：Dieter Naumann、Bernd Wilkes

  DOI：10.1016/s0022-1139(00)80903-3

  日期：1985.1
• Preparations and properties of tetrakis(perfluoroorgano)-tellurium compounds
  作者：D. Naumann、B. Wilkes、J. Hanke

  DOI：10.1016/s0022-1139(00)83262-5

  日期：1985.8
• On fluoro-organo tellurium, iodine and xenon derivatives
  作者：D.J. Naumann

  DOI：10.1016/0022-1139(94)06013-c

  日期：1995.4

  The syntheses, thermal and chemical stabilities as well as the reactivities of an isovalent series of CF3 and C6F5 compounds of Te, I and Xe have been compared.In the isovalent series Te(CF3)(2), ICF3 and Xe, an increase in stability is observed from the Te compound to elemental xenon. Te(CF3)(2) and ICF3 can be prepared via thermal reactions from Hg(CF3)(2) and TeCl4 and I-2, respectively. A variation in stability is observed in oxidation reactions. Xenon is only oxidized by elemental fluorine, ozone is required for the oxidation of ICF3, while elemental oxygen suffices for the oxidation of Te(CF3)(2). This variation raises the question as to whether the neutral compounds Te(CF3)(4), I(CF3)(3) and Xe(CF3)(2) or the cations [Te(CF3)(3)](+), [I(CF3)(2)](+) and [XeCF3](+) exist.