perfluoroethylcyclohexene | 80308-96-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: perfluoroethylcyclohexene
• 英文别名: perfluoro-1-ethyl-cyclohexene；perfluoro(1-ethylcyclohex-1-ene)；Cyclohexene, 1,3,3,4,4,5,5,6,6-nonafluoro-2-(pentafluoroethyl)-；1,3,3,4,4,5,5,6,6-nonafluoro-2-(1,1,2,2,2-pentafluoroethyl)cyclohexene
• CAS: 80308-96-9
• 化学式: C₈F₁₄
• 分子量: 362.066
• InChiKey: FOWHSSKFNBVODM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  perfluoroethylcyclohexene 在 三乙胺 、 cesium fluoride 作用下， 以 二乙二醇二甲醚 为溶剂， 反应 3.0h， 生成 1-ethoxyperfluoro-2-ethylcyclohexene
  参考文献：
  名称：

  Reactions of perfluoro-1-alkylcycloalkenes with alcohols and properties of vinyl ethers formed

  摘要：

  DOI：

  10.1007/bf00956599
• 作为产物：
  描述：

  perfluoro-(2-ethylcyclohexanesulfofluoride) 以 二乙二醇二甲醚 为溶剂， 以81.5%的产率得到perfluoroethylcyclohexene
  参考文献：
  名称：

  ?-Fluoroalkylamides, a new source of nonhydrated fluoride ion. 3.19F NMR spectra of perfluoro carbanions generated by means of N,N,N?,N?-tetramethylformamidinium bifluoride

  摘要：

  DOI：

  10.1007/bf00963403

文献信息

• Partial oxidation of internal fluoroolefins by potassium permanganate
  作者：I. L. Knunyants、S. A. Postovoi、N. I. Delyagina、Yu. V. Zeifman

  DOI：10.1007/bf00961993

  日期：1987.10
• Technology for the preparation of perfluoro-organic compounds
  作者：Dmitrii D Moldavskii、Tatjana A Bispen、Galina I Kaurova、Georgii G Furin

  DOI：10.1016/s0022-1139(98)00351-0

  日期：1999.4

  Fluorination by elemental fluorine of fluorine-containing alkenes, alkanes, ethers and tertiary amines was investigated, aimed at obtaining the perfluorinated analogs. The factors affecting yield of the target compounds were studied. Elements of technology were elucidated. (C) 1999 Elsevier Science S.A. All rights reserved.
• Karpov; Mezhenkova; Platonov, Russian Journal of Organic Chemistry, 1999, vol. 35, # 8, p. 1176 - 1181
  作者：Karpov、Mezhenkova、Platonov

  DOI：——

  日期：——
• Fluoroalkenylphosphonates from branched chain and cyclic perfluoroolefins
  作者：Alexander A. Kadyrov、Dmitry V. Silaev、Kiril N. Makarov、Lev L. Gervits、Gerd-Volker Röschenthaler

  DOI：10.1016/j.jfluchem.2003.11.014

  日期：2004.10

  In a Arbuzov-type reaction branched chain and cyclic perfluoroolefins react with trimethylsilyl diethyl phosphite to give new fluorinated alkenylphosphonates. Two internal olefins furnish by a radical addition of dialkyl phosphites fluoroalkylphosphonates, which could be converted using BF3.NEt3 to give the respective fluoroalkenylphosphonates. (C) 2003 Elsevier B.V. All rights reserved.
• Furin, G. G., Russian Journal of Organic Chemistry, 1995, vol. 31, # 4, p. 465 - 468
  作者：Furin, G. G.

  DOI：——

  日期：——