2-Hydroxypropyl 2-ethylbutanoate | 1462389-91-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-Hydroxypropyl 2-ethylbutanoate
• 英文别名: 2-hydroxypropyl 2-ethylbutanoate
• CAS: 1462389-91-8
• 化学式: C₉H₁₈O₃
• 分子量: 174.24
• InChiKey: SDMOAXOFXREKIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-乙基丁酸 、 methyloxirane 在 吡啶 、 iron(III) chloride 作用下， 以 neat (no solvent) 为溶剂， 反应 12.0h， 生成 2-Hydroxypropyl 2-ethylbutanoate 、 1-Hydroxypropan-2-yl 2-ethylbutanoate
  参考文献：
  名称：

  FeCl 3 /pyridine: dual-activation in opening of epoxide with carboxylic acid under solvent free condition

  摘要：

  Inexpensive, non-toxic, and readily available catalyst system FeCl3/pyridine was found to be highly efficient for the opening of a wide variety of epoxides with carboxylic acid under solvent free conditions. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.08.074

文献信息

• POLYVINYL ACETAL SHEET AND PROCESS FOR PRODUCTION THEREOF
  申请人：Denki Kagaku Kogyo Kabushiki Kaisha

  公开号：EP2083039A1

  公开（公告）日：2009-07-29

  Provided are a polyvinyl acetal sheet which is excellent in adhesion to glass, easy in control of adhesion, little colored, highly transparent and excellent in penetration resistance even under high-temperature conditions when the sheet is used for laminated glass or the like, a process for its production and a process for producing polyvinyl acetal particles used for the sheet. The polyvinyl acetal sheet is produced by molding polyvinyl acetal particles into a sheet with a degree of acetalization of from 75.0 to 84.0 mass% and with a porosity of from 60 to 85%. The polyvinyl acetal particles are preferably produced by an acetalization reaction of 100 parts by mass of a polyvinyl alcohol and from 40 to 75 parts by mass of an aldehyde in the presence of an acid catalyst at a reaction temperature of from 20 to 60°C, and the acetalization reaction comprises supplying the polyvinyl alcohol, the aldehyde and the acid catalyst to a reactor to bring about acetalization, discharging a reaction mixture from the reactor after the degree of acetalization of the produced polyvinyl acetal has reached 13 mass%, and subjecting the discharged reaction mixture to an aging reaction.

  本发明提供了一种聚乙烯醇缩醛片材，该片材与玻璃的粘合力极佳，易于控制粘合力，着色少，透明度高，即使在高温条件下用于夹层玻璃或类似材料时也具有极佳的抗渗透性；还提供了一种生产该片材的工艺和一种生产用于该片材的聚乙烯醇缩醛颗粒的工艺。 聚乙烯醇缩醛板是通过将聚乙烯醇缩醛颗粒模塑成缩醛度为 75.0 至 84.0 质量％、孔隙率为 60 至 85％的板材而制成的。聚乙烯醇缩醛颗粒最好是由 100 质量份的聚乙烯醇和 40 至 75 质量份的醛在酸催化剂存在下，在 20 至 60°C 的反应温度下进行缩醛反应制得，缩醛反应包括提供聚乙烯醇、醛和催化剂、在生产的聚乙烯醇缩醛的缩醛度达到 13 质量％后，将反应混合物从反应器中排出，并将排出的反应混合物进行老化反应。
• FeCl 3 /pyridine: dual-activation in opening of epoxide with carboxylic acid under solvent free condition
  作者：Yichao Zhao、Wen Wang、Jian Li、Feng Wang、Xiufang Zheng、Hongying Yun、Weili Zhao、Xiaochun Dong

  DOI：10.1016/j.tetlet.2013.08.074

  日期：2013.10

  Inexpensive, non-toxic, and readily available catalyst system FeCl3/pyridine was found to be highly efficient for the opening of a wide variety of epoxides with carboxylic acid under solvent free conditions. (C) 2013 Elsevier Ltd. All rights reserved.