perfluoro-(1,3-dimethylcyclopentane) | 4536-12-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: perfluoro-(1,3-dimethylcyclopentane)
• 英文别名: Perfluoro-1,3-dimethylcyclopentane；1,1,2,2,3,4,4,5-octafluoro-3,5-bis(trifluoromethyl)cyclopentane
• CAS: 4536-12-3
• 化学式: C₇F₁₄
• 分子量: 350.055
• InChiKey: SGXUAYOWYOIPSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  三烯丙基胺 、 三氟甲苯 在 氢氟酸 作用下， 生成 perfluoro-(1,3-dimethylcyclopentane) 、 全氟甲基环戊烷 、 全氟环己胺 、 全氟甲基环己烷 、 alkaline earth salt of/the/ methylsulfuric acid 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Electrochemical fluorination of toluene and benzotrifluoride in the presence of triallylamine

  摘要：

  Electrochemical fluorination of benzotrifluoride in the presence of triallylamine as depolarizer was studied. The possibility of preparing perfluoromethylcyclohexane and its isomers with high current efficiency and substance yield in combination with perfluorinated tertiary amines was examined.

  DOI：

  10.1134/s1070427207120169

文献信息

• Electrochemical fluorination of toluene and benzotrifluoride in the presence of triallylamine
  作者：V. A. Matalin、G. I. Kaurova、V. V. Berenblit、V. I. Gribel’

  DOI：10.1134/s1070427207120169

  日期：2007.12

  Electrochemical fluorination of benzotrifluoride in the presence of triallylamine as depolarizer was studied. The possibility of preparing perfluoromethylcyclohexane and its isomers with high current efficiency and substance yield in combination with perfluorinated tertiary amines was examined.