2,4-dimethylphenoxide ion | 86260-38-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-dimethylphenoxide ion
• 英文别名: 2,4-dimethyl phenolate；2,4-dimethylphenoxide；2,4-Dimethylphenolate
• CAS: 86260-38-0
• 化学式: C₈H₉O
• 分子量: 121.159
• InChiKey: KUFFULVDNCHOFZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N,N-二乙基-2-硝基丁烷-1-胺 在 sodium tetrahydroborate 作用下， 以 氘代二甲亚砜 为溶剂， 生成 4-硝基苯酚阴离子 、 2,4-dimethylphenoxide ion
  参考文献：
  名称：

  Phototriggering of geometric dendrimer disassembly: an improved synthesis of 2,4-bis(hydroxymethyl)phenol based dendrimers

  摘要：

  Dendrimers capable of phototriggered disassembly were prepared up to the second-generation using an improved synthesis of 2,4-bis(hydroxymethyl)phenol based dendrimers. It was found that disassembly proceeds to 75-80% completion after 2 h of irradiation at 310 nm for all molecules studied. The lack of complete reaction is attributed to an inefficient photochemical deprotection process rather than the disassembly itself. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.06.078

文献信息

• Phototriggering of geometric dendrimer disassembly: an improved synthesis of 2,4-bis(hydroxymethyl)phenol based dendrimers
  作者：Michael L. Szalai、Dominic V. McGrath

  DOI：10.1016/j.tet.2004.06.078

  日期：2004.8

  Dendrimers capable of phototriggered disassembly were prepared up to the second-generation using an improved synthesis of 2,4-bis(hydroxymethyl)phenol based dendrimers. It was found that disassembly proceeds to 75-80% completion after 2 h of irradiation at 310 nm for all molecules studied. The lack of complete reaction is attributed to an inefficient photochemical deprotection process rather than the disassembly itself. (C) 2004 Elsevier Ltd. All rights reserved.