2,6-di-tert-butyl-4-methylpyrylium cation | 46426-69-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2,6-di-tert-butyl-4-methylpyrylium cation
• 英文别名: 2,6-di-tert-butyl-4-methyl-pyranylium；2,6-di-tert-butyl-4-methyl-pyrylium cation；2,6-Di-tert.-butyl-4-methylpyrylium-salz；2,6-Di-tert.-butyl-4-methylpyrylium-ion；2,6-Di-tert.-butyl-4-methyl-pyrylium；2,6-Di-tert.-butyl-4-methylpyrylium；2,6-Ditert-butyl-4-methylpyrylium
• CAS: 46426-69-1
• 化学式: C₁₄H₂₃O
• 分子量: 207.336
• InChiKey: RYAQAOLNUHTJAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.46
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,6-di-tert-butyl-4-methylpyrylium cation 在 一水合肼 作用下， 以 甲醇 为溶剂， 生成 3,7-di-tert-butyl-5-methyl-4H-1,2-diazepine
  参考文献：
  名称：

  Electron impact mass spectra of 3,5,7-triaryl-and -trialkyl-4H-1,2-diazepines

  摘要：

  AbstractElectron impact mass spectra of 3,5,7‐trisubstituted 4H‐1,2‐diazepines indicate that aryl substituents lead to N2expulsion while alkyl substitutents do not. A common fragmentation pattern is observed and discussed for all alkyldiazepines, most of which are newly reported compounds. Assignments are based on electron impact mass spectra of deuteriated substrates and high resolution mass spectra. A previous interpretation of N2expulsion is corrected.

  DOI：

  10.1002/oms.1210181006

文献信息

• Pyridinium cationic lipids as gene transfer agents
  申请人：Balaban T. Alexandru

  公开号：US20050196863A1

  公开（公告）日：2005-09-08

  Pyridinium cationic lipids useful as non-viral gene delivery agents are disclosed. The agents are prepared by reaction of pyrylium salts with primary amines. Also disclosed are methods of trasfectind cells using the pyridinium cationic lipids as gene transfer agents.

  披萨是一种美味的食物，通常由面团、番茄酱、奶酪和各种配料制成。
• METHOD FOR PRODUCTION OF N-CARBOXY AMINO ACID ANHYDRIDE AND AMINO ACID CARBAMATE COMPOUND
  申请人：Endo Takeshi

  公开号：US20110152561A1

  公开（公告）日：2011-06-23

  A method for production of an N-carboxy amino acid anhydride with efficiency is provided. The method for production of an N-carboxy amino acid anhydride includes a step of reaction of an amino acid organic salt compound with a carbonic acid diester.

  提供了一种高效的生产N-羧基氨基酸酐的方法。该生产N-羧基氨基酸酐的方法包括将氨基酸有机盐化合物与碳酸二酯反应的步骤。
• Synthesis of squarylium compounds
  申请人：POLAROID CORPORATION

  公开号：EP0516985A1

  公开（公告）日：1992-12-09

  Squarylium compounds of the formula: wherein Q¹ and Q² are each independently a pyrylium, thiopyrylium, selenopyrylium, benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus, and R¹ and R² are each independently an aliphatic or cycloaliphatic group, can be prepared by reacting a squaric acid derivative of the formula: with a compound of the formula Q²CH₂R² in the presence of a base. The derivatives of Formula II may be prepared by condensing a 2,3,4,4-tetrahalocyclobut-2-en-1-one with a compound of the formula Q¹CH₂R¹ in the presence of a base to produce a compound of the formula: wherein Q¹ and R¹ are as defined above, and X represents chlorine or bromine, and hydrolyzing the compound of Formula III. Alternatively, the derivatives of Formula II may be prepared by reacting a diester, monoacid chloride monoester or diacid chloride of squaric acid with a compound of the formula Q¹CH₂R¹ in the presence of a base, followed by hydrolysis of the resultant monoacid chloride or monoester derivative of the compound of Formula II to the parent compound.

  式中的鳞片状化合物： 其中 Q¹ 和 Q² 各自独立地为吡喃鎓、硫吡喃鎓、硒吡喃鎓、苯并吡喃鎓、苯硫吡喃鎓或苯并硒吡喃鎓原子核，R¹ 和 R² 各自独立地为脂肪族或环脂族基团： 与式 Q²CH₂R² 的化合物在碱存在下反应，可制备式 II 衍生物。式 II 衍生物可通过在碱存在下将 2,3,4,4-四卤环丁-2-烯-1-酮与式 Q¹CH₂R¹ 的化合物缩合生成式的化合物来制备： 其中 Q¹ 和 R¹ 如上所定义，X 代表氯或溴，然后水解式 III 的化合物。另外，式 II 衍生物的制备方法是：在碱存在下，将角鲨酸的二酯、单酰氯单酯或二酰氯与式 Q¹CH₂R¹ 的化合物反应，然后将得到的式 II 化合物的单酰氯或单酯衍生物水解为母体化合物。
• N-CARBOXY AMINO ACID ANHYDRIDE AND AMINO ACID CARBAMATE COMPOUND PRODUCTION METHOD
  申请人：JSR Corporation

  公开号：EP2322515A1

  公开（公告）日：2011-05-18

  A method for production of an N-carboxy amino acid anhydride with efficiency is provided. The method for production of an N-carboxy amino acid anhydride includes a step of reaction of an amino acid organic salt compound with a carbonic acid diester.

  本发明提供了一种高效生产 N-羧基氨基酸酐的方法。生产 N-羧基氨基酸酐的方法包括氨基酸有机盐化合物与碳酸二酯反应的步骤。
• A process for the preparation of an N-carboxy amino acid anhydride or an amino acid carbamate
  申请人：JSR Corporation

  公开号：EP2322515B1

  公开（公告）日：2016-04-20