2-[1-(3-methylphenyl)ethyl]phenol | 1239712-25-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[1-(3-methylphenyl)ethyl]phenol
• CAS: 1239712-25-4
• 化学式: C₁₅H₁₆O
• 分子量: 212.291
• InChiKey: AAIWJFIANHGRLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-甲基苯乙烯 、 苯酚 在 iron-containing mesoporous aluminosilicate Al-MCM-41 作用下， 以 环己烷 为溶剂， 反应 7.0h， 以81%的产率得到2-[1-(3-methylphenyl)ethyl]phenol
  参考文献：
  名称：

  Iron-Containing Mesoporous Aluminosilicate: A Highly Active and Reusable Heterogeneous Catalyst for Hydroarylation of Styrenes

  摘要：

  Hydroarylation of various styrene derivatives has been successfully carried out in excellent yield using Fe-Al-MCM-41 catalyst. The C-H functionalization using solid heterogeneous catalyst provides a straightforward access to a series or important 1,1-diarylalkane products. The catalyst can be recovered and reused at least three times without any significant loss in its catalytic activity.

  DOI：

  10.1021/jo100803y

文献信息

• Iron-Containing Mesoporous Aluminosilicate: A Highly Active and Reusable Heterogeneous Catalyst for Hydroarylation of Styrenes
  作者：Satyajit Haldar、Subratanath Koner

  DOI：10.1021/jo100803y

  日期：2010.9.3

  Hydroarylation of various styrene derivatives has been successfully carried out in excellent yield using Fe-Al-MCM-41 catalyst. The C-H functionalization using solid heterogeneous catalyst provides a straightforward access to a series or important 1,1-diarylalkane products. The catalyst can be recovered and reused at least three times without any significant loss in its catalytic activity.