pentamethylphenyl ether | 80959-75-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pentamethylphenyl ether
• 英文别名: 1,2,3,4,5-Pentamethyl-6-(2,3,4,5,6-pentamethylphenoxy)benzene
• CAS: 80959-75-7
• 化学式: C₂₂H₃₀O
• 分子量: 310.48
• InChiKey: AROVEQOVUVEKDC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  五甲基碘苯 在 copper(l) iodide 、 sodium 2,2,2-trifluoroacetate 作用下， 以 六甲基磷酰三胺 为溶剂， 反应 15.0h， 以38%的产率得到1,2,3,4,5-pentamethyl-6-(trifluoromethyl)benzene
  参考文献：
  名称：

  碘化铜 (I) 辅助未活化的碘代芳烃与三氟乙酸钠在六甲基磷酸三酰胺中的反应。核三氟甲基化和二芳醚形成

  摘要：

  聚甲基碘苯与三氟乙酸钠在碘化铜 (I) 存在下，在六甲基磷三酰胺中于 150–180°C 反应，生成相应的聚甲基三氟苯、母烃和双（聚甲基苯基）醚的混合物。

  DOI：

  10.1246/cl.1982.135

文献信息

• METHOD FOR PRODUCTION OF BLOCK COPOLYMER
  申请人：Yokozawa Tsutomu

  公开号：US20100099823A1

  公开（公告）日：2010-04-22

  Disclosed is a method for producing a block copolymer which comprises two or more blocks composed of aromatic units having different basic structures from each other and has a high molecular weight, a narrow chain length distribution and a narrow molecular weight distribution. Also disclosed is a block copolymer produced by the method. The method for producing a block copolymer comprises the step of sequentially reacting two or more aromatic compounds which are selected from aromatic compounds represented by a specific general formula and are different in the group Ar, in the presence of a nickel complex containing a phosphine compound represented by a specific general formula or a palladium complex containing a phosphine compound represented by a specific general formula to thereby form blocks comprising the aromatic compounds sequentially, wherein the two or more aromatic compounds are reacted in descending order of parameter of aromatic ring charge.

  本发明公开了一种生产块状嵌段共聚物的方法，该共聚物由两个或更多组成的芳香族单元块组成，这些单元块具有不同的基本结构，具有高分子量、窄的链长分布和窄的分子量分布。本发明还公开了通过该方法生产的块状嵌段共聚物。生产块状嵌段共聚物的方法包括以下步骤：在特定的一般式所表示的芳香族化合物中选择两个或更多个芳香族化合物，这些化合物在基团Ar中不同，并在含有特定一般式所表示的膦化合物的镍络合物或含有特定一般式所表示的膦化合物的钯络合物的存在下，依次反应这些芳香族化合物，从而形成含有这些芳香族化合物的块，其中这两个或更多个芳香族化合物按芳香环电荷参数的降序反应。
• POLYARYLENE
  申请人：Fukushima Daisuke

  公开号：US20090045725A1

  公开（公告）日：2009-02-19

  A high-molecular compound, characterized by containing a chain consisting of repeating units represented by the general formula (1) and having an average number of repeating units constituting the chain of 3 or above and a ratio of bonds formed between the head and the tail to all the bonds formed between repeating units of 85% or above: (1) wherein Ar 1 is a divalent aromatic group whose aromatic ring is an aromatic hydrocarbon ring; R 1 is a substituent on Ar 1 ; n is an integer of 0 to 30; when n is 2 or above, plural R 1 's may be the same or different from each other, when the carbon atoms of a repeating unit of the general formula (1) are numbered as a divalent group according to Nomenclature of Organic Chemistry by IUPAC, between the two carbon atoms having free valencies, the carbon atom with a smaller number is defined as the head and the carbon atom with a larger number is defined as the tail; and no repeating unit of the general formula (1) has a two-fold axis of symmetry intersecting the straight line joining the head and the tail at right angles at the middle point.
• US8349997B2
  申请人：——

  公开号：US8349997B2

  公开（公告）日：2013-01-08
• COPPER(I) IODIDE ASSISTED REACTION OF NONACTIVATED IODOARENES WITH SODIUM TRIFLUOROACETATE IN HEXAMETHYLPHOSPHORIC TRIAMIDE. NUCLEAR TRIFLUOROMETHYLATION AND DIARYL ETHER FORMATION
  作者：Hitomi Suzuki、Yoshiki Yoshida、Atsuhiro Osuka

  DOI：10.1246/cl.1982.135

  日期：1982.1.5

  Polymethyliodobenzenes react with sodium trifluoroacetate, in tine presence of copper(I) iodide, in hexamethylphosphoric triamide at 150–180°C, giving a mixture of the corresponding polymethylbenzotrifluoride, parent hydrocarbon, and bis(polymethylphenyl) ether.

  聚甲基碘苯与三氟乙酸钠在碘化铜 (I) 存在下，在六甲基磷三酰胺中于 150–180°C 反应，生成相应的聚甲基三氟苯、母烃和双（聚甲基苯基）醚的混合物。